Cleavage of the Fe—Fe Bond of （Me2SiSiMe2） [η^5－C5H4Fe（CO）2]2 with Na／Hg and Molecular Structure of the Ring－Opened Complex

The reaction of the rifle cyclic complex (1) with sodium amalgam in THF resulted in the expected cleavage of the Fe-Fe bond to afford his-sodium salt ( Me2SiSiMe2 ) [η^5-C5H4Fe(CO)2]2 (4). The latter was not isolated and was used directly to react with MeI, PhCH2Cl, CH3C(O)Cl, PhC(O)Cl,Cy3SnCl (Cy= cyclohexyl) or Ph3SnCl to afford corresponding ring-opened derivatives (Me2SiSiMe2) [η^5-C5H4Fe(CO)2]2 [5, R=Me; 6, R=PhCH2; 7, R=CH3C(O); 8, R=PhC(O); 9, R = Cy3Sn or 10, R = Ph3Sn ]. The crystal and molecular structures of 10 were determined by X-ray diffraction analysis. The molecule took the desired ant/ conformation around the Si-Si bond. The length of the Si--Si bond is 0.2343(3)nm, which is essentially identical to that in the cyclic structure of 1[0.2346(4) tun]. This result unambiguously demonstrates that the Si--Si bond in the cyclic structure of 1 is not subject to obvious strain.     

Cleavage of the Fe-Fe Bond of(Me_2SiSiMe_2)[η~5-C_5H_4Fe(CO)_2]_2 with Na/Hg and Molecular Structure of the Ring-Opened Complex

The reaction of the title cyclic complex(1) with sodium amal-gam in THF resulted in the expected cleavage of the Fe--Febond to afford bis-sodium salt (Me_2SiSiMe_2) [η~5-C_5H_4Fe(CO)_2Na]_2 (4). The latter was not isolated and was used di-rectly to react with MeI, PhCH_2Cl, CH_3C(O)Cl, PhC(O)Cl,Cy_3SnCl (Cy=cyclohexyl) or Ph_3SnCl to afford correspondingring-opened derivatives (Me_2SiSiMe_2) [η~5-C_5H_4Fe(CO)_2R]_2[5, R=Me; 6, R=PhCH_2; 7, R=CH_3C(O); 8, R=PhC     

Isolation of New Disilanylene-bridged Bis（cyclopentadienyl）tetracarbonyldiiron Complexes and Molecular Structure of [η^5, η^5-C5H4SiMe（SiMePh2）C5H4]Fe2（CO）2（μ-CO）2

1,2-Diphenyl-1,2-dimethyldisilanylene-bridged bis-cyclopentadienyl complex[η~5,η~5-C_5H_4PhMeSiSiMePh-C_5H_4]Fe_2(CO)_2(μ-CO)_2(1)was synthesized by a modified procedure,from which the trans-isomer 1b that was pre-viously difficult to obtain has been isolated for the first time.More interestingly,two new regio-isomers[η~5,η~5C_5H_4SiMe(SiMePh_2)C_5H_4]Fe_2(CO)_2(μ-CO)_2(2)and [η~5,η~5-C_5H_4Me_2SiSiPh_2C_5H_4]Fe_2(CO)_2(μ-CO)_2(3)were occa-sionally obtained during above process,the novel structures of which opened up new options for further study ofthis type of Si—Si bond-containing transition metal complexes.The molecular structure of 2 has been determinedby the X-ray diffraction method.     

Surface Light Extraction Mapping from Photonic Quasicrystal on Current Two-Dimensional Array of 12-Fold Injected GaN-Based LEDs

A two-dimensional array of dodecagonal photonic quasicrystal （12PQC） is fabricated on the surface of current injected GaN-based LEDs to out-couple guided modes. The spatially-resolved surface light extraction mapping of 12PQC is observed and compared with that of triangular lattice photonic crystal （3PC） by microscopic electrical luminescence and scanning near-field microscopy. The higher enhancement factor of 12PQC is obtained to be larger than that of 3PC. It is shown that 12PQC is more favourable and efficient for light extraction of guided lights.     

催化剂比例对单壁碳纳米管制备的影响

采用电弧放电法以Y/Ni为催化剂制备了单壁碳纳米管 ,研究了不同催化剂比例对制备产物的影响。获得了不同激发波长下 (476 5～ 1 0 6 4nm)单壁碳纳米管的拉曼光谱 ,采用图表法对径向呼吸模的谱峰进行了认定。结果表明 :样品中碳管的直径分布在 1 2～ 1 6nm之间 ,直径在 1 43nm附近的碳管居多。催化剂的比例只是影响碳管的产额 ,对其直径分布的影响很小     

纳米集成光路中的光源、光波导和光增强

使用近场光学显微术(scanning near-field optical microscopy, SNOM)研究了ZnO亚微米线端面出射性质,不同空间形貌Ⅱ-Ⅵ族半导体荧光器件光波导特性,二维光子晶体、准晶光子晶体对LED的出射增强作用以及表面等离激元(surface plasmon polariton, SPP)与半导体纳米荧光器件的相互作用,对纳米集成光路中的光源、光波导、光增强三个重要问题做了实验和理论上的分析.研究发现半导体微纳米线端面出射光束的质量与样品的直径有密切关系.通过合理地设计其直径和 关键词： 纳米集成光路 扫描近场光学显微术 光波导 光增强     

纳米集成光路中的光源、光波导和光增强

使用近场光学显微术(scanning near-field optical microscopy, SNOM)研究了ZnO亚微米线端面出射性质，不同空间形貌Ⅱ-Ⅵ族半导体荧光器件光波导特性，二维光子晶体、准晶光子晶体对LED的出射增强作用以及表面等离激元(surface plasmon polariton, SPP)与半导体纳米荧光器件的相互作用，对纳米集成光路中的光源、光波导、光增强三个重要问题做了实验和理论上的分析.研究发现半导体微纳米线端面出射光束的质量与样品的直径有密切关系.通过合理地设计其直径和