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The title compound [2-(2,6-dioxacyclohexyl)-5-methoxylphenols]2 was synthesized by the reaction of 2-hydroxyl-3-methoxylbenzaldehyde and 1,3-propanediol in the presence of DMF-DMS adduct and characterized by IR spectrum, UV-Vis spectrum and X-ray crystallography. The title compound belongs to monoclinic, space group P21 with a = 9.8967(10), b = 8.2240(9), c = 13.3654(14) A^°, β= 90.016(2)°, C11H14O4, Mr = 210.22, V = 1087.8(2)A^°3, Z = 4, Dc = 1.284 Mg/m^3, F(000) = 448,μ = 0.098 mm^-1, the final R = 0.0300 and wR = 0.0761 for 2070 observed reflections with I 〉 2σ(I). The molecules are connected via intermolecular O-H…O hydrogen bonds into a 2D network structure. Moreover, theoretical investigations of the title compound with HF/6-31G(d) method were performed, and its stability, frontier molecular orbital composition and Mulliken charge distribution were also discussed. The compound is a bis-molecule. The two molecules stay together and could not be separated. Two crystallographically independent molecules exist in an asymmetric unit. The bond lengths and bond angles of the two molecules are slightly different with each other. 相似文献
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The transmission properties of quasiperiodic photonic crystals (QPCs) based on the random square-triangle tiling system are investigated by the multiple scattering method. The hollow cylinders are introduced in our calculation. It is found that QPCs with hollow cylinders also possess a complete band gap common to s- and p-polarized waves when the inner radius of hollow cylinders is larger than a certain value. The QPCs possessing the complete band gap can be applied to the fields of light emitting, wave-guides, optical filters, high-Q resonators and antennas. 相似文献
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Negative Refraction and Near-Field Imaging of an Elliptical-Rod Photonic Crystal Slab in the Second Band 下载免费PDF全文
Negative refraction and imaging properties of the electromagnetic wave through a two-dimensional photonic crystal (PC) slab, which consists of a square lattice of elliptical dielectric rods immersed in the air background, is studied by the plane-wave expansion method and the finite-difference time-domain method. A point source placed in the vicinity of the PC slab can form a good-quality image spot through the PC slab for the incident frequencies within the second photonic band. The calculated result also shows that negative refraction occurs in this kind of PC slab. 相似文献
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A highly efficient W3 Y-branch filter in a two-dimensional photonic crystal slab with triangular lattice of air holes is designed and fabricated, and its transmission properties are measured. By accurately adjusting the size of the resonant cavities, the minimum wavelength spacing of 7 nm between two channels is realized. The corresponding resonant wavelengths of the two cavities agree well with the calculated ones. This implies that this kind of fiIter may be promising in integrated wavelength division multiplexing system. 相似文献
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二维正方晶格光子晶体平板的近场成像特性 总被引:1,自引:1,他引:0
光子晶体是由两种或两种以卜不同介电函数的材料周期性排列组成的一种人工晶体.由于介电甬数的周期性分布对入射光的调制作用,使得特定频率区域的人射光在光子晶体中传播时的群速度方向和相速度方向相反,因而使得光子晶体平板表现出负折射特性.系统研究了介质柱的形状对二维正方品格光子品体近场成像特性的影响.通过对分别由正方形、三角形、椭网形、长方形等形状介质柱组成的二维正方品格光子晶体平板近场成像特性的理论分析,发现当介质柱形状的对称性降低到一定程度后可以实现光子晶体近场成像的纵向平移.进一步通过对相应等频率曲线形状的分析,明确了光子晶体近场成像是由于自准直效应和负折射效应的共同作用形成的. 相似文献
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