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1.
为了提升兰州重离子加速器冷却存储环(HIRFL-CSR)中放射性次级束流装置(RIBLL2)的粒子鉴别能力,在其F1色散面上研发、安装了一套可测量核反应产物起始时间和位置等信息的新型高性能探测器,并发展了一种利用测量的位置及飞行时间等实验数据提取束线光学参数从而修正粒子磁刚度的实验方法。使用F1色散面上的新型探测器,再结合粒子磁刚度修正方法,首次在RIBLL2-ETF分离器上实现了全动量接收度下300 MeV/nucleon 78Kr弹核碎裂产物的清楚鉴别,结果显示:对于较重的75As33+,其电荷分辨σZ~0.19、质核比分辨σA/Z~5.8×10?3。这一结果,有效提升了RIBLL2粒子鉴别能力,增加了奇异核收集效率,使研究范围由低质量核区(A<40)拓展到了中等质量核区(A~80),这将有效促进RIBLL2上放射性次级束物理实验的发展。  相似文献   
2.
A batch Markov arrival process (BMAP) X* = (N, J) is a 2-dimensional Markov process with two components, one is the counting process N and the other one is the phase process J. It is proved that the phase process is a time-homogeneous Markov chain with a finite state-space, or for short, Markov chain. In this paper, a new and inverse problem is proposed firstly: given a Markov chain J, can we deploy a process N such that the 2-dimensional process X* = (N, J) is a BMAP? The process X* = (N, J) is said to be an adjoining BMAP for the Markov chain J. For a given Markov chain the adjoining processes exist and they are not unique. Two kinds of adjoining BMAPs have been constructed. One is the BMAPs with fixed constant batches, the other one is the BMAPs with independent and identically distributed (i.i.d) random batches. The method we used in this paper is not the usual matrix-analytic method of studying BMAP, it is a path-analytic method. We constructed directly sample paths of adjoining BMAPs. The expressions of characteristic (D k , k = 0, 1, 2 · · ·) and transition probabilities of the adjoining BMAP are obtained by the density matrix Q of the given Markov chain J. Moreover, we obtained two frontal Theorems. We present these expressions in the first time.  相似文献   
3.
Studies on N2 activation and transformation by transition metal hydride complexes are of particular interest and importance. The synthesis and diverse transformations of a dinitrogen dititanium hydride complex bearing the rigid acridane-based acriPNP-pincer ligands {[(acriPNP)Ti]2(μ2-η1:η2-N2)(μ2-H)2} are presented. This complex enabled N2 cleavage and hydrogenation even without additional H2 or other reducing agents. Furthermore, diverse transformations of the N2 unit with a variety of organometallic compounds such as ZnMe2, MgMe2, AlMe3, B(C6F5)3, PinBH, and PhSiH3 have been well established at the rigid acriPNP-ligated dititanium framework, such as reversible bonding-mode change between the end-on and side-on/end-on fashions, diborylative N=N bond cleavage, the formal insertion of two dimethylaluminum species into the N=N bond, and the formal insertion of two silylene units into the N=N bond. This work has revealed many unprecedented aspects of dinitrogen reaction chemistry.  相似文献   
4.
A multi‐state and multi‐stimuli‐responsive oxazine molecular switch that combines an electro‐base property and sensitive base/acid‐responsive properties was designed and synthesized. The multi‐state structures of the molecular switch, with different colors, were predicted by comparing the optical properties with reference molecules and confirmed by using NMR spectroscopy. The color‐switching mechanism under stimulation with acids and bases was investigated by using DFT calculations. Three single states can be obtained and the switching is unidirectional under acid and base stimulation. The electrochromic phenomenon of the molecular switch, which combines its electro‐base and base‐sensitive properties, was demonstrated. An electrochromic device that exhibited good electrochromic properties with excellent reversibility (2000 cycles) and high coloration efficiency (804 cm2 C?1) was successfully constructed.  相似文献   
5.
