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Antimony-based bismuth-doped thin film,a new kind of super-resolution mask layer,is prepared by magnetron sputtering.The structures and optical constants of the thin films before and after annealing are examined in detail.The as-deposited film is mainly in an amorphous state.After annealing at 170-370℃,it is converted to the rhombohedral-type of structure.The extent of crystallization increased with the annealing temperature.When the thin film is annealed,its refractive index decreased in the most visible region,whereas the extinction coefficient and reflectivity are markedly increased.The results indicate that the optical parameters of the film strongly depend on its microstructure and the bonding of the atoms. 相似文献
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Novel phthalocyanine thin film for compact disc recordable 总被引:1,自引:0,他引:1
In this paper, the spin-coated thin films of phthalocyanine dye are presented. Absorption spectrum of the thin film shows a comparatively broad absorption in the wavelength range 630 - 770 nm. Optical parameters of the thin film were measured by a spectroscopic ellipsometer system. 5-in CD-R discs made of this dye exhibit good performance with Yamaha 20-speed recorder. Jitters of land and pit are less than 30 ns, and the 3T-11T's signals show very good quality. This dye is a promising recording medium for CD-R with much higher recording speed. 相似文献
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研究了两种新型芴类衍生物9,9_二(2_乙基已基)_2,7_二咔唑_9H_芴(简记为DCZF)和9 ,9_二(2_乙基已基)_2,7_二(2_(4_甲氧基)苯_2,1_乙烯基)芴(简记为BMOSF)在N ,N_二甲基甲酰胺(DMF)中的线性吸收和单光子荧光行为,并用脉冲宽度为38ps,重复 频率为10 Hz的1064 nm Nd:YAG脉冲激光研究了两种化合物的三光子吸收性质.结果表明: 两种新材料的最大线性吸收峰分别位于330和380nm,吸收区域覆盖了270—420 nm波段. 两种化合物的荧光带位于蓝_紫区,中心波长为369和442 nm,都具有较小的斯托克斯位移. 化合物DCZF和BMOSF的三光子吸收系数分别为γDCZF=678×10- 20 cm3/W2和γBMOSF=592×10-20 cm3/W2. 同时, 两种新材料还表现出明显的三光子吸收光限幅效应,当入射光强分别为8和6GW/cm2时,非线性透过率分别达到30%和45%.
关键词:
芴类衍生物
三光子吸收
光限幅
非线性透过率 相似文献
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Monoamino substituted asymmetrical phthalocyanine zinc(Ⅱ), 2-amino-9,10,16,17,23,24-hexapentyloxy phthalocyanine zinc(Ⅱ), was synthesized by statistical condensation and characterized by elemental analysis, UV-Vis, IR and TOF-MS. The aggregative behavior was studied in DMF, THF and CH2Cl2. The results show that it is not aggregateve in DMF and THF, whereas form dimer in CH2Cl2 at 8 × 10-7~8 × 10-6 mol·L-1. The equilibrium constant for the dimer was calculated at the same time, indicating that the less polar solvent is unfavorable for the presence of the monomer. 相似文献
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Thiophene-fluorene derivatives with high three-photon absorption activities and their application to optical power limiting 下载免费PDF全文
The three-photon absorption (3PA) properties of two thiophene-fluorene derivatives (abbreviated as MOTFTBr and ATFTBr) have been determined by using a Q-switched Nd:YAG laser pumped with 38ps pulses at 1064nm in DMF. The measured 3PA cross-sections are 152×10^-78cm^6s^2 and 139× 10^-78cm^6s^2, respectively. The optimized structures were obtained by AM1 calculations and the results indicate that these two molecules show nonplanar structures, and attaching different donors has different effects on the molecular structure. The charge density distributions during the excitation were also systematically studied by using AM1 method. In addition, an obvious optical power limiting effect induced by 3PA has been demonstrated for both derivatives. 相似文献
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Optical Recording Properties of Metal-Azo Dye as Recording Medium with Super-Resolution Near-Field Structure 下载免费PDF全文
A novel metallized azo dye has been synthesized. The absorption spectra of the thin film and thermal characteristic are measured. Static optical recording properties with and without the Bi mask layer super-resolution near-field structure (Super-RENS) of the metal-azo dye are investigated. The results show that the metal-azo dye film has a broad absorbance band in the region of 450-650 nm and the maximum absorbance wavelength is located at 603 nm. It is also found that the new metallized azo dye occupies excellent thermal stability, initiatory decomposition temperature is at 270℃ and the mass loss is about 48% in a narrow temperature region (15℃). The complex refractive index N (N = n + iκ) is measured. High refractive index (n = 2.45) and low extinction coefficient (κ = 0.2) at the recording wavelength 65Ohm are attained. Static optical recording tests with and without Super-RENS are carried out using a 65Ohm semiconductor diode laser with recording power of 7mW and laser pulse duration of 200ns. The AFM images show that the diameter of recording mark on the dye film with the Bi mask layer is reduced about 42%, compared to that of recorded mark on the dye film without Super-RENS. It is indicated that Bi can well performed as a mask layer of the dye recording layer and the metallized azo dye can be a promising candidate for recording media with the super-resolution near-field structure. 相似文献
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测定了一组八烷氧基萘酞菁镍(Ⅱ)配合物Ni(Ⅱ)(RO)8NPC(R=C4H9,C8H17,C12H25,NPC=C48H16N8)在5种有机溶剂(Py、DMSO、DMF、CH2Cl2、C6H12)中的电子吸收光谱和荧光光谱,研究了这些配合物的结构与光谱的关系。结果表明该系列RO取代萘酞菁镍(Ⅱ)配合物的Q带吸收光谱比无取代的红移75nm左右,荧光光谱屯相应红移50~80nm,而溶剂对其影响不大。 相似文献