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采用固相反应法, 制备了钙钛矿结构氧化物LaFe1-xCrxO3较宽范围内(x=0.0—0.7)的系列单相样品, 并测量了各样品的X射线衍射谱(XRD)和扩展X射线吸收精细结构(EXAFS)谱. 通过对XRD的分析样品均为钙钛矿结构正交相, 同时晶格常数随着掺杂量x的增加而减小. 通过对EXAFS的分析和研究得到在LaFe1-xCrxO3氧化物中Fe-O键长和Fe-La键长随掺杂浓度x的变化, 发现Fe-La键长发生比较大的变化, 说明La在体系掺杂中对结构的稳定起到重要作用. 相似文献
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Detection of Fe 3d electronic states in the valence band and magnetic properties of Fe-doped ZnO film 下载免费PDF全文
Fe-doped ZnO film has been grown by laser molecular beam epitaxy(L-MBE) and structurally characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM),all of which reveal the high quality of the film.No secondary phase was detected.Resonant photoemission spectroscopy(RPES) with photon energies around the Fe 2p-3d absorption edge is performed to detect the electronic structure in the valence band.A strong resonant effect at a photon energy of 710 eV is observed.Fe3+ is the only valence state of Fe ions in the film and the Fe 3d electronic states are concentrated at binding energies of about 3.8 eV and 7 eV~8 eV.There are no electronic states related to Fe near the Fermi level.Magnetic measurements reveal a typical superparamagnetic property at room temperature.The absence of electronic states related to Fe near the Fermi level and the high quality of the film,with few defects,provide little support to ferromagnetism. 相似文献
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