首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9748篇
  免费   1826篇
  国内免费   1451篇
化学   7612篇
晶体学   109篇
力学   620篇
综合类   88篇
数学   1335篇
物理学   3261篇
  2023年   152篇
  2022年   196篇
  2021年   267篇
  2020年   375篇
  2019年   431篇
  2018年   343篇
  2017年   303篇
  2016年   477篇
  2015年   558篇
  2014年   584篇
  2013年   736篇
  2012年   878篇
  2011年   893篇
  2010年   704篇
  2009年   676篇
  2008年   719篇
  2007年   583篇
  2006年   518篇
  2005年   484篇
  2004年   443篇
  2003年   389篇
  2002年   491篇
  2001年   403篇
  2000年   251篇
  1999年   208篇
  1998年   175篇
  1997年   129篇
  1996年   113篇
  1995年   104篇
  1994年   82篇
  1993年   64篇
  1992年   56篇
  1991年   54篇
  1990年   33篇
  1989年   27篇
  1988年   20篇
  1987年   12篇
  1986年   9篇
  1985年   7篇
  1984年   13篇
  1983年   10篇
  1982年   4篇
  1981年   11篇
  1980年   5篇
  1979年   6篇
  1978年   4篇
  1976年   3篇
  1974年   5篇
  1938年   2篇
  1936年   2篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
We experimentally analyze the heat capacity and thermal expansion of reference solids in a wide temperature range from several Kelvin to melting temperature,and establish a universal double-linear relation between the experimental heat capacity Cp and thermal expansion β,which is different from the previous models.The universal behavior between heat capacity and thermal expansion is important to predict the thermodynamic parameters at constant pressure,and is helpful for understanding the nature of thermal properties in solids.  相似文献   
2.
微量原位水质总碱度在线检测新方法研究   总被引:1,自引:0,他引:1  
为实现原位水质总碱度快速准确检测的需求,融合顺序注射分析(sequential injection analysis, SIA)与连续光谱检测法,设计了一种小型微量原位水质总碱度在线快速检测仪,系统主要通过设计滴定池将SIA和连续光谱检测法应用于总碱度自动化滴定检测流程,并对连续光谱检测法判断滴定临界值的新方法进行实验研究。基于国标总碱度检测中工业循环冷却水及地表水总碱度的测定标准,设计了原位水质总碱度检测流程,并以顺序注射技术为控制滴定流程基础,在连续光谱扫描测量溶液检测过程的条件下,使用酚酞和甲基橙作为指示剂,对水质总碱度进行滴定分析。通过连续光谱扫描对酚酞碱度及甲基橙碱度滴定过程进行监测,以吸光度曲线552 nm处峰值归零作为酚酞碱度滴定临界值判断条件;以吸光度曲线峰值由465 nm偏移至504 nm处作为甲基橙碱度滴定临界值判断条件;分析通过滴加不同剂量酚酞和甲基橙指示剂所得溶液吸光度曲线得出最佳指示剂用量分别为0.01和0.04 mL。该系统利用最小二乘拟合算法建立总碱度测定的回归模型,并对检测系统及检测流程进行优化,实验结果表明,水质总碱度在0.20~25.00 mmol·L-1范围内与盐酸消耗量线性相关,工作曲线拟合系数≥0.994 2;测定总碱度重复性相对标准偏差(RSD)为0.207%~1.151%;废液量≤16 mL;最低检出限为0.03 mmol·L-1;样品加标回收率在97.2%~102.3%之间;与国标法对比实验结果无明显差别。利用连续光谱检测法判断滴定临界值的新方法对于提升水质总碱度检测仪的技术性能具有重要意义,可适用于系统网格化监控地表水、循环冷却水、养殖循环水等多种监测应用平台。  相似文献   
3.
In this work we extend the method of the constrained large-eddy simulation(CLES) to simulate the turbulent flow over inhomogeneous rough walls. In the original concept of CLES, the subgrid-scale(SGS) stress is constrained so that the mean part and the fluctuation part of the SGS stress can be modelled separately to improve the accuracy of the simulation result. Here in the simulation of the rough-wall flows, we propose to interpret the extra stress terms in the CLES formulation as the roughness-induced stress so that the roughness inhomogeneity can be incorporated by modifying the formulation of the constrained SGS stress. This is examined with the simulations of the channel flow with the spanwise alternating high/low roughness strips. Then the CLES method is employed to investigate the temporal response of the turbulence to the change of the wall condition from rough to smooth. We demonstrate that the temporal development of the internal boundary layer is just similar to that in a spatial rough-tosmooth transition process, and the spanwise roughness inhomogeneity has little impact on the transition process.  相似文献   
4.
We are concerned with qualitative analysis of weak solutions for a class of magnetic Laplace equations with lack of compactness. By variational arguments, we establish related nonexistence, existence and multiplicity results.  相似文献   
5.
