黄光类水滑石的制备、表面改性及应用

采用共沉淀法合成了荧光类水滑石材料,该材料在470 nm蓝光激发下可发出黄色荧光(557 nm),采用硅烷偶联剂对其进行表面改性,探讨了表面改性对黄光类水滑石的发光性能、结构及热稳定性的影响。将改性黄光类水滑石与GaN基蓝光芯片封装后制得了白光LED。研究结果表明,改性的黄光类水滑石是制作白光LED可供选用的黄色发光材料。本文成功地将低温一步法制备得到的金属有机配合物/无机纳米杂化材料应用于LED,拓展了LED用荧光粉的选用范围。     

瀑布沟水电站库首右岸深部裂缝成因分析

水电工程常常建在高山峡谷地带,其天然岸坡通常由坡面向内有一个强卸荷带和弱卸荷带以及相应的强风化和弱风化带,内侧则为完整新鲜的岩石。对涉及的工程岸坡在正常卸荷带以内发育的一系列张性破裂或破裂带,称之为“深拉裂缝”。瀑布沟水电站库首右岸存在两个拉裂变形体,通过对其岸坡深部拉裂缝空间发育分布、变形特征的考察,综合分析造成深部裂缝发育规律与变形特征的因素。在此基础上提出,库首右岸深部拉裂缝是岸坡快速卸荷条件下浅表生改造的产物,其形成时期相当于河谷由宽谷深切为峡谷这一转换时期。     

一种新型黄色荧光类水滑石材料的制备及表征

用适量的Zn(Ⅱ)取代镁铝水滑石中的Mg(Ⅱ),同时将一定量的2-对联苯基-8-羟基喹啉分散到类水滑石层间的亲油性阴离子中,使其与层板表面上的Zn(Ⅱ)配位,用一步法合成、组装得到一类新型黄色荧光类水滑石复合物(Zn-(HQ-4-biPh)-HTlc)。采用荧光光谱、红外光谱、X射线衍射、扫描电子显微镜和热分析等对其进行了表征。研究结果表明,Zn-(HQ-4-biPh)-HTlc在蓝光(481 nm)激发下可发出黄色荧光(554 nm),与其相应的含锌配合物(Zn[2-(p-biph)-8-Q-O]2)相比,不仅可节省配体用量,而且具有更高的发光强度和更好的热稳定性,有望在白光LED等光电领域得到应用。     

Efficient and stable wireless power transfer based on the non-Hermitian physics

As one of the most attractive non-radiative power transfer mechanisms without cables,efficient magnetic resonance wireless power transfer(WPT)in the near field has been extensively developed in recent years,and promoted a variety of practical applications,such as mobile phones,medical implant devices and electric vehicles.However,the physical mechanism behind some key limitations of the resonance WPT,such as frequency splitting and size-dependent efficiency,is not very clear under the widely used circuit model.Here,we review the recently developed efficient and stable resonance WPT based on non-Hermitian physics,which starts from a completely different avenue(utilizing loss and gain)to introduce novel functionalities to the resonance WPT.From the perspective of non-Hermitian photonics,the coherent and incoherent effects compete and coexist in the WPT system,and the weak stable of energy transfer mainly comes from the broken phase associated with the phase transition of parity-time symmetry.Based on this basic physical framework,some optimization schemes are proposed,including using nonlinear effect,using bound states in the continuum,or resorting to the system with high-order parity-time symmetry.Moreover,the combination of non-Hermitian physics and topological photonics in multi-coil system also provides a versatile platform for long-range robust WPT with topological protection.Therefore,the non-Hermitian physics can not only exactly predict the main results of current WPT systems,but also provide new ways to solve the difficulties of previous designs.     

A Photonic Bandgap Filter Using Metallic Hilbert Curves

We theoretically suggest that a metallic plate with Hilbert curves can possesses multiple resonances in a linear scale, leading to multiple stop bands and pass bands for electromagnetic waves over a wide frequency range.The forward transmission from a line source nearby a small plate covered by four cells with Hilbert curves is checked by a probe at the far field, the results agree well with the multiple resonance frequencies calculated by the plane wave incidence under a periodic boundary condition, the return loss spectra show that radiations of a line antenna working at 4.5 GHz can be greatly enhanced, which results from the interaction of the antenna and the subwavelength metallic plate. This kind of metallic pattern is very practical in multi-frequency functioned wave devices with sub-wavelength sizes.     

光子晶体耦合腔波导的色散特性

理论研究表明，在基于光子晶体的耦合腔波导中，杂质带的色散性质取决于相邻缺陷间局域电磁场的特性，而非缺陷间距离的大小.在第一布里渊区中出现的杂质带的反常色散实际上是能带折叠的结果.通过计算结构的有效折射率，证实了杂质带色散是正常色散. 关键词： 光子晶体 反常色散 耦合腔 杂质带     

利用集总L-C元件构造的一维metamaterials特性的实验研究

在普通微带传输线中周期性地加载集总L C元件能够构造一维特异性材料(metamaterials)，它具有与众不同的特异性质.通过实验证实了波在这种结构中传播具有相速度与群速度方向相反的左手性通带，其折射率为负值，并发现平均折射率为零的能隙.这种结构具有结构紧凑，参数可调，制作简单的优点. 关键词： 负折射率 特异性材料 周期性结构 微带线     

双能带三维光子晶体中二能级原子的自发辐射

研究了双能带三维光子晶体中二能级原子自发辐射的性质.由于双能带各向异性色散关系的影响，辐射场中的局域场和传输场不能共存，导致原子上能级占据数不再具有准周期性振荡的性质，而是随时间趋于常数，或者随时间按幂函数形式衰减，或者随时间按指数形式衰减.这些性质不仅与原子上能级和能带带边的相对位置有关，而且与光子晶体上、下能带之间的能隙宽度有关.这些性质也有别于单能带各向同性光子晶体中二能级原子自发辐射的性质. 关键词： 光子晶体 二能级原子 自发辐射     

一类新型高荧光性类水滑石（Al-HTLc）的合成与性能

采用共沉淀法,合成、组装得到一类将铝离子（Al^3＋）量减少到一定值的镁铝型类水滑石,并使分散于其镁铝水滑石板层上的铝离子与板层间溶于亲油性阴离子中的计量8-羟基喹啉（8-HQ）配位,获得一类新型高荧光性类水滑石（Al-HTLc）．采用荧光光谱、红外光谱、紫外光谱、XRD、XPS和热分析等对其进行了表征．研究结果表明,该Al-HTLc在紫外光下可发出荧光强度高达4．9×10^5（a．u.）的强烈蓝绿色荧光（487nm）,荧光寿命为21．24ns,光量子产率为67％,高于纯8-羟基喹啉铝（Alq3）,且具有更高热稳定性,有望作为一类高性能的新型荧光材料而获得应用．