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Theoretical Study of Interesting Fine-Structure Splittings Based on a Scenario for Precise Calculations 下载免费PDF全文
Based on the multi-configuration Dirac-Fock self-consistent field method, a scenario has been presented to calculate the fine-structure energy levels of C^2+ and Si^2+ excited states (31 D2 and 33D1,2,3). The Breit interactions and quantum electrodynamics corrections are added as perturbations. The present calculation results are found to be in excellent agreement with the experimental data. By means of the precise calculation procedure, we elucidate that four competitive mechanisms influence the interesting fine-structure splittings in C^2+ and Si^2+, such as spin-orbit interactions, relativistic corrections of exchange interactions, the Breit interactions and electron correlation effects. Furthermore, the mechanism of relativistic correction of exchange interactions has been studied clearly. We elucidate that the inner shell 2p1/2,3/2 orbitals are essential to relativistic corrections of exchange interactions which are crucial for the final anomalous fine-structure splittings. 相似文献
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A scheme for a microwave atomic clock is proposed for Cs or Rb atoms trapped in a blue detuned optical lattice. The ac Stark shift of the clock transition due to a trapping laser is calculated. We analyze it at some specific laser wavelength. Compared with the case of the fountain clock, the cavity related shifts, the collision shift and the Doppler effect are eliminated or suppressed dramatically in an atomic lattice clock. By analyzing various sources of clock uncertainty, a microwave atomic lattice clock with a high accuracy and small volume is feasible. 相似文献
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X射线激光的研究是目前的一个重要的课题.它的实现将对基础研究和实际应用有着重大的影响.实现X射线激光的一个关键是如何提高增益系数.本文着重讨论X射线激光介质中的微观原子过程以及我们最近的软X射线条纹相机诊断实验. 相似文献
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Momentum Transfer Dependence of Two Types of the Broad Enhancement Phenomena: CO Spectra in the Valence Energy Region 下载免费PDF全文
Partial generalized oscillator strength densities of CO molecules related to the excitation of a 5σ or 1π electron are calculated by using multi-scattering self-consistent-field methods.Momentum transfer dependence of two types of the broad enhancement phenomena above the threshold with one-electron character,i.e. shape resonance and non-resonance enhancement,is studied.Our calculations show that the energy position of a non-resonance enhancement is related to the momentum transfer K.Therefore,electron impact based experiments can be used to identify the two types of the broad enhancement phenomena. 相似文献
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Based on relativistic multichannel theory,the autoionization states of C are studied.We calculate all the autoionization states in the energy region of 193900-231700cm^-1,and the results are in good agreement with the experimental data.The energy structure we obtain will be important in the dielectronic recombination processes,which plays a key role in determining the abundance of carbon in a nebula. 相似文献
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Silane photoabsorption spectra mear the Si 2p thresholds:the geometry of Si 2p excited SiH4 下载免费PDF全文
Based on the multiple-scattering self-consistent-field method, we have studied the photoabsorption spectra near the Si 2p thresholds of silane. According to our calculations, the clear assignments of the inner-shell photoabsorption spectra are provided. In comparison with the high-resolution experimental spectra, the geometric structure of the Si 2p-excited SiH_{4}^{**} is recommended to be of a C_{2v} symmetry. More specifically, the Si 2p-excited SiH_{4}^{**} have two bond lengths of 2.50 a.u. and another two bond lengths of 2.77 a.u., and the corresponding two bond angles are 104.0° and 112.5° respectively. 相似文献