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1.
Hydrogels containing benzo-18-crown-6 were used to modify microcantilevers for measurements of the concentration of Pb2+ in aqueous solutions. These microcantilevers undergo bending deflection upon exposure to solutions containing various Pb2+ concentrations as the result of a swelling of the hydrogels. It was found that a concentration of 10(-6) M Pb2+ can be detected using this technology. Other cations, such as Na+, have no effect on the deflection of this cantilever. The cation K+, which also complexes with benzo-18-crown-6, could interfere with Pb2+ detection, but only at high concentrations (> 10(-4) M).  相似文献   
2.
The kinetics of the hydrolysis of p-nitrophenyl esters of three types of single-chain carboxylic acids, namely, saturated, olefinic and acetylenic, was investigated in two aquiorgano binary solvent systems, DMSO-H2O and dioxane (DX)-H2O. The ester probes used are: octanoic (C8), dodecanoic (C12) , stearic (C18) , oleic (C18-ol) , elaidic (C18-el ) and stearolic (C18-st). The order of measured CAgC values is: C18-ol>C18-el>C18>C18-st, whereas the order of decreasing magnitude of the observed hydrolytic rate constants of the monomeric species (km) is: C18>C18-el>C18-ol> C18-st. These rather unanticipated results are discussed.  相似文献   
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Qi Ji 《Tetrahedron》2006,62(11):2529-2536
Regio- and stereocontrolled synthesis and conformational analysis of a series of benzimidazole nucleosides were achieved. A simple method by 1H NMR 1D NOE experiment was developed for estimation of syn or anti conformation of benzimidazole nucleosides. Substituents at C2 of benzimidazole demonstrated to play a key role both in the unexpected regioselectivity of the glycosidic reaction and in the conformation distributions of the final products.  相似文献   
7.
The maximum intensity, Imax, and time required to reach the maximum emission, taumax, for 1-aminopyrene monitored in 1,1'-oxalyldi-4-methylimidazole (OD4MI) chemiluminescence (CL) reactions are approximately 61 times higher and 16 times faster than their respective values for bis(2,4,6-trichlorophenyl)oxalate (TCPO) CL reactions in the presence of imidazole (ImH).  相似文献   
8.
The effects of the pretreatment of copper in benzimidazole solutions on the anodic reactions have been observed. The structures of the chemisorbed benzimidazole on copper were studied by using the infrared reflection-absorption technique and X-ray photoelectron spectroscopy. It was found that a compact film of benzimidazolato copper(I) was formed on the copper surface when copper was immersed in a stirred benzimidazole solution and cyclic voltammetry applied. This compact polymer film inhibited anodic oxidation effectively.  相似文献   
9.
The selectivity and analytical application of a thin-layer electrochemical detector comprised of glassy carbon electrode coated with Nafion film were investigated. As a result of the ion-exchange characteristics of the Nafion polymer, the selectivity and stability were improved greatly. The coated electrode has a good response only for cations with the same sensitivity as an uncoated (bare) electrode, but not for anions, and the response for neutral molecules is decreased three-fold. The diffusion of electroactive compounds in Nafion film is discussed based on the results of flow injection experiments. The peak current at the coated electrode was independent of the flow-rate of the mobile phase. Electrode poisoning due to protein adsorption was minimized. The use of 30% methanol or 10% acetonitrile in the mobile phase did not affect the performance of the coated electrode. Various analytes having three kinds of charge state, i.e., anionic, cationic and neutral, were tested. Liquid chromatography with electrochemical detection of ascorbic acid, norepinephrine, epinephrine, dopamine and uric acid was demonstrated.  相似文献   
10.
Application of the spin trapping technique in intact animals requires an understanding of the stability and distribution of the spin traps and their spin adducts in vivo. We studied the stability of DMPO in vivo in mice using HPLC and the stability of spin adducts of DMPO by EPR in plasma, whole blood, peritoneal fluid, and homogenized heart tissue of the rat. At 15 minutes after intraperitoneal injection DMPO had similar concentrations in the liver, heart, and blood of the mice and 40% remained in the organs 2 hours after the injection. In contrast, the spin adduct DMPO-OH was short lived, with a half-life of 3.0 minutes in plasma, and was not detectable 1 minute after formation in whole blood and homogenized heart tissue. The carbon centered spin adduct DMPO-CH(OH)CH3 was more stable, having half-lives of 16, 11, 3.6, and 0.79 minutes in plasma, peritoneal fluid, whole blood, and homogenized heart tissue, respectively. The spin adduct DMPO-SO3 was sufficiently stable for the adduct to be observed directly from living mice.  相似文献   
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