Synthesis,Crystal Structure and Theoretical Calculation of [2-（2,6-Dioxacyclohexyl）-5-methoxylphenols]2

The title compound [2-（2,6-dioxacyclohexyl）-5-methoxylphenols]2 was synthesized by the reaction of 2-hydroxyl-3-methoxylbenzaldehyde and 1,3-propanediol in the presence of DMF-DMS adduct and characterized by IR spectrum, UV-Vis spectrum and X-ray crystallography. The title compound belongs to monoclinic, space group P21 with a = 9.8967（10）, b = 8.2240（9）, c = 13.3654（14） A^°, β= 90.016（2）°, C11H14O4, Mr = 210.22, V = 1087.8（2）A^°3, Z = 4, Dc = 1.284 Mg/m^3, F（000） = 448,μ = 0.098 mm^-1, the final R = 0.0300 and wR = 0.0761 for 2070 observed reflections with I 〉 2σ（I）. The molecules are connected via intermolecular O-H…O hydrogen bonds into a 2D network structure. Moreover, theoretical investigations of the title compound with HF/6-31G（d） method were performed, and its stability, frontier molecular orbital composition and Mulliken charge distribution were also discussed. The compound is a bis-molecule. The two molecules stay together and could not be separated. Two crystallographically independent molecules exist in an asymmetric unit. The bond lengths and bond angles of the two molecules are slightly different with each other.     

Complete Band-Gap in Two-Dimensional Quasiperiod Photonic Crystals with Hollow Cylinders

The transmission properties of quasiperiodic photonic crystals (QPCs) based on the random square-triangle tiling system are investigated by the multiple scattering method. The hollow cylinders are introduced in our calculation. It is found that QPCs with hollow cylinders also possess a complete band gap common to s- and p-polarized waves when the inner radius of hollow cylinders is larger than a certain value. The QPCs possessing the complete band gap can be applied to the fields of light emitting, wave-guides, optical filters, high-Q resonators and antennas.     

二维平板光子晶体直波导的制备和光传输特性的测量

利用聚焦离子束刻蚀的方法在SOI(silicon on insulator)基片上制备了W3型二维光子晶体直波导.观察并测量了近红外激光通过光子晶体波导的散射图形和透过谱.实验结果说明，激光在有引入引出脊形波导的光子晶体直波导中具有很好的传输特性. 关键词： 光子晶体波导 光子带隙 脊型波导     

Negative Refraction and Near-Field Imaging of an Elliptical-Rod Photonic Crystal Slab in the Second Band

Negative refraction and imaging properties of the electromagnetic wave through a two-dimensional photonic crystal （PC） slab, which consists of a square lattice of elliptical dielectric rods immersed in the air background, is studied by the plane-wave expansion method and the finite-difference time-domain method. A point source placed in the vicinity of the PC slab can form a good-quality image spot through the PC slab for the incident frequencies within the second photonic band. The calculated result also shows that negative refraction occurs in this kind of PC slab.     

Transmission Properties of W3 Y-Branch Filters in Two-Dimensional Photonic Crystal Slabs

A highly efficient W3 Y-branch filter in a two-dimensional photonic crystal slab with triangular lattice of air holes is designed and fabricated, and its transmission properties are measured. By accurately adjusting the size of the resonant cavities, the minimum wavelength spacing of 7 nm between two channels is realized. The corresponding resonant wavelengths of the two cavities agree well with the calculated ones. This implies that this kind of fiIter may be promising in integrated wavelength division multiplexing system.     

