Application of step-scan FTIR to the research of quantum cascade lasers

Fourier transform infrared (FTIR) spectroscopy has moreadvantages over many other techniques for high resolu-tion studies in the mid-infrared and far-infrared spectralranges. In addition to the high frequency resolution, itexhibits a high signal-to-noise ratio (SNR), high through-put, and broad band range. There are two ways forthe spectrometer to implement the scan process, i.e.,the rapid-scan (continuous-scan) mode and the step-scan mode. Although many relatively simple rapid-scanFTIRs h…     

High-Duty-Cycle Operation of GaAs/AlGaAs Quantum Cascade Laser above Liquid Nitrogen Temperature

We present a detailed study of λ- 9.75 μm GaAs/AlGaAs quantum cascade lasers. For a coated 2-rmm-long and 40-μm-wide laser, an optical power of 85 μ W is observed at 95% duty cycle at 80K. At a moderate driving pulse （1 kHz and 1% duty cycle）,the device presents a peak power more than 20mW even at 120K. At 80K, the fitted result of threshold current densities shows evidence of potential cw operation.     

High-Power and Low-Threshold-Current-Density GaAs/AlGaAs Quantum Cascade Lasers

We report on the realization of GaAs/AlGaAs quantum cascade lasers with an emission wavelength of 9.1 μm above the liquid nitrogen temperature. With optimal current injection window and ridge width of 24 and 60μm respectively, a peak output power more than 500mW is achieved in pulsed mode operation. A low threshold current density Jth = 2.6 kA/cm^2 gives the devices good lasing characteristics. In a drive frequency of i kHz, the laser operates up to 20% duty cycle.     

基于凹面光栅的特定蛋白分析仪结构设计及性能分析

为解决罗兰光栅光谱成像不易直接读取、平面场凹面光栅成像算法复杂等问题,设计了一种基于全息凹面光栅原理的用于特定蛋白分析仪生化检测的分光光度计。该结构以罗兰光栅为基底,采用双透镜作为过渡元件,将罗兰光栅的曲面成像过渡成平场光谱,同时采用光学设计软件Zemax对该结构进行模拟和优化。优化结果表明,分光光度计能够实现光谱平场化,工作波段为320～800 nm,最高分辨率可达0.5 nm,整体分辨率优于1.7 nm,可被光电二极管阵列直接读取,结构特性满足特定蛋白分析仪的测量要求。样机实验结果与模拟结果一致,仪器重复性、准确度、稳定性及线性度均达到行业标准。     

基于CdSe/ZnS量子点构建丝裂霉素荧光检测体系的研究

建立了一种基于CdSe/ZnS量子点的快速、高效的检测丝裂霉素的荧光方法。pH=7.4,反应10 min,CdSe/ZnS量子点的荧光随丝裂霉素浓度增加而猝灭,量子点的荧光强度与丝裂霉素的浓度呈良好的线性关系,适用于丝裂霉素浓度1.8~60 μmol/L,且相关系数为0.996,丝裂霉素的检测限为0.11 μmol/L,该方法相对无共存物质的干扰,并证明完全适用于丝裂霉素注射液与尿液中丝裂霉素的测定。     

基于CdSe/ZnS量子点构建多巴胺荧光检测方法的研究

以CdSe/ZnS量子点为荧光探针,基于多巴胺对CdSe/ZnS量子点的荧光猝灭效应,建立了一种可快速测定多巴胺的荧光检测方法。在最优实验条件下(pH7.4,反应时间20min),多巴胺浓度在0.01~0.7μmol/L范围内与CdSe/ZnS量子点的荧光猝灭强度比值呈良好的线性关系(r=0.996),方法检出限为1.6×10-4μmol/L,相对标准偏差为1.2%。与文献报道的方法相比,该方法的检出限更低,更为灵敏,可用于多巴胺注射液及人体尿样中多巴胺的快速检测。     

融创新理念于军事后勤化学教学

将创新理念融入化学教学是学科特点,也是时代的要求,更是军队院校改革的要求。在军事后勤专业化学教学中,一是利用PBL教学法培养创新意识,二是融入团队的科研成果和学术前沿,三是利用第二课堂提升学员创新能力,培育具有创新思维和组织能力的后勤专业人才。