A New Manganese Coordination Polymer Based on Azobenzene Tetracarboxylate and Auxiliary Pyridine Ligand: Synthesis,Crystal Structure and Magnetic Property

A new manganese coordination polymer(CP)has been synthesized under hydrothermal conditions.It’s formula is{Mn2(Oaobtc)(bpe)(H₂O)₄]}n,where H4Oobtc represents oxide azobenzene 2,2',3,3'-tetracarboxyl acid,and bpe is 1,2-bis(4-pyridine)ethylene.It was characterized by elemental analysis,infrared spectrum and X-ray single-crystal diffraction.The coordination polymer crystallizes in the monoclinic system,space group P2₁/c.The central ion was coordinated with H₄Oobtc ligands using bridging model,and carboxylic group connects two adjacent Mn(Ⅱ)ions into dimer units.The oxygen from carboxylates connect these dimer units into a one-dimensional(1D)chain,and N atoms from the bpe further expanded them into three-dimensional(3D)supramolecular edifice,eventually.Variable-temperature magnetic measurements of CP 1 indicate the presence of weak antiferromagnetic exchange between two nearest Mn(Ⅱ)ions with J=–0.367 cm^-1.     

冲蚀与气蚀复合磨损试验研究

通过改造MCF-30型冲蚀腐蚀试验机,建立了水、沙、气三相流冲蚀磨损试验装置;试验研究了水、沙混合流场中试样的磨损特征,通过扫描电子显微镜观测了三相流冲蚀磨损表面,并借助计算机模拟分析水、沙混合条件下产生气蚀破坏的条件.结果表明:合理的设计可以实现冲蚀与气蚀的复合磨损模拟试验;形成三相流共同作用下的冲蚀与气蚀复合磨损重要条件为介质中含有较多气体,并且在试样中有气泡溃灭.三相流磨损模拟试验与仿真为进一步开展三相流气蚀与冲蚀磨损研究奠定了基础.     

Impact of the self-steepening effect on soliton spectral tunneling in PCF with three zero dispersion wavelengths

This work presents a numerical investigation of the self-steepening(SS) effect on the soliton spectral tunneling(SST) effect in a photonic crystal fiber(PCF) with three zero dispersion wavelengths. Interestingly, the spectral range and flatness can be flexibly tuned by adjusting the SS value. When the SS coefficient increases, the energy between solitons and dispersion waves is redistributed, and the red-shifted soliton forms earlier in the region of long wavelength anomalous dispersion. As a consequence, the SST becomes more obvious. The findings of this work provide interesting insights in regard to the impact of the SST effect on tailored supercontinuum generation.     

一种特殊截止单模光纤的传输性能研究

为了提高特殊截止单模光纤的弯曲可靠性,采用气相沉积工艺制作了包层直径80μm碳涂覆的特殊截止单模光纤,测试了光纤的截止波长、模场、衰减谱、宏弯、色散等传输性能和应力腐蚀敏感性参数。测试结果表明光纤截止波长小于915nm,能够实现915nm以上波长单模工作,在常用的几个波段具有较低的传输损耗,光纤的零色散波长红移到1 670nm。采用碳涂覆工艺提高光纤的应力腐蚀敏感性参数达到35,结合小包层直径预期可以提高光纤的使用寿命。     

纳米SiO2/HPAM/SDS分散体系稳定性的改进及其对驱油性能的影响

分析了60℃、1. 0×104mg/L氯化钠盐水和模拟地层水中纳米SiO2/HPAM/SDS分散体系的浊度实验及Zeta电位,发现Ca2+、Mg2+离子是体系失去稳定性的主要原因。根据沉降实验及Zeta电位分析仪探讨了降低p H值和添加络合剂对模拟地层水中纳米SiO2/HPAM/SDS体系稳定性的改善效果及机理,同时利用流变仪及界面张力仪分析了两种方法对体系驱油性能的影响。结果表明,p H值降低,体系的Zeta电位绝对值降低,但SiO2周围H+保护层的形成及水化作用力的增强改善了体系的稳定性;络合剂Na2EDTA、ATM P和Na4EDTA均能增强体系的稳定性,Na2EDTA和ATM P络合Ca2+、Mg2+的同时降低了体系的p H值,而体系的黏度随p H值的降低急剧下降; Na4EDTA加入后,体系的p H值增大,稳定配位化合物的形成使体系的Zeta电位绝对值、黏度、储能模量和损耗模量增加,降低界面张力的能力增强。因此,在SiO2质量分数为0. 5%的体系中加入质量分数为0. 4%的Na4EDTA(最佳质量分数),采收率提高了3. 1%。     

介孔SBA-15棒负载的Pd3Cl催化剂催化Sonogashira偶联反应（英文）

通过静电吸引策略将具有高度分散性的原子精确纳米团簇[Pd3Cl(PPh2)2(PPh3)3]+(Pd3Cl)负载在介孔SBA-15棒上。结构明确的Pd3Cl/SBA-15催化剂在以水作为溶剂以及温和的反应条件下对催化Sonogashira碳-碳偶联反应展现了较好的催化性能以及循环性。在此基础上,我们研究了Pd3Cl团簇结构与性能之间的关系,并证实内核的Pdδ+(0<δ<2)与配体之间的协同效应是催化反应的关键。     

煤粉与煤焦燃烧时颗粒物的生成特性研究

在实验室沉降炉中进行煤粉热解制焦、煤焦燃烧及煤粉燃烧实验,研究了煤焦燃烧过程对颗粒物生成的影响.研究发现,煤焦燃烧生成的PM1和PM10浓度均低于煤粉燃烧时,说明热解制焦过程对PM1和PM10生成的影响很大;随着温度由1073 K升至1573 K,煤焦燃烧生成PM1浓度与煤粉燃烧生成PM1浓度之比减小,而PM1-10之...     

光纤环形外腔半导体激光器频偏特性研究

本文给出了在环形光纤外腔光反馈之下半导体激光器频偏特性的小信号分析理论.分析表明,尤其在千兆赫以下的调制频段中,耦合腔相移、内外腔光耦合强度及内外腔光场相位失谐对频偏功率比均有显著影响.可望用作强度调制直接检测高速率、长距离光纤通信系统中的光源.     

UNIFORM GROOVE-DEPTH RAC BY USING TRANSDUCER WEIGHTING

A new weighting method,transducer weighting.for the uniform groove-deph RAC is proposed in thispaper.The weighted input and output transducersform a weighting transversal filter In addition,the groove-width weighting,which can be used as an auxiliary is also discussed. By using the new methods,two uniform groove depth RACs have been designed and fabricated,Thesidelobe suppressions achieved are 31 dB and 32 dB.respectively.The results are considered satisfactorybecause the phase compensation by metal strip was not applied.     

Ronchi光栅光密度的一种测试方法

本文提出利用衍射光栅的反射特性,在自光图像处理系统中对光栅进行实时无损伤检验.这种方法灵敏度高、简便易行,有较高的实用价值.理论与实验结果一致.