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1.
介绍一种利用二乙基二硫代氨基甲酸钠分离后以EDTA滴定测定矿石中铝的新方法。锰矿样品用Na OH,Na_3PO_4和Na_2O_2混合熔剂熔融,消除Ca,Mg,Ti的干扰,用含无水乙醇的热水浸取,其中的Mn变为Mn O2沉淀析出,干过滤,定容。将滤液中和至弱酸性,加入二乙基二硫代氨基甲酸钠,一些金属阳离子形成难溶水的络合物而分离,再次过滤,一定量的滤液与过量的EDTA标准溶液反应,用锌标准溶液滴定剩余的EDTA,即得氧化铝的含量。该法采用二甲酚橙为指示剂,同时加入少量氯化十六烷基吡啶,滴定终点颜色突变明显,改善了测量精密度,操作易于掌握。样品测定结果的相对标准偏差为0.42%~1.08%(n=5),加标回收率为97.39%~99.94%。分析过程只需滴定一次,且不使用含铅、铜、氟溶液,方法便捷环保。 相似文献
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Ruoyu Hong * Jianmin Ding Guoliang Zheng College of Chemistry Chemical Engineering Soochow University Suzhou P. R. China Institute of Process Engineering Chinese Academy of Sciences Beijing P. R. China IBM HYDA/- C Highway North Rochester MN USA *Author to whom correspondence should be addressed. E-mail: rhong@suda.edu.cn 《中国颗粒学报》2004,2(5):207-214
1. Introduction1.1 Silica nanoparticles and synthesis methods Silica (SiO2) nanoparticles are widely used in industry asan active filler for polymer reinforcement, a rheologicaladditive in fluids, a free flow agent in powders, and anagent for chemical mechanical polishing during IC (inte-grated circuit) fabrication (Sniegowski & de Boer, 2000).Silica powder is also used for producing silicon carbide(Koc & Cattamanchi, 1998) or opaque silica aerosols (Leeet al., 1995). Many methods can … 相似文献
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The effects of PEA on the γ-phase PVDF crystal structure and the crystallization of PEA within the pre-existing γ-phase PVDF spherulites have been investigated by optical microscopy(OM), infrared spectroscopy(IR) and scanning electron microscopy(SEM). The results demonstrate that the γ-phase PVDF spherulites consist of the lamellae exhibiting a highly curved scroll-like morphology and develop preferentially in PEA-rich blend. With increasing PEA concentration, the scroll diameter increases and the scrolls are better separated from each other. PEA crystallizes first in the interspherulitic region and transcrystalline layer develops. Subsequently, the transcrystalline layer of PEA continues to grow within the γ-phase PVDF spherulites, e.g., in the region between the scrolls, until impinging on other PEA transcrystalline layers or spherulites. The crystallization kinetics results indicate that the growth rate of PEA crystals in the intraspherulitic region of γ-phase PVDF shows a positive correlation with content of PEA, but a negative one with the crystallization temperature of γ-phase PVDF. 相似文献
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研究了 OFDMA 中继下行链路通信系统中的动态资源分配问题,提出了一种可以保证用户最低 QoS 需求的资源分配算法.首先在简化资源优化问题的过程中,采用等功率分配方法以降低算法复杂度,然后通过拉格朗日松弛优化方法推导出了子载波分配和中继选择最优解,并在此基础上引入用户速率权衡因子,根据速率权衡因子越大的用户,越具有选择子载波和中继的优先权这一准则进行子载波分配和中继选择.仿真结果表明:新算法能够获得较高的系统容量,同时也能很好地保证不同用户的最低速率需求. 相似文献
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LIU KaiQiang PENG JunXia XUE Min YAN Ni LIU Jing & FANG Yu* Key Laboratory of Applied Surface Colloid Chemistry Ministry of Education School of Chemistry Materials Science Shaanxi Normal University Xi’an China 《中国科学B辑(英文版)》2011,(3)
Five new diacid amides of di-cholesteryl L-glycinates were designed and prepared.The compounds with linkers containing 0,1, 2,3,or 4 methylene units are denoted as 1,2,3,4,and 5,respectively.Their gelation behaviors in 25 solvents were tested as novel low-molecular-mass organic gelators(LMOGs).It was shown that the length of the linker connecting the two-cholesteryl residues in a gelator plays a crucial role in the gelation behavior of the compound.1 gels 11 of the 25 solvents tested at a concentration lowe... 相似文献
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Hong Zhu * Patrick Phelan Tianhua Duan Gregory Raupp H. J. S. Fernando Beijing Institute of Microbiology Epidemiology Beijing P. R. China Department of Mechanical Aerospace Engineering Arizona State University Tempe Department of Chemical Materials Engineering Arizona State University Tempe *Author to whom correspondence should be addressed. Tel: -- E-mail: zhuhong@hotmail.com 《中国颗粒学报》2003,1(3):119-123
1.IntroductionBioaerosolsaremicroorganismsorparticles,gases,vapors,orfragmentsofbiologicalorigin(i.e.,aliveorreleasedfromalivingorganism)thatexistintheair.Bioaerosolsareeverywhereintheenvironment.Underfavorableconditions,bioaerosolsareabletogrowandpropagateonavarietyofbuildingmaterialsandindoorsurfaces,causingindoorairpollution.Therefore,owingtotheirubiquitouspresenceinnature,bioaerosolsasapollutionsourcearealmostinevitableinarangeofenclosedenvironmentsandincommunityair(Kodama&McGee,1986;Lig… 相似文献
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