CuS纳米粒子在太赫兹波段的光电性质研究

关键词： 太赫兹 CuS纳米粒子 Lorentz理论 Drude-Smith模型     

二维正方晶格光子晶体平板的近场成像特性

光子晶体是由两种或两种以卜不同介电函数的材料周期性排列组成的一种人工晶体.由于介电甬数的周期性分布对入射光的调制作用,使得特定频率区域的人射光在光子晶体中传播时的群速度方向和相速度方向相反,因而使得光子晶体平板表现出负折射特性.系统研究了介质柱的形状对二维正方品格光子品体近场成像特性的影响.通过对分别由正方形、三角形、椭网形、长方形等形状介质柱组成的二维正方品格光子晶体平板近场成像特性的理论分析,发现当介质柱形状的对称性降低到一定程度后可以实现光子晶体近场成像的纵向平移.进一步通过对相应等频率曲线形状的分析,明确了光子晶体近场成像是由于自准直效应和负折射效应的共同作用形成的.     

微腔旋转对耦合腔光波导群速度的影响

本文利用多重散射方法和时域有限差分方法,理论研究了微腔旋转对二维正方晶格光子晶体耦合腔光波导群速度的影响.研究结果表明,通过旋转微腔可以造成传播模的模式分裂,从而实现群速度的降低.当微腔旋转角度为45°时,传播模的群速度最小,两个传播模的群速度分别达到了0.0016倍和0.0009倍于真空光速,与微腔未旋转时相比降低了一个数量级.上述两种传播模群速度的差别是由传播模的空间对称性决定的. 关键词： 二维光子晶体 耦合腔光波导 群速度     

基于无人机高光谱遥感的东北粳稻冠层叶片氮素含量反演方法研究

为探究遥感监测水稻冠层叶片氮素含量的较优高光谱反演模型，以水稻小区试验为基础，获取了不同生长期水稻冠层高光谱数据。在综合比较一阶导数变换(1-Der)、标准正态变量变换(SNV)和SG滤波法等处理方法基础上，提出一种将SNV与一阶导数变换的SG滤波法相结合的光谱处理方法(SNV-FDSGF)，并将处理后的数据经无信息变量消除法(UVE)与竞争自适应重加权采样法（CARS）选出不同生长期的敏感波段。将各生长期的敏感波段两两随机组合，并构建与水稻叶片含氮量相关性较高的差值光谱植被指数(DSI)、比值光谱植被指数(RSI)、归一化光谱植被指数(NDSI)。其中分蘖、拔节和抽穗3个时期的最优植被指数和决定系数R2分别为：DSI(R₈₅₇, R₆₂₃), 0.704; DSI(R₆₇₀, R₅₇₈), 0.786; DSI(R₉₉₅, R₅₀₈), 0.754。以各生长期内的较优的三种植被指数作为输入分别构建自适应差分优化的极限学习机(SaDE-ELM)、径向基神经网络(RBF-NN)以及粒子群优化的BP神经网络(PSO-BPNN)反演模型。结果表明：SaDE-ELM建模效果最好，在模型稳定性和预测能力上比RBF-NN和PSO-BPNN都有了明显提高，各生长期反演模型的训练集和验证集决定系数R2均在0.810以上，RMSE均在0.400以下，可为东北水粳稻冠层叶片含氮量的检测与评估提供科学和技术依据。     

基于Fernald-PSO法反演气溶胶激光雷达比及其 对斜程能见度的影响

为了提高斜程能见度的计算精度,提出了一种基于Fernald-PSO法求解气溶胶激光雷达比的方法.首先,以均匀层底部和顶部的大气消光系数相等为条件构建气溶胶激光雷达比和气溶胶消光系数边界值的方程.然后,再以激光雷达数据反演和AERONET网站观测的气溶胶光学厚度相等为条件构造另一参量方程.最后,采用Fernald-PSO法解方程组,用得到的参量反演气溶胶消光系数计算斜程能见度.采用激光雷达和AERONET数据对该方法进行验证,分析气溶胶激光雷达比对斜程能见度反演的影响.结果表明,同一信号气溶胶激光雷达比假设值与计算值相差越大,气溶胶消光系数和斜程能见度的相对误差绝对值也越大,最大误差分别为18.93%和19.90%.