纤维素基吸附分离材料研究进展

以纤维素为原料制备吸附分离材料可以减少对石油资源的依赖,并具有成本低、环境友好和生物相容性好等优点。利用纤维素中的羟基基团,通过交联、接枝、引入无机粒子或与聚合物复合,可以制备出微球和薄膜等不同形态的吸附分离材料,广泛应用于生物医学,废水处理、气体分离等领域。本文结合近五年来国内外纤维素及其复合材料在吸附分离领域的研究近况,从水、油、重金属、气体和有机物的应用进行了综述,总结了纤维素基吸附分离材料的研究尚存在的问题,探讨了今后的研究方向。     

高考填空题压轴题的解题策略及思考

作为独立题型,填空题大多是计算型（尤其是推理计算型）和概念性质运用型的试题,解答时必须按规则进行切实的计算与合乎逻辑的推演和判断,但填空题要是考点多、解题长度较长、影响结论的因素较多等,那么即使做到了最后一步才出错,在得分上却和一窍不通的考生是没有任何差别的,尽管他们在水平上存在很大差异,这正是它的缺点,客观上影响了考试的信度与效度．然而,     

高考填空题压轴题的解题策略及思考

作为独立题型,填空题大多是计算型(尤其是推理计算型)和概念性质运用型的试题,解答时必须按规则进行切实的计算与合乎逻辑的推演和判断,但填空题要是考点多、解题长度较长、影响结论的因素较多等,那么即使做到了最后一步才出     

Optical Properties of Hexagonal and Cubic ZnS Nanoribbons: Experiment and Theory

Optical properties of hexagonal and cubic ZnS nanoribbons are studied by using valence electron energy loss spectroscopy （VEELS） and ab initio band structure calculations. The peaks in VEELS are assigned to interband transitions by comparing the interband transition strengths with the calculated densities of states. The optical properties are deduced from the experimental VEELS, and the theoretical calculations give consistent results. This combination of experimental and theoretical approaches provides a comprehensive understanding of the optical properties of polytype ZnS.     

AEs蛋白在心肌细胞急性损伤与保护的差异性表达

以原代培养的SD新生乳鼠心肌细胞为研究对象,建立缺氧/复氧(A/R)损伤和缺氧预适应(APC)保护模型.通过RT-PCR法和Western blot法检测阴离子交换蛋白(AEs)各亚型AE1、AE2和AE3在A/R损伤与APC保护中表达是否存在差异.结果发现,A/R损伤后AE2表达增加,APC可抑制其增加；但AE1和AE3经APC处理后,表达却明显上调；提示:AE2可能参与心肌细胞A/R损伤,AE1和AE3则可能参与了心肌细胞APC的保护作用.     

Measurements of 79Se with AMS based on extracting molecular negative ions

A new method for measuring selenium-79 with AMS, which is based on extracting molecular negative ions, is described in this paper. According to the experimental results, the extraction ion form SeO₂^－ could depress the interference of Bromine-79 as much as 5 order levels, that is to say, the background of ⁷⁹Br can be deducted to ⁷⁹Br/Se≈10^－10. By the way, the chemical form of sample and preparation flow was also developed. Finally, three ⁷⁹Se AMS calibration standard samples with theoretical ⁷⁹Se/Se ratios of 5.06×10^－7, 6.87×10^－8, 5.40×10^－10 were obtained and the method of ⁷⁹Se measurement was set up, which actualized transmission and detection of ⁷⁹Se. By using our Bragg curve detector, the two isobars ⁷⁹Br and ⁷⁹Se could be partly identified to a certain extent and ⁷⁹Se can be identified from ⁷⁹Br about 1 order level. AMS measurements of the three calibration standard samples above were performed and good linearity was obtained. The sensitivity of the measurement is (5.16±1.80)×10^－11.     

AMS measurement of In-situ produced cosmogenic 10Be in Loess Quartz in Luochuan

Loess is the most important and the most typical continental classic sediments of Quaternary. So the measurement of In-situ produced cosmogenic ¹⁰Be is expected to be used for the Loess stratigraphic age. But the production rate of In-situ produced cosmogenic ¹⁰Be in Loess quartz is very low. It requires very high sensitivity and accuracy of measurement. This work has measured the concentrations of ¹⁰Be of two layers in Loess section of Luochuan including L8, L9 and the concentrations of ¹⁰Be in (of) blank sample with the HI-13 AMS system at China Insitute of Atomic Energy(CIAE), then calculated the content of ¹⁰Be in loess quartz for each layer. The ratio of ¹⁰Be/⁹Be was found in the range of 10^－13. The background of ¹⁰Be/⁹Be was about 3×10^－14.     

桁架结构的拓扑优化设计

本文提出了一种杆系结构的拓扑优化设计方法。在本方法中,通过求解一个给出位移场的线性规划确定出结构的新的拓扑形式;将m个位移约束与n个应力约束等效为n个独立的应力约束;接着,利用专家系统技术对所得到的具有新拓扑的结构进行机动性分析並提供修改方案。几个数值实例说明了本方法的可行性。     

CeO2缓冲层热处理对Tl-2212薄膜超导特性的影响

本文采用原子力显微镜(AFM)和XRD研究了生长在蓝宝石(11-02)基片上的CeO2缓冲层在不同的退火温度和退火时间下表面形貌和相结构的变化,以及对Tl-2212薄膜超导特性的影响。AFM和XRD研究表明,CeO2薄膜在流动氧环境中退火,表面形貌发生显著的变化;CeO2薄膜在最佳条件下退火后,可获得原子级光滑表面,结晶质量明显提高。实验结果表明,缓冲层的结晶质量和表面粗糙度与Tl-2212薄膜的超导特性密切相关。在经过最佳条件退火后的CeO2缓冲层上制备了厚度为500nm无裂纹的Tl-2212超导薄膜,其临界转变温度(Tc)达到107K,液氮温度下临界电流密度(Jc)为3.9MA/cm2(77K,0T),微波表面电阻(Rs)约为281μΩ(77K,10GHz)。