A self-powered and sensitive terahertz photodetection based on PdSe2

With the rapid development of terahertz technology, terahertz detectors are expected to play a key role in diverse areas such as homeland security and imaging, materials diagnostics, biology, medical sciences, and communication. Whereas self-powered, rapid response, and room temperature terahertz photodetectors are confronted with huge challenges. Here, we report a novel rapid response and self-powered terahertz photothermoelectronic (PTE) photodetector based on a low-dimensional material: palladium selenide (PdSe₂). An order of magnitude performance enhancement was observed in photodetection based on PdSe₂/graphene heterojunction that resulted from the integration of graphene and enhanced the Seebeck effect. Under 0.1-THz and 0.3-THz irradiations, the device displays a stable and repeatable photoresponse at room temperature without bias. Furthermore, rapid rise (5.0 μs) and decay (5.4 μs) times are recorded under 0.1-THz irradiation. Our results demonstrate the promising prospect of the detector based on PdSe₂ in terms of air-stable, suitable sensitivity and speed, which may have great application in terahertz detection.     

热泵型纯电动客车空调结霜特性实验研究

针对热泵型纯电动客车空调系统在冬季低温高湿环境下,车外换热器易结霜而造成系统制热性能严重衰减的问题,开发了一种带有经济器的补气型纯电动客车热泵空调系统,对车外管翅式换热器结霜特性进行了实验研究。结果表明,当车外换热器完全结霜后,系统制热量和COP均大幅下降。由于采用中压补气技术,系统仍能稳定运行,当车外温度为0、-10、-20℃时,结霜过程中系统制热量分别降低了5、3.2、2.3 kW,COP分别降低了1.1、0.7、0.45,且车外空气相对湿度越大,系统制热性能衰减越严重。     

带经济器的热泵型纯电动客车空调系统结霜特性研究

针对热泵型纯电动客车空调系统在冬季低温供热运行时车外换热器易结霜问题,设计并搭建一套带经济器、有三种不同补气方式的热泵空调系统实验台。通过实验研究并对比分析该系统在不同补气方式下运行时车外微通道平行流换热器的结霜性能,发现车外环境温度为-15℃工况时,在中压补气方式下结霜运行时系统COP、制热量、蒸发温度均明显最高,此时系统可高效运行。     

定曲率螺旋盘管式汽车尾气余热回收装置的性能研究

为研究汽车尾气余热回收装置不同参数对其性能的影响,对汽车尾气余热回收装置定曲率螺旋盘管换热器建立三维仿真模型,研究了雷诺数在4 000～14 000的范围内,定曲率螺旋盘管换热器盘管直径和螺旋直径两个几何参数对阻力和换热性能的影响。结果表明:改变换热器盘管直径,对换热器流动阻力性能影响不大,换热量随着换热器盘管直径的增加而增加;螺旋直径为70 mm时流动阻力增量最大,换热量随着螺旋直径的减小而增大。     

复合材料层合板的低速冲击损伤及其剩余压缩强度研究

本文采用理论和实验方法研究了复合材料层合板的低速冲地及其剩余压缩强度。文中利用有限元方法和能量转换原理计算了层合板受到低速冲击的受载最危险状态，以及此时的应力分布；并用Ｔｓａｉ－Ｗｕ张量准则判断损伤情况，对产生损伤的单元进行相应的刚度折减，且作重复计算直至不产生新的损伤为止；最后，对受冲击的层合板还进行剩余压缩强度计算。在实验中，采用激光全息无损检测法测量了层合板的冲击损伤，并对受冲击的层合板进行     

正交异性板条的渐近分析

本文阐明由三维薄弹性体的渐近分析导出各级精度板壳理论的基本方法。将多尺度分析用于板的内部区域和边界层区域导出应力,应变和位移等物理量的不同的无量纲小厚度参数ε的渐近展开式。与工程的方法不同,推导仅基于ε→0的渐近分析,对板的变形不做任何假定。给出正交异性板的平面应变渐近展开的具体列式,仅有一些常数待定。结果表明,内域解渐近级数的首项正是熟知的Kirchhoff板理论解。本文为内域解和边界层解的渐近匹配,从而正确表述圣维南原理并用以建立各级渐近解的边界条件进而求解的研究做好了准备。     

