排序方式: 共有56条查询结果,搜索用时 46 毫秒
1.
采用静电纺丝法制备了聚醚酰亚胺(PEI)纤维膜,通过扫描电子显微镜(SEM)和偏振红外对PEI纤维膜的微观结构进行研究.实验结果显示纺丝液溶剂决定了PEI的可纺性,以N-甲基吡咯烷酮(NMP)为溶剂时,空气湿度显著地影响纺丝过程以及纤维的形态.在相同纺丝工艺条件下,随着纺丝液浓度的增加,所得PEI取向纤维沿辊筒收集方向的排列规整性提高,纤维平均直径由405 nm增加到3.25 μm.PEI纤维膜介电性能的研究表明,取向纤维膜的介电常数很小,最低可达到1.1,其介电损耗也维持在较低的水平,纤维膜的接收方式以及热牵伸处理会对PEI纤维膜的介电性能产生影响. 相似文献
2.
3.
正丙硫基芳氧基硫赶膦酰胺的合成 总被引:3,自引:0,他引:3
正丙硫基硫代膦酸酯类化合物具有较好的生物活性,其杀虫活性和杀螨活性尤为突出,八十年代以来国外已有商品化产品问世[1~3]。新近,美国氰胺公司还推出了一个含正硫基的有机膦酸酯类新品种BAS-301,为广谱型杀线虫剂[4]。唐除痴研究小组报道了各种烷基硫... 相似文献
4.
由于含丙硫基磷酸酯对某些抗性品系昆虫具有良好的生物活性,同时具有高效、低毒的突出优点,近十多年来已引起广泛的重视,近几年来相继出现了一些有推广应用价值的商品化品 相似文献
5.
1 INTRODUCTIONInrecentyears ,triazolo[3,4, b] 1 ,3,4 thiadiazolederivativeshavebeenat tractingmuchattentionfromchemistsandpharmacologistsbecausetheyshowbroadspectraofbiologicalactivities,suchasinsecticidal[1 ] ,antifungal[2 ] ,herbicidal[3] ,an tibacterial[4] ,hypotensiv… 相似文献
6.
利用自组织生长InAs/GaAs量子点的垂直相关排列机制,生长了上下两层用6.5nm GaAs间隔的InAs结构.下层InAs已经成岛,由于应力传递效应,上层InAs由二维生长向三维成岛生长的转变提前发生,临界厚度从1.7ML变成小于1.5ML.透射电子显微镜截面象显示形成上下两层高度差别很大的InAs量子点,但是由于两层量子点之间存在强烈的电子耦合,光致发光谱中只有与包含大量子点的InAs层相对应的一个发光峰. 相似文献
7.
A new surface cleaning method for Si MBE is described in which a very weak Ge beam flux is deposited on the surface for removing the thin passivative layer of SiO2 on the Si subetrate. It has proved that the SiO2 will react with Ge at a relatively low temperature (620℃), and as a result, the oxide layer becomes volatile. Here the high temperature annealing in the conventional Shiraki method is no longer required, and since the oxide layer is removed in ultra high vacuum, only very little carbon contamination may occur. Furthermore, to reduce the excessive Ge on the substrate surface, Ge is deposited at 620℃ and then the sample is annealed at 700℃; the residual Ge atoms on Si substrate can be reduced to less than 0.1 monolay-er (ML). Ge beam treatment turns out to be an effective low-temperature Si surface-cleaning method, especially for the heteroepitaxial growth of GexSi1-x/Si. 相似文献
8.
将湿法工艺合成的β-磷酸钙纳米粒子与左旋聚乳酸(PLLA)的混合溶液通过电纺丝法制成杂化纳米纤维膜,以期制备一种新型纳米纤维骨组织修复材料。采用FT-IR,XRD,TEM,DSC等手段研究了β-磷酸钙(β-TCP)的结构和形态,采用SEM和直径分布探讨了优化PLLA/β-TCP纤维的电纺丝工艺。结果表明:采用湿法合成β-TCP的纳米粒子具有良好的晶型结构,直径在219~328 nm之间;采用双溶剂体系在优化条件下制备的PLLA/β-TCP杂化纳米纤维直径在500~700 nm之间,PLLA/β-TCP界面结合良好,β-TCP起到了增强作用。在湿态条件下,PLLA纤维膜的力学性能有所提高,而PLLA/β-TCP纤维膜的力学性能则呈现下降趋势。 相似文献
9.
采用5,6-二氢-6-烷基(芳基)-2H-吡喃-2,4-二酮和醛进行缩合反应,合成了二[4-羟基-5,6-二氢-6-烷基(芳基)-2H-吡喃-2-酮-3-]烃.其结构经1HNMR和元素分析证实.对反应条件(反应温度、反应时间)进行了探讨.生物活性初步测定表明,该类化合物具有一定的杀菌和抗烟草花叶病毒的活性. 相似文献
10.
Radiative transition in δ-doped GaAs superlattices with and without Al0.1Ga0.9As barriers is investigated by using photoluminescence at low temperatures. The experimental results show that the transition mechanism of δ-doped superlattices is very different from that of ordinary superlattices. Emission intensity of the transition from the electron first excited state to hole states is obviously stronger than that from the electron ground state to hole states due to larger overlap integral between wavefunctions of electrons in the first excited state and hole states. Based on the effective mass theory we have calculated the self-consistent potentials, optical transition matrix elements and photoluminescence spectra for two different samples. By using this model we can explain the main optical characteristics measured. Moreover, after taking into account the bandgap renormalization energy, good agreement between experiment and theory is obtained. 相似文献