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采用共振拉曼光谱和完全活化空间自洽场方法研究了N,N-二甲基硫代乙酰胺在被激发至S3(ππ*)态后的衰减动力学. 指认了紫外吸收光谱和振动光谱. 获得了乙腈、甲醇和水溶剂中不同激发波长下的A带共振拉曼光谱,以探测Franck-Condon区域的结构动力学. 开展了CASSCF计算以确定低能单重激发态和锥形交叉点的电子激发能和优化几何结构. 通过共振拉曼强度分析和CASSCF计算获得了结构参数、A带结构动力学和S3(ππ*)态衰减机制. 提出了主要衰减通道为3,FC(ππ*)→S3(ππ*)/S1(nπ*)→1(nπ*). 相似文献
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DMD光栅的衍射特性及其在可调谐激光中的应用 总被引:1,自引:0,他引:1
相比较于液晶空间光调制器,数字微镜晶片(DMD)具有开关速度快、显示精度高、偏振不相关、衍射效率高和宽带调制等优势。研究利用DMD的衍射效应作为波长选择器,将其应用于可调谐光纤激光器中,理论推导这种二维DMD光栅的衍射效率与入射光角度,像素间距等物理量之间的定量关系,重点讨论了两种不同像素间距的0.7″和0.55″DMD在单像素因子和多像素干涉共同作用下的衍射级数和强度分布。研究结果表明:0.7″DMD在光强不显著为零且满足实验约束条件下,允许出现4个干涉极大值,但由于极大值位置均远离闪耀条件,因此光强相对较弱。0.55″DMD仅出现1个干涉极大值,且接近闪耀条件,因此光强和效率均明显高于0.7″DMD的情况。由此可见,在可调谐光纤激光器中,利用0.55″DMD光栅作为波长选择器更有利于减小衍射损耗,提高系统稳定性。 相似文献
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The disorder effect on the performance of novel waveguides constructed in two-dimensional amorphous photonic materials 下载免费PDF全文
On the basis of two-dimensional amorphous photonic materials,we have designed a novel waveguide by inserting thinner cylindrical inclusions in the centre of basic hexagonal units of the amorphous structure along a given path.This waveguide in amorphous structure is similar to the coupled resonator optical waveguides in periodic photonic crystals.The transmission of this waveguide for S-polarized waves is investigated by a multiple-scattering method.Compared with the conventional waveguide by removing a line of cells from amorphous photonic materials,the guiding properties of this waveguide,including the transmissivity and bandwidth,are improved significantly.Then we study the effect of various types of positional disorder on the functionality of this device.Our results show that the waveguide performance is quite sensitive to the disorder located on the boundary layer of the waveguide,but robust against the disorder in the other area in amorphous structure except the waveguide border.This disorder effect in amorphous photonic materials is similar to the case in periodic photonic crystals. 相似文献
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Tunable microwave signal generation based on an Opto-DMD processor and a photonic crystal fiber 下载免费PDF全文
Frequency-tunable microwave signal generation is proposed and experimentally demonstrated with a dual-wavelength single-longitudinal-mode (SLM) erbium-doped fiber ring laser based on a digital Opto-DMD processor and four-wave mixing (FWM) in a high-nonlinear photonic crystal fiber (PCF). The high-nonlinear PCF is employed for the generation of the FWM to obtain stable and uniform dual-wavelength oscillation. Two different short passive sub-ring cavities in the main ring cavity serve as mode filters to make SLM lasing. The two lasing wavelengths are electronically selected by loading different gratings on the Opto-DMD processor controlled with a computer. The wavelength spacing can be smartly adjusted from 0.165 nm to 1.08 nm within a tuning accuracy of 0.055 nm. Two microwave signals at 17.23 GHz and 27.47 GHz are achieved. The stability of the microwave signal is discussed. The system has the ability to generate a 137.36-GHz photonic millimeter signal at room temperature. 相似文献
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Experimental investigation of the impact on nearby solid boundary during laser-generated bubble collapse 下载免费PDF全文
Cavitation damage has been considered as being responsible for many effects in hydraulic machinery and biological medicine. In order to better understand the cavity interaction with nearby solid surfaces, the impact loading induced by the high-speed liquid-jet and subsequent jet flow during the final stage of the bubble collapse in a static fluid is investigated by focusing a Q-switched pulsed laser into water. By means of a new method based on a fibre-coupling optical beam deflection technique, a detailed experimental study has been made to clarify the relationship of the impact pressure against a solid boundary as a function of the dimensionless γ that is generally used to describe the bubble dynamics with its definition γ= s/R_{max}(R_{max} being the maximum bubble radius and s denoting the distance of the cavity inception from the boundary). The experimental results are shown that for γ in the range of about 0.67 to 0.95 with a pulsed laser energy 230mJ, the transient pressure applied on the solid surface is maximum; while for γ>1 or γ<0.67, it is gradually decreased. By combination of our experimental results with the other work that detected the acoustic emission during the bubble collapse at different γ, it is concluded that in this range of 0.67-0.95, the destructive effect due to a liquid-jet and the following jet flow impact actually outweighs the well-known effect of shock wave emission and plays a vital role during the cavitation bubble collapse. 相似文献