首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9969篇
  免费   1902篇
  国内免费   865篇
化学   6531篇
晶体学   60篇
力学   658篇
综合类   61篇
数学   1178篇
物理学   4248篇
  2024年   5篇
  2023年   239篇
  2022年   228篇
  2021年   320篇
  2020年   419篇
  2019年   412篇
  2018年   337篇
  2017年   327篇
  2016年   491篇
  2015年   457篇
  2014年   534篇
  2013年   731篇
  2012年   891篇
  2011年   1000篇
  2010年   624篇
  2009年   656篇
  2008年   656篇
  2007年   559篇
  2006年   520篇
  2005年   431篇
  2004年   326篇
  2003年   276篇
  2002年   236篇
  2001年   196篇
  2000年   203篇
  1999年   188篇
  1998年   190篇
  1997年   184篇
  1996年   141篇
  1995年   187篇
  1994年   159篇
  1993年   120篇
  1992年   96篇
  1991年   83篇
  1990年   84篇
  1989年   58篇
  1988年   39篇
  1987年   26篇
  1986年   21篇
  1985年   14篇
  1984年   17篇
  1983年   14篇
  1982年   10篇
  1981年   4篇
  1980年   7篇
  1979年   2篇
  1978年   3篇
  1975年   3篇
  1974年   2篇
  1957年   3篇
排序方式: 共有10000条查询结果,搜索用时 21 毫秒
1.
Ding  Qingran  Zhang  Xingyu  Lin  Zheshuai  Xiong  Zheyao  Wang  Yusong  Long  Xifa  Zhao  Sangen  Hong  Maochun  Luo  Junhua 《中国科学:化学(英文版)》2022,65(9):1710-1714
Science China Chemistry - As structural variants of famous hexagonal tungsten bronzes, hexagonal tungsten oxides (HTO) represent an important family with fascinating functional properties, such as...  相似文献   
2.
Luo  Y.  Hao  Y.-Q. 《JETP Letters》2022,116(5):288-292
JETP Letters - A GaAs/AlOx high index contrast subwavelength grating with TE polarization is presented for the GaAs-based vertical cavity surface emitting laser (VCSEL). The rigorous coupled wave...  相似文献   
3.
Bo  Luo  Gao  Wei  Yu  Yuguo  Chen  Xiaojun 《Nonlinear dynamics》2022,110(1):281-311
Nonlinear Dynamics - The perovskite solar cell (PSC) is one of the most promising photovoltaic candidates along with the highly increasing demand for green electricity. One of the main concerns...  相似文献   
4.
通过改装多旋翼无人机(UAV)和搭载各类载荷以及联合地基观测设备对大柴旦地区大气、环境以及气溶胶参数进行测量。利用获得的数据资料,对该地区近地层气溶胶粒子数浓度(即单位体积空气中气溶胶粒子的数目)、消光系数以及气象要素等特征进行了分析。结果表明,在大柴旦地区,近地层气溶胶粒子数浓度日变化显著,呈现双峰形态,气溶胶粒子数浓度的变化范围为75~220 cm-3,消光系数的变化范围为0.004~0.038 km-1;当风速小于6 m/s时,气溶胶粒子数浓度与风速呈负相关关系;当风速大于6 m/s时,二者呈正相关关系;相对湿度对气溶胶粒子的影响较小,这可能是由于该地区以沙尘型气溶胶为主,吸湿性较弱。本研究基于多旋翼无人机探测平台,可以有效地获得近地层精细化大气、环境结构,有助于研究人员了解该地区气溶胶的结构、变化特征以及建立气溶胶模式,同时也为气溶胶及大气环境参数探测方法提供了技术支撑及思路拓展。  相似文献   
5.
Xi  Gao-Wen  Luo  Qiu-Ming 《The Ramanujan Journal》2022,58(2):505-522
The Ramanujan Journal - We show that if $$E/\mathbb {Q}$$ is an elliptic curve with a rational p-torsion for $$p=2$$ or 3, then there is a congruence relation between Ramanujan’s tau function...  相似文献   
6.
罗正 《物理通报》2022,(3):94-96
光滑半圆槽放置在光滑水平地面上,均质细直杆在半圆槽内运动,因其具有角速度而不同于小球在光滑半圆槽内的运动.运用动量守恒和机械能守恒求解或运用理论力学和微积分相关知识从系统运动的瞬时状态求解,可以推导出均质细直杆的角速度.基于MATLAB的数值模拟表明,系统做周期运动,且随着半圆槽与均质细直杆质量比的增大,运动周期增大并收敛.  相似文献   
7.
