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1.
We give a characterization of the cyclic subgroup separability and weak potency of the fundamental group of a graph of polycyclic-by-finite groups and free-by-finite groups amalgamating edge subgroups of the form × D,where h has infinite order and D is finite. 相似文献
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Antoine Barthélemy Dr. Harald Scherer Prof. Dr. Ingo Krossing 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(53):e202201369
The tetracationic, univalent cluster compounds [{M(dmpe)}4]4+ (M=Ga, In; dmpe=bis(dimethylphosphino)ethane) were synthesized as their pf salts ([pf]−=[Al(ORF)4]−; RF=C(CF3)3). The four-membered ring in [{M(dmpe)}4]4+ is slightly puckered for M=Ga and almost square planar for M=In. Yet, although structurally similar, only the gallium cluster is prevalent in solution, while the indium cluster forms temperature dependent equilibria that include even the monomeric cation [In(dmpe)]+. This system is the first report of one and the same ligand inducing formation of isoelectronic and isostructural gallium/indium cluster cations. The system allows to study systematically analogies and differences with thermodynamic considerations and bonding analyses, but also to outline perspectives for bond activation using cationic, subvalent group 13 clusters. 相似文献
4.
研究了广义半交换环的幂零结构,定义了一类新的环类,即幂零$\alpha$-半交换环.说明了$\alpha$-半交换环与半交换环, $\alpha$-半交换环和$\alpha$-刚性环等环密切相关,通过构造反例说明了幂零$\alpha$-半交换环未必是$\alpha$-半交换环.研究了幂零$\alpha$-半交换环的各种性质,推广和统一了与环的半交换性质有关的若干结论. 相似文献
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Angela Milinkovic Dr. Antoine Dupé Ao. Univ.-Prof. Dr. Ferdinand Belaj Univ.-Prof. Dr. Nadia C. Mösch-Zanetti 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(55):e202201867
Molybdenum