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Selection rules for electric multipole transition of triatomic molecule in scattering experiments 下载免费PDF全文
In the electron or x-ray scattering experiment,the measured spectra at larger momentum transfer are dominated by the electric dipole-forbidden transitions,while the corresponding selection rules for triatomic molecules have not been clearly elucidated.In this work,based on the molecular point group,the selection rules for the electric multipolarities of the electronic transitions of triatomic molecules are derived and summarized into several tables with the variation of molecular geometry in the transition process being considered.Based on the summarized selection rules,the electron energy loss spectra of H_2O,CO_2,and N_2O are identified,and the momentum transfer dependence behaviors of their valence-shell excitations are explained. 相似文献
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为了提高原子分子动力学参数的测量精度,本文把气体相对流量技术应用到快电子碰撞研究中.并且在此基础上测量了氙原子6s激发的广义振子强度,所得结果在小动量转移区间与前人的结果符合很好,表明气体相对流量技术在电子碰撞方法中的适用性.大动量转移区间6s的表观广义振子强度对电子碰撞能量的依赖行为,说明500 eV的电子碰撞能量还不满足一阶玻恩近似条件.与Hartree-Fock方法相比,考虑电子关联效应更全面的随机相移近似计算结果与本文的实验结果符合更好,说明对于像Xe这样的重原子,电子关联效应十分重要. 相似文献
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在入射电子能量2500eV、能量分辨200meV的条件下测量了一氧化二氮分子在7.8~24.5 eV的光学振子强度密度谱和光电离质谱,报道了N2O+、NO+、O+、N2+和N+等离子在较高能量分辨下的部分光学振子强度密度,首次给出了一氧化二氮分子在13.0~21.0 eV能区中性解离的振子强度密度.并在对这些数据进行分析的基础上阐述了一氧化二氮分子超激发态的不同退激发道的竞争过程. 相似文献
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在入射电子能量 2 5 0 0eV下测量了He的 11S→ 2 1S ,2 1P ,31S和 31P的微分散射截面和广义振子强度 ,并与前人的实验和理论结果进行了比较 ,认为在此入射电子能量下一阶Born近似对此 4个跃迁成立. With electron impact energy of 2 500 eV and energy resolution of 85 meV, the differential cross sections and the generalized oscillator strengths of the excitations of 1 1S→2 1S, 2 1P, 3 1S and 3 1P of helium has been measured by electron energy loss spectroscopy . Comparing with previous experimental and theoretical results, it seems that the first Born approximation is valid for these excitations under such an electron impact energy. 相似文献
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Enhancement of electron–ion recombination rates at low energy range in the heavy ion storage ring CSRm 下载免费PDF全文
Nadir Khan 黄忠魁 汶伟强 汪书兴 汪寒冰 马万路 朱小龙 赵冬梅 冒立军 李杰 马晓明 汤梅堂 殷达钰 杨维青 杨建成 原有进 朱林繁 马新文 《中国物理 B》2020,(3):169-175
Recombination of Ar14+, Ar15+, Ca16+, and Ni19+ ions with electrons has been investigated at low energy range based on the merged-beam method at the main cooler storage ring CSRm in the Institute of Modern Physics, Lanzhou,China. For each ion, the absolute recombination rate coefficients have been measured with electron–ion collision energies from 0 meV to 1000 meV which include the radiative recombination(RR) and also dielectronic recombination(DR)processes. In order to interpret the measured results, RR cross sections were obtained from a modified version of the semiclassical Bethe and Salpeter formula for hydrogenic ions. DR cross sections were calculated by a relativistic configuration interaction method using the flexible atomic code(FAC) and AUTOSTRUCTURE code in this energy range. The calculated RR + DR rate coefficients show a good agreement with the measured value at the collision energy above 100 meV.However, large discrepancies have been found at low energy range especially below 10 meV, and the experimental results show a strong enhancement relative to the theoretical RR rate coefficients. For the electron–ion collision energy below 1 meV, it was found that the experimentally observed recombination rates are higher than the theoretically predicted and fitted rates by a factor of 1.5 to 3.9. The strong dependence of RR rate coefficient enhancement on the charge state of the ions has been found with the scaling rule of q3.0, reproducing the low-energy recombination enhancement effects found in other previous experiments. 相似文献
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The ionization and ionic dissociation of the superexcited state of N20 are studied by using electron energy loss spectroscopy and positive ion time-of-flight mass spectroscopy at different momentum transfers; that is, 0 and 0.23 a.u. (atomic unit) . The transitions at 13.8 eV and 14.0 eV are reassigned as 3pπ(000) and 3pσ(000) converging to A^2∑+, respectively. The competition between the main decay pathways of superexcited states at different momentum transfers is revealed. It is found that 3dσ converging to C^2∑+ mainly decays into N2O^+ while 4dσ can decay into both N2^O+ and NO^+. 相似文献
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许鑫 汪书兴 黄忠魁 汶伟强 汪寒冰 徐天衡 啜晓亚 豆丽君 徐卫青 陈重阳 李传莹 王建国 师应龙 董晨钟 冒立军 殷达钰 李杰 马晓明 杨建成 原有进 马新文 朱林繁 《中国物理 B》2018,(6)
The electron–ion recombination for phosphorus-like~(112) Sn~(35+)has been measured at the main cooler storage ring of the Heavy Ion Research Facility in Lanzhou, China, employing an electron–ion merged-beams technique. The absolute total recombination rate coefficients for electron–ion collision energies from 0 e V–14 e V are presented. Theoretical calculations of recombination rate coefficients were performed using the Flexible Atomic Code to compare with the experimental results. The contributions of dielectronic recombination and trielectronic recombination on the experimental rate coefficients have been identified with the help of the theoretical calculation. The present results show that the trielectronic recombination has a substantial contribution to the measured electron–ion recombination spectrum of~(112)Sn~(35+). Although a reasonable agreement is found between the experimental and theoretical results the precise calculation of the electron–ion recombination rate coefficients for M-shell ions is still challengeable for the current theory. 相似文献