In-situ cation exchange enhances room temperature phosphorescence of a family of metal-organic frameworks

The rational designability and chemical tunability of metal-organic frameworks(MOFs)are enabling tributes to efficaciously enhance their room temperature phosphorescence(RTP)performance.A family of stable anionic MOFs,[Zn₂(4,5-ImDC)₂]M₂(NKU-132,M=(CH₃)₂NH₂or(CH₂CH₃)₂NH₂),featuring significant RTP have been synthesized.By rational cation selection and in-situ replacement from dimethylammonium to diethylammonium,the phosphorescence lifetime is increased from 30.88 to126.3 ms,along with less sensitivity to air.This work provides an anti-quenching and lifetime tuning example for RTP-MOFmaterials via facile host-guest chemistry.     

A luminescent Zn(II)-Containing Complex: Selective Sensing of Cr(VI) Anion and Application Values on Tuberculosis Care Through Increasing the Antibacterial Response of Macrophages

Journal of Fluorescence - A new Zn(II)-bearing metal-organic framework (MOF), namely, {[Zn2(L)2(H2O)]·8H2O·DMF}n (1) has been generated via applying...     

Vacuum-gap-based lumped element Josephson parametric amplifier

We propose a lumped element Josephson parametric amplifier with vacuum-gap-based capacitor.The capacitor is made of quasi-floating aluminum pad and on-chip ground.We take a fabrication process compatible with air-bridge technology,which makes our design adaptable for future on-chip integrated quantum computing system.Further engineering the input impedance,we obtain a gain above 20 dB over 162-MHz bandwidth,along with a quasi quantum-limit noise performance.This work should facilitate the development of quantum information processing and integrated superconducting circuit design.     

Association measures for interval variables

Advances in Data Analysis and Classification - Symbolic Data Analysis (SDA) is a relatively new field of statistics that extends conventional data analysis by taking into account intrinsic data...     

CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]− Anionic Framework

The first alkali-metal vanadium iodate fluoride, CsVO₂F(IO₃), with a novel 3D anionic framework, has been rationally designed and hydrothermally synthesized. The 3D [VO₂F(IO₃)]⁻ framework in CsVO₂F(IO₃) is built from 0D Λ-shaped cis-[VO₃F(IO₃)₂]⁴⁻ polyanions via corner-sharing of oxo anions and bridging of the iodate groups. CsVO₂F(IO₃) displays both a strong second-harmonic generation (SHG) 1.1 times as strong as KTiOPO₄ (KTP) under 2.05 μm laser radiation and high laser-induced damage threshold (LIDT) of 107.9 MW cm⁻². This work provides a new route to design SHG crystals with stable 3D anionic structures from low-dimensional structural building units.     

三点起爆控制参数对尾翼爆炸成型弹丸成型的影响

针对三点起爆控制参数（起爆直径、起爆同步误差）对尾翼爆炸成型弹丸（explosively formed projectile，EFP）成型的影响问题，理论分析了三点起爆条件下爆轰波的马赫碰撞，计算获得了不同起爆直径下马赫波的相关参数，利用LS-DYNA有限元软件通过数值模拟研究了不同起爆直径下三点起爆同步误差对EFP尾翼成型及飞行速度的影响规律。结果表明，起爆直径越大，马赫波在药型罩上的作用面积越小，马赫超压越大，形成的EFP长径比和速度越大；起爆直径为30、40、50 mm三点起爆成型装药形成较佳尾翼EFP应满足的最大起爆同步误差分别为50、100、150 ns；此外，尽量使中间起爆点起爆同步误差约为最大同步误差的一半，有利于降低尾翼EFP的侧向分速度，提高飞行稳定性。     

Biological Applications of Macrocyclic Schiff Base Ligands and Their Metal Complexes: A Survey of the Literature (2005–2019)

This article aims to provide a survey of biological applications of Schiff base macrocycles and their metal complexes, with emphasis given to the synthesis of the compounds and to their uses as antibacterial and antifungal agents. The literature on the subject, published during the 2005–2019 period, is shortly reviewed. This is an informed report collecting information on the addressed topic in a concise systematic way, and can be expected to be useful as a fast literature catalogue for researchers working on this and related domains.