替代M-型钡铁氧体纳米粒子的微波吸收性能

The microwave-absorbing behavior of substituted M-type barium ferrite nano-particles was investigated. The nano-particles were synthesized with coprecipitation-melted salt method. For the purpose of comparison, corre-sponding micro-particles were also prepared through direct coprecipitation and sintering. XRD and TEM of the nano-particles showed that the ferrite was hexagonal in structure and widely distributed in size with particle size being less than 100nm, the complex permittivity and permeability of a 1.50mm thick specimen and a 1.40mm thick specimen containing 60% by weight of substituted M-type barium ferrite nano-particles and micro-particles were measured respectively in X band (8.2～12.4GHz) range, from which the reflection loss (R.L.) of microwaves was calculated and two comparative absorption curves were given. The results showed that the synthetic nano-particles could well absorb microwaves in X band. The absorption was larger than 10dB in the range of 9.2～12.4GHz while the maximum absorption was 38.6dB at 10.6GHz.     

Kinetic calculation for the reaction of H with Si_2H_6 using the variational transition state theory

The reaction of disilane with atomic hydrogen has been studied. This reaction involves both substitution and abstraction. Calculations show that the hydrogen abstraction is the strongest competing channel. The canonical variational transition state theory with a small curvature tunneling correction (SCT) has been used for the kinetic calculation. The theoretical results are in good agreement with the available experimental data. Comparing the reactions of atomic hydrogen with disilane and silane, it can be seen that the reactivity of the Si-H bond is higher in Si2H6than that in SiH4.     

二氧化硅改性片状铁粒子的微波吸收性能

The preparation and microwave-absorbing behavior of micrometric silica-modified platelet iron particles (SMPLIP) were investigated. Through precipitation， hydrothermal reaction， silica-modification and reduction with hydrogen， micrometric porous SMPLIP were yielded. The permittivity values of SMPLIP had been significantly decreased due to the presence of silica. Measurements and calculations showed that a 1.93mm thick sample containing SMPLIP as much as 60% by weight was capable of absorbing X band(8.2～12.4GHz) microwaves with reflection loss being greater than -10dB within the frequency range of 8.2～11.36GHz， while the maximum re-flection loss was -14.8dB at 9.4GHz. The results had also shown that it was practicable to prepare thin， light-weight microwave absorbent with SMPLIP.     

用变分过渡态理论对CH3SiH3+O反应体系的动力学研究

用变分过渡态理论对ＣＨ３ＳｉＨ３与氧原子Ｏ的抽提反应进行了理论研究。利用从头算计算了反应体系的构型、振动频率和能量等信息,分析了此反应的反应机理;在２９８～１０００Ｋ计算了主要反应通道的速率常数。结果表明,在低温下,变分对于此反应影响较大,隧道效应较明显;计算得到的室温速率常数和实验符合很好。     

用变分过渡态理论对CH3SiH3+O反应体系的动力学研究

用变分过渡态理论对CH3SiH3与氧原子O的抽提反应进行了理论研究。利用从头算计算了反应体系的构型、振动频率和能量等信息,分析了此反应的反应机理;在298～1000 K计算了主要反应通道的速率常数。结果表明,在低温下,变分对于此反应影响较大,隧道效应较明显;计算得到的室温速率常数和实验符合很好。     

聚硅氮烷包敷纳米铁磁粉PSZFe的合成及其雷达波吸收性能研究

金属磁性材料是一类很重要的雷达波吸收材料 ,而纳米铁磁粉是其中的姣姣者 ,具有质量轻、居里温度高、磁化强度高 (可以是铁氧体磁性材料的 2～ 3倍 ) [1,2 ] 、矫顽力大、雷达波吸收性能好和频带宽等优点[3 ] ;但由于其颗粒太细 ,暴露在空气中即被强烈氧化 ,实际应用很困难 ,对其进行包敷处理是一种很有效的抗氧化腐蚀方法 .聚硅氮烷(PSZ)做为纳米铁磁粉包敷层有很多优点 :包敷层所要求的化学和力学性能可以通过调整氯硅烷单体的比例以及反应条件而实现[4] ;包敷层具有高致密性、高疏水性 ,从而使潮气、水和氧气很难侵入 ;包敷层耐热性好…     

多晶铁纤维的合成与微波吸收性能的研究

The preparation and microwave-absorbing behavior of polycrystalline iron fibers modified with the thermal decomposition of carbonyl iron were studied in this paper. Through preparation of α-FeOOH fiber precursor, dehydration, reduction with hydrogen, modification with the thermal decomposition of carbonyl iron and passivation, polycrystalline iron fibers were yielded. α-FeOOH fiber precusor with optimum diameter and aspect ratio was made by using uniform seed crystal with optimum concentration and controlling the reaction time. Lacunas from procedure of dehydration and reduction were well modified with carbonyl iron. The sample with 1.95 mm thickness containting 60 % by weight of modified polycrystalline iron fibers showed reflection loss over 10 dB within the frequency range of 8.5～14.6 GHz, and the maximum reflection loss was 21.8 dB at 11.3GHz, while the sample of nonmodified polycrystalline iron fiber showed less reflection loss under same conditions.