Shang  Ao  Luo  Siwei  Zhang  Jianquan  Zhao  Heng  Xia  Xinxin  Pan  Mingao  Li  Chao  Chen  Yuzhong  Yi  Jicheng  Lu  Xinhui  Ma  Wei  Yan  He  Hu  Huawei 《中国科学:化学(英文版)》2022,65(9):1758-1766

Side-chain engineering has been demonstrated as an effective method for fine-tuning the optical, electrical, and morphological properties of organic semiconductors toward efficient organic solar cells (OSCs). In this work, three isomeric non-fullerene small molecule acceptors (SMAs), named BTP-4F-T2C8, BTP-4F-T2EH and BTP-4F-T3EH, with linear and branched alkyl chains substituted on the α or β positions of thiophene as the side chains, were synthesized and systematically investigated. The results demonstrate that the size and substitution position of alkyl side chains can greatly affect the electronic properties, molecular packing as well as crystallinity of the SMAs. After blending with donor polymer D18-Cl, the prominent device performance of 18.25% was achieved by the BTP-4F-T3EH-based solar cells, which is higher than those of the BTP-4F-T2EH-based (17.41%) and BTP-4F-T2C8-based (15.92%) ones. The enhanced performance of the BTP-4F-T3EH-based devices is attributed to its stronger crystallinity, higher electron mobility, suppressed biomolecular recombination, and the appropriate intermolecular interaction with the donor polymer. This work reveals that the side chain isomerization strategy can be a practical way in tuning the molecular packing and blend morphology for improving the performance of organic solar cells.

  相似文献   
8.
Atopic dermatitis is characterized by leukocyte migration into the skin dermis and typically driven by excessive chemokine production at the site of inflammation. Conventional topical formulations such as gels, creams, and ointments are insufficient for this treatment because of low penetration of drug molecules into the targeted skin tissues. Herein, using a simple, green, sustainable strategy, we have developed novel primary zein nanoparticles embedded in curcumin (Cur) and coated with silk sericin (ZHSCs) for the topical delivery of Cur to penetrate into the dermis and exercise anti-dermatitis effects on the lesion with minimal side-effects. Transdermal delivery experiments and porcine skin fluorescence imaging indicated that ZHSCs facilitate the penetration of Cur across the epidermis layer of skin to reach deep-seated sites. Notably, ZHSCs = 1:0.25 (zein-to-silk sericin mass ratios of 1:0.25) markedly elevated the skin permeability and cumulative turnover of Cur transferred, which were provided a greater than a 3.8-fold increase relative to free Cur. The special nanoparticles of ZHS = 1:0.25 possessed the deepest localization depth and experience a transition of the particle structure and core-shell separation after penetrating into the dermis of skin. In a cell model of dermatitis induced by tumor necrosis factor α/interferon γ co-stimulation, compared with free Cur, Cur-loaded ZHS nanoparticles down-regulated the generation of inflammatory cytokines and chemokines in keratinocytes through suppression of the nuclear translocation of NF-κBp65 and hence exerted an anti-dermatitis effect. This strategy may provide new avenues and direction for the demanding issues of valid topical delivery systems.  相似文献   
9.
A reasonable prediction of photofission observables plays a paramount role in understanding the photofission process and guiding various photofission-induced applications, such as short-lived isotope production, nuclear waste disposal, and nuclear safeguards. However, the available experimental data for photofission observables are limited, and the existing models and programs have mainly been developed for neutron-induced fission processes. In this study, a general framework is proposed for characterizing the photofission observables of actinides, including the mass yield distributions (MYD) and isobaric charge distributions (ICD) of fission fragments and the multiplicity and energy distributions of prompt neutrons (np) and prompt γ rays (γp). The framework encompasses various systematic neutron models and empirical models considering the Bohr hypothesis and does not rely on the experimental data as input. These models are then validated individually against experimental data at an average excitation energy below 30 MeV, which shows the reliability and robustness of the general framework. Finally, we employ this framework to predict the characteristics of photofission fragments and the emissions of prompt particles for typical actinides including 232Th, 235, 238U and 240Pu. It is found that the 238U(γ, f) reaction is more suitable for producing neutron-rich nuclei compared to the 232Th(γ, f) reaction. In addition, the average multiplicity number of both np and γp increases with the average excitation energy.  相似文献   
10.
Journal of Solid State Electrochemistry - Cortisol, a steroid hormone, has been confirmed as a kind of biomarker that reflects the stress response of psychobiology and related adverse health...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号