本文合成了三种具有多氢键的联萘酚轴手性硫脲催化剂,并将其用于催化合成1,4-二氢吡啶衍生物。结果显示,所合成的新型多氢键硫脲均表现出较好的催化作用,能有效地提高1,4-二氢吡啶衍生物的收率和对映选择性。所有新化合物结构均经过~1H NMR、~(13)C NMR、IR、熔点等表征所确认。  相似文献   
6.
Necessary and sufficient conditions for qualitative properties of infinite dimensional linear programing problems such as solvability, duality, and complementary slackness conditions are studied in this article. As illustrations for the results, we investigate the parametric version of Gale’s example.  相似文献   
7.
An iron‐catalyzed C?H/N?H alkyne annulation was realized by using a customizable clickable triazole amide under exceedingly mild reaction conditions. A unifying mechanistic approach combining experiment, spectroscopy, kinetics, and computation provided strong support for facile C?H activation by a ligand‐to‐ligand hydrogen transfer (LLHT) mechanism. Combined Mössbauer spectroscopic analysis and DFT calculations were indicative of high‐spin iron(II) species as the key intermediates in the C?H activation manifold.  相似文献   
8.
Quantized vortices are important topological excitations in Bose–Einstein condensates. The Gross–Pitaevskii equation is a widely accepted theoretical tool. High accuracy quantized-vortex solutions are desirable in many numerical and analytical studies. We successfully derive the Padéapproximate solutions for quantized vortices with winding numbers ω = 1, 2, 3, 4, 5, 6 in the context of the Gross–Pitaevskii equation for a uniform condensate. Compared with the numerical solutions, we find that(1) they approximate the entire solutions quite well from the core to infinity;(2) higher-order Padé approximate solutions have higher accuracy;(3) Padé approximate solutions for larger winding numbers have lower accuracy. The healing lengths of the quantized vortices are calculated and found to increase almost linearly with the winding number. Based on experiments performed with ~(87)Rb cold atoms, the healing lengths of quantized vortices and the number of particles within the healing lengths are calculated, and they may be checked by experiment. Our results show that the Gross–Pitaevskii equation is capable of describing the structure of quantized vortices and physics at length scales smaller than the healing length.  相似文献   
9.
The use of natural compounds to construct biomaterials, including delivery system, is an attractive strategy. In the present study, through threading functional α‐cyclodextrins onto the conjugated macromolecules of poly(ethylene glycol) (PEG) and natural compound bile acid, glycopolymers of polyrotaxanes with the active targeting ability are obtained. These glycopolymers self‐assemble into micelles as evidenced by dynamic light scattering and transmission electron microscopy, in which glucosamine, as an example of targeting groups, is introduced. These micelles after loading doxorubicin (DOX) exhibit the selective recognition with cancer cells 4T1. Meanwhile, the maximal half inhibitory concentration is determined to be ≈2.5 mg L?1 for the DOX‐loaded micelles, close to the value of free DOX·HCl (1.9 mg L?1). The cumulative release of DOX at pH 5.5 is faster than at pH 7.4, which may be used as the controlled release system. This drug delivery system assembled by glycopolymers features high drug loading of DOX, superior biocompatibility. The strategy not only utilizes the micellization induced by bile acids, but also overcomes the major limitation of PEG such as the lack of targeting groups. In particular, this drug delivery platform can extend to grafting the other targeting groups, rendering this system more versatile.  相似文献   
10.
Two typical molecular switches of spiropyran (SP) and benzoxazine (OX) were fused by sharing an indole to achieve a new dual‐addressable molecular switch (SP‐OX‐NO2). Through proper molecular modification with NO2, the transformation from merocyanine (MC) to ring‐closed SP or ring‐closed OX can be controlled separately with visible light or base stimuli in solution, respectively, and these processes are verified by UV‐vis and NMR spectroscopy as well as control experiments. The cis‐merocyanine (cis‐MC) form is involved in the basochromic process in solution. DFT calculation suggests that the bidirectional switching property of the fused SP‐OX molecular switch can be controlled separately, when the OX isomer is more stable than the deprotonated SP isomer. Because of the significant color variations in solution, the simple dual‐addressable switch has been further successfully applied to construct a multicolor reversible display on paper.  相似文献   
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