A multifunctional silicotungstic acid-modified Li-rich manganese-based cathode material with excellent electrochemical properties

Journal of Solid State Electrochemistry - Li-rich layered oxide (LrLO) cathode has attracted much attention for Li-ion batteries in recent years due to its superior capacity of exceeding...     

In Situ Generated Gold Nanoparticles on Active Carbon as Reusable Highly Efficient Catalysts for a C −C Stille Coupling

Gold nanoparticle catalysts are important in many industrial production processes. Nevertheless, for traditional C ?C cross‐coupling reactions they have been rarely used and Pd catalysts usually give a superior performance. Herein we report that in situ formed gold metal nanoparticles are highly active catalysts for the cross coupling of allylstannanes and activated alkylbromides to form C ?C bonds. Turnover numbers up to 29 000 could be achieved in the presence of active carbon as solid support, which allowed for convenient catalyst recovery and reuse. The present study is a rare case where a gold metal catalyst is superior to Pd catalysts in a cross‐coupling reaction of an organic halide and an organometallic reagent.     

In-depth profiling,characterization, and comparison of the ginsenosides among three different parts (the root,stem leaf,and flower bud) of Panax quinquefolius L. by ultra-high performance liquid chromatography/quadrupole-Orbitrap mass spectrometry

Analytical and Bioanalytical Chemistry - Despite Panax quinquefolius L. serving as a crucial source for food additives, healthcare products, and herbal medicines, unawareness of the metabolome...     

Study on the activity and mechanism of skimmianine against human non-small cell lung cancer

The present research was to investigate the effects of skimmianine (SK) in four non-small cell lung cancer (NSCLC) cells. We found that SK can significantly inhibit the growth of NSCLC cells and markedly induce apoptosis in NSCLC cells. The effects of growth inhibition and apoptosis induction were in a concentration–response relationship and caspase-dependent manner.     

An energy functional for Lagrangian tori in $$\mathbb {C}P^2$$

A two-dimensional periodic Schrödingier operator is associated with every Lagrangian torus in the complex projective plane \({\mathbb C}P^2\). Using this operator, we introduce an energy functional on the set of Lagrangian tori. It turns out this energy functional coincides with the Willmore functional \(W^{-}\) introduced by Montiel and Urbano. We study the energy functional on a family of Hamiltonian-minimal Lagrangian tori and support the Montiel–Urbano conjecture that the minimum of the functional is achieved by the Clifford torus. We also study deformations of minimal Lagrangian tori and show that if a deformation preserves the conformal type of the torus, then it also preserves the area, i.e., preserves the value of the energy functional. In particular, the deformations generated by Novikov–Veselov equations preserve the area of minimal Lagrangian tori.     

Sulfono‐γ‐AApeptides as a New Class of Nonnatural Helical Foldamer

Foldamers offer an attractive opportunity for the design of novel molecules that mimic the structures and functions of proteins and enzymes including biocatalysis and biomolecular recognition. Herein we report a new class of nonnatural helical sulfono‐γ‐AApeptide foldamers of varying lengths. The crystal structure of the sulfono‐γ‐AApeptide monomer S6 illustrates the intrinsic folding propensity of sulfono‐γ‐AApeptides, which likely originates from the bulkiness of tertiary sulfonamide moiety. The two‐dimensional solution NMR spectroscopy data for the longest sequence S1 demonstrates a 10/16 right‐handed helical structure. Optical analysis using circular dichroism further supports well‐ defined helical conformation of sulfono‐γ‐AApeptides in solution containing as few as five building blocks. Future development of sulfono‐γ‐AApeptides may lead to new foldamers with discrete functions, enabling expanded application in chemical biology and biomedical sciences.