From A to B to Z     
Jackson  Marcel  Zhang  Wen Ting 《Semigroup Forum》2021,103(1):165-190
Semigroup Forum - The variety generated by the Brandt semigroup $$B_2$$ can be defined within the variety generated by the semigroup $$A_2$$ by the single identity $$x^2y^2\approx y^2x^2$$ . Edmond...  相似文献   
6.
Zheng  Xinyan  Hu  Po  Yao  Ruxian  cheng  Jinhe  Chang  Yiheng  Wu  Haitao  Mei  Hongying  Sun  Shuxiang  Chen  Qingtai  liu  Fang  Chen  Shujing  Wen  Hua 《Journal of Radioanalytical and Nuclear Chemistry》2022,331(5):2217-2226
Journal of Radioanalytical and Nuclear Chemistry - Enhancement of U(VI) biomineralization by Saccharomyces cerevisiae through addition of inorganic phosphorus was studied in this work. The addition...  相似文献   
7.
设计合成了一个新的双1,8-萘酰亚胺衍生物(Bis-Nph), 并通过核磁共振波谱和高分辨质谱鉴定了其结构. Bis-Nph呈现出典型的分子内电荷转移(ICT)和聚集诱导增强发射(AIEE). 该化合物可以作为荧光探针检测水溶液中的苦味酸(2,4,6-三硝基苯酚, TNP), 检出限为5.8×10-7 mol/L. 作用机制为TNP的质子转移到Bis-Nph, 有效地阻断了其ICT发射, 使荧光发生显著猝灭. 另外, Bis-Nph的细胞毒性较低, 可做成试纸进行TNP的快速检测.  相似文献   
8.
Black bean, in which isoflavones are the main active constituent, also contains saponins and monoterpenes. Soybean isoflavone is a secondary metabolite that is formed during the growth of soybean; it exhibits antioxidant and cardiovascular activities and traces estrogen-like effects. In this study, black bean isoflavones were extracted with n-butanol, and ultrafiltration–liquid chromatography–mass spectrometry was used to screen their activity. Subsequently, the inhibitors were isolated and purified using semipreparative liquid chromatography and stepwise flow rate countercurrent chromatography. Thereafter, five active compounds were identified using mass spectrometry and nuclear magnetic resonance experiments. Finally, the inhibition types of the xanthine oxidase inhibitors were determined using enzymatic kinetic studies. The IC50 values of daidzin, glycitein-7-O-glucoside, genistin, daidzein, and genistein were determined to be 35.08, 56.22, 30.76, 68.79, and 95.37 μg/mL, respectively. Daidzin, genistin, and daidzein exhibited reversible inhibition, whereas glycitein-7-O-glucoside and genistein presented irreversible inhibition. This novel approach, which was based on ultrafiltration–liquid chromatography–mass spectrometry and stepwise flow rate countercurrent chromatography, is a powerful method for screening and isolating xanthine oxidase inhibitors from complex matrices. The study of enzyme inhibition types is helpful for understanding the underlying inhibition mechanism. Therefore, a beneficial platform was developed for the large-scale production of bioactive and nutraceutical ingredients.  相似文献   
9.
Ning  Zuozhou  Zhang  Zhicheng  Yan  Qingsong  Zhou  Naifu  Wen  Linzi  Peng  Xichao  Tang  Yu  Feng  Pengju 《中国科学:化学(英文版)》2022,65(10):1962-1967
Science China Chemistry - A mild and practical protocol for selectively time-dependent dehydrogenative C-C coupling, as well as tandem coupling-cyclization reaction between indoles or/and other...  相似文献   
10.
In order to reduce the pollutants of environment and electromagnetic waves, environment friendly polymer foams with outstanding electromagnetic interference shielding are imminently required. In this paper, a kind of electromagnetic shielding, biodegradable nanocomposite foam was fabricated by blending poly (butylene succinate) (PBS) with carbon nanotubes (CNTs) followed by foaming with supercritical CO2. The crystallization temperature and melting temperature of PBS/CNTs nanocomposites with 4 wt % of CNTs increased remarkably by 6 °C and 3.1 °C compared with that of pure PBS and a double crystal melting peak of various PBS samples appeared in DSC curves. Increasing the CNT content from 0 to 4 wt % leads to an increase of approximately 3 orders of magnitude in storage modulus and nearly 9 orders of magnitude in enhancement of electrical properties. Furthermore, CNTs endowed PBS nanocomposite foam with adjustable electromagnetic interference (EMI) shielding property, giving a specific EMI shielding effectiveness of 28.5 dB cm3/g. This study provides a promising methodology for preparing biodegradable, lightweight PBS/CNTs foam with outstanding electromagnetic shielding properties.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号