铯-铷-钒系低温硫酸催化剂的研制

Cs Rb V catalyst for H 2SO 4 production at low temperature was prepared by use of metallurgical waste liquid (MWL) containing alkali metal salts. The result showed that X (SO 2)=24 8% on the catalyst prepared directly with MWL can be reached at 410 ℃, and if n (Na)/ n (V) has been adjusted properly, X (SO 2) can be increased to 35 6% at the same tempertaure. When MWL has been refined and mixed with other liquid material, it can make the catalyst activity at low temperature even higher. From the DTA result of the catalyst prepared from the refined liquid, it is found that both the endothermic apices and exothermic apices shift to low temperature obviously, indicating that the catalyst possesses higher activity at low temperature.     

苯乙烯喹啉衍生物的合成及其光谱性质

报道了一种苯乙烯基喹啉衍生物的合成新方法。将10 mmol苯胺溶于10 mL 6 mol·L-1盐酸中,加热至100 ℃,搅拌下缓慢滴加丁烯醛(20 mmol)的甲苯溶液8 mL,100 ℃反应3 h生成中间体2-甲基喹啉;2-甲基喹啉(10 mmol)再同芳香醛(12 mmol)衍生物在冰醋酸(15 mL)中回流8 h合成八个苯乙烯喹啉衍生物,产率71%～88%,该方法操作简便、便于纯化、产率较高、环境友好。合成的衍生物进行MS,1HNMR,IR结构表征,红外图谱在960～980 cm-1间出现中等强度的吸收峰,核磁图谱中烯碳上氢的邻位偶合常数在12～18 Hz之间,表明结构中的碳碳双键为反式构型。测定了八个衍生物在CH₃OH,DMSO,THF和DMF等四种溶剂中的最大吸收波长,将最大吸收波长作激发波长,测定了其发射波长。结果表明：苯乙烯喹啉衍生物的最大吸收波长为325～376 nm,发射波长为367～477 nm,摩尔消光系数为1.738×104～4.578×104 L·mol-1·cm-1。含甲氧基、羟基、苄基的衍生物的最大吸收波长和发射波长大于其他化合物。衍生物在不同溶剂中的最大吸收波长变化微弱,发射波长变化明显,表现为DMSO>DMF>CH₃OH>THF,表明同一种化合物在非质子溶剂中的斯托克斯位移值大于质子溶剂。2-(3,4,5-三甲氧基)苯乙烯基喹啉(化合物Ⅱ)的荧光性质最好,斯托克斯位移值最大,有进一步研究的价值。     

Precision Higgs physics at the CEPC

The discovery of the Higgs boson with its mass around 125 GeV by the ATLAS and CMS Collaborations marked the beginning of a new era in high energy physics.The Higgs boson will be the subject of extensive studies of the ongoing LHC program.At the same time,lepton collider based Higgs factories have been proposed as a possible next step beyond the LHC,with its main goal to precisely measure the properties of the Higgs boson and probe potential new physics associated with the Higgs boson.The Circular Electron Positron Collider(CEPC)is one of such proposed Higgs factories.The CEPC is an e~+e~- circular collider proposed by and to be hosted in China.Located in a tunnel of approximately 100 km in circumference,it will operate at a center-of-mass energy of 240 GeV as the Higgs factory.In this paper,we present the first estimates on the precision of the Higgs boson property measurements achievable at the CEPC and discuss implications of these measurements.     

克服光纤Mach-Zehnder干涉仪信号衰落的新方法及分析

为了克服光纤Mach-Zehnder干涉仪易受环境因素影响而引起偏置相位漂移从而导致输出信号衰落(波动)的问题,提出一种新的简单方法,即:将干涉仪输出信号分为直流和交流两个分量,通过直流分量的大小来计算交流信号的补偿因子,以达到克服交流信号衰落、稳定检测传感信号的目的在小信号测量情况下,该方法在很大范围内能有效抑制随机温度涨落等因素引起的信号衰落的问题文中对补偿方法的误差和局限性也做了分析和讨论.