A corresponding-state approach to quark-cluster matter

The state of super-dense matter is essential for us to understand the nature of pulsars; however, non- perturbative quantum chromodynamics makes it very difficult to make direct calculations of the state of cold matter at realistic baryon number densities inside compact stars. Nevertheless, from an observational point of view, it is conjectured that pulsars could be made up of quark clusters since the strong coupling between quarks might render the quarks to be grouped in clusters. In this paper, we attempt to find an equation of state of condensed quark-cluster matter in a phenomenological way. Supposing that the quark-clusters could be analogized to inert gases, we apply here the corresponding-state approach to derive the equation of state of quark-cluster matter, as was similarly demonstrated for nuclear and neutron-star matter in the 1970s. According to the calculations that we have presented, the quark-cluster stars, which are composed of quark-cluster matter, could have a high maximum mass that is consistent with observations and, in turn, further observations of pulsar mass could also place a constraint on the properties of quark-cluster matter. We will also briefly discuss the melting heat during the solid-liquid phase conversion and its related astrophysical consequences.     

对三氟甲基苯甲酸和2，2′-联吡啶双核铽配合物的合成、晶体结构及发光性质

A new dinuclear complex [Tb₂(BA)₆(2,2′-bipy)₂] (BA=4-(trifluoromethyl)benzoic acid, 2,2′-bipy=2,2′-bipyridine) has been synthesized. The complex was characterized by X-ray single-crystal structure analysis. The complex is a dimer with an inversion center. In the complex, two Tb3+ ions are linked by four carboxylate groups of BA ligands in bridging-bidentate coordination mode. Each Tb³⁺ ion is eight-coordinated with two nitrogen atoms from one 2,2′-bipy molecule, four oxygen atoms from four bridging-bidentate BA ligands and two oxygen atoms from one chelating-bidentate BA ligand. Intermolecular hydrogen bonds are formed in the crystal. The complex exhibits strong green fluorescence under ultraviolet light and the fluorescence spectrum consists of four lines peaking at 489, 545, 584 and 620 nm, which are corresponding to the ⁵D₄→⁷F_j (j=6～3) transitions of Tb³⁺ ion, respectively. CCDC: 727763.     

液相基质中重金属元素激光诱导击穿光谱实验参数的优化

针对混合溶液中重金属元素的激光诱导击穿光谱(LIBS)测量系统,为提高测量系统的检测灵敏度,以提高混合溶液中Ca和Cr金属元素LIBS光谱线强度的信噪比为目标,对LIBS测量系统中的激光脉冲能量、液相样品流速、ICCD门宽、延时等实验参数进行了优化,得到最优化参数激光脉冲能量、样品流速、ICCD门宽、延时分别为35 m J、30 ml/min、1400 ns和2400 ns,为降低LIBS技术应用于混合溶液中痕量重金属元素的检出限提供了实验参数支撑.     

新型超支化聚(芴-co-吡啶并[3,2-b]吡嗪)共聚物的合成与发光性能

合成了新型三溴代的含有吡啶并[3,2-b]吡嗪的化合物,通过Suzuki缩聚反应合成了以吡啶并[3,2-b]吡嗪为核,以9,9-二辛基芴为枝的超支化共聚物.该共聚物在甲苯和四氢呋喃等有机溶剂中具有较好的溶解性能.采用共聚物制备了结构为ITO/PEDOT/polymer/Ca/Al的发光器件,其中基于共聚物PFPQ-2的器件在电流密度为3.8 mA/cm2时得到蓝光发射,最大外量子效率为1.29%,最大亮度为1173 cd/m2,色坐标为(0.16,0.11).