Analysis of nano channel formation in quartz cubes by laser-induced process

A novel laser processing technique was developed for making channels in the nano regime in this paper. A Nd:YAG laser was used to dry fabricate micro channels (25μm～100μm di ameter) in a 1 cm^3 fused silica substrate by thermal-induced processing. By controlling the locations of these initiating micro channels on a silica cube, 1D-controllable self-connecting nano fractures can be formed as rectangular channels. These nano channels are smooth and with extremely high aspect ratio (～10^4 depth to width ratio). A possible mechanism is proposed to explain the formation of the nano channels. This laser-based nano channel fabrication technique is fast and inexpensive, and with potential applications in capillary electrophoresis and electro-osmosis driven nano-filtration.     

气相中HRnCCH和X(X=H_2O,NH_3)反应机理的理论研究

在CCSD(T)//MP2/aug-cc-pVTZ-pp理论水平上,研究了HRnCCH与大气中H2O及NH3分子反应的机理,反应主要包括HRnCCH与HRnOH及HRnNH2之间的转化、H2O和NH3在HRnCCH中的碳碳三键上的加成反应以及HRnCCH与双分子水反应等.结果表明,HRnCCH与H2O反应生成HCCH和HRnOH及HRnCCH与NH3反应生成HCCH和HRnNH2的能垒分别为54.1和75.2 kJ/mol,而生成HRnCHC(OH)H,HRnC(OH)CH2,HRnCHC(NH2)H和HRnC(NH2)CH2的活化能分别为219.6,220.5,174.4和182.4kJ/mol,此结果表明HRnCCH反应性较弱且是稳态存在的.此外,在HRnCCH与H2O反应中加入单个水分子,仍然生成HRnCHC(OH)H,但反应活化能却降低了96.4 kJ/mol,说明水分子对该反应有明显的催化作用.     

Classical mechanics in non-commutative phase space

In this paper the laws of motion of classical particles have been investigated in a non-commutative phase space. The corresponding non-commutative relations contain not only spatial non-commutativity but also momentum non-commutativity. First, new Poisson brackets have been defined in non-commutative phase space. They contain corrections due to the non-commutativity of coordinates and momenta. On the basis of this new Poisson brackets, a new modified second law of Newton has been obtained. For two cases, the free particle and the harmonic oscillator, the equations of motion are derived on basis of the modified second law of Newton and the linear transformation (Phys. Rev. D, 2005, 72: 025010). The consistency between both methods is demonstrated. It is shown that a free particle in commutative space is not a free particle with zero-acceleration in the non-commutative phase space, but it remains a free particle with zero-acceleration in non-commutative space if only the coordinates are non-commutative.     

具有Manning-Rosen标量势与矢量势的Klein-Gordon方程的任意l波束缚态近似解析解

在球坐标系中研究了具有离心项的Manning-Rosen型标量势与矢量势的Klein-Gordon方程.在标量势等于矢量势的条件下，运用合适的指数近似将具有离心项的径向Klein-Gordon方程转化成超几何微分方程，从而获得了系统的任意l波Klein-Gordon方程解析束缚态径向波函数.最后，对l=0和α=0或1两种特殊情况进行了简单讨论. 关键词： Manning-Rosen势 Klein-Gordon方程 束缚态 近似解析解     

具有Manning-Rosen标量势与矢量势的Klein-Gordon方程的任意l波束缚态近似解析解

在球坐标系中研究了具有离心项的Manning-Rosen型标量势与矢量势的Klein-Gordon方程.在标量势等于矢量势的条件下,运用合适的指数近似将具有离心项的径向Klein-Gordon方程转化成超几何微分方程,从而获得了系统的任意l波Klein-Gordon方程解析束缚态径向波函数.最后,对l=0和α=0或1两种特殊情况进行了简单讨论.     

激光沉积法制备（Y1—xHox）Ba2Cu3O7—δ薄膜

本文报道了用激光沉积法在（１００）ＬａＡｌＯ３衬底上制备（Ｙ１－ｘＨｏｘ）Ｂａ２Ｃｕ３Ｏ７－δ（ｘ＝０，０．２，０．４）超导薄膜．结果表明，新超导薄膜表面光滑，具有很强的ｃ轴织构，零电阻温度Ｔｃ０约９１Ｋ，最佳临界电流密度Ｊｃ为４．７×１０６Ａ／ｃｍ２（７７Ｋ）．     

Stimulated photoluminescence emission and trap states in Si/SiO2 interface formed by irradiation of laser

Stimulated photoluminescence （PL） emission has been observed from an oxide structure of silicon when optically excited by a radiation of 514nm laser. Sharp twin peaks at 694 and 692nm are dominated by stimulated emission, which can be demonstrated by its threshold behaviour and linear transition of emission intensity as a function of pump power. The oxide structure is formed by laser irradiation on silicon and its annealing treatment. A model for explaining the stimulated emission is proposed, in which the trap states of the interface between an oxide of silicon and porous nanocrystal play an important role.     

低温退火形成团簇CdSe棒状结构的实验分析

为了研究新型纳米结构对发光的影响，实验采用自组装的方法在低温（170℃）退火的条件下成功制备了棒状CdSe微结构阵列，并使用中心波长为365 nm的激光测量了棒状CdSe微结构阵列的荧光光谱。本文首先论述了团簇CdSe半导体材料的特性以及其荧光性质，然后通过对退火后的棒状CdSe微结构阵列的荧光测量，分析实验结果表明：棒状CdSe微结构的长度、直径和阵列间距分别为505.91 nm、205 nm和309 nm，荧光光谱出现36.16 nm蓝移。而且，按照非平衡态统计物理系统中，基于低温退火对半导体材料产生的影响，通过一维福克-普朗克方程对其形成机理进行了实验分析。这种低温退火方法为未来在新材料制备上提供了一个新的途径。     

激光加工过程中激光诱导等离子体的动态过程研究

本文利用高速摄影机对激光加工过程中伴随产生的等离子体在室温大气压下的动态过程进行监测研究.对等离子体持续过程及其随时间的变化进行实验分析,提出等离子体在通道内突然消失的可能机制,并为进一步控制等离子体的形成提供了实验基础.     

激光加工过程中激光诱导等离子体的动态过程研究

本文利用高速摄影机对激光加工过程中伴随产生的等离子体在室温大气压下的动态过程进行监测研究．对等离子体持续过程及其随时间的变化进行实验分析，提出等离子体在通道内突然消失的可能机制，并为进一步控制等离子体的形成提供了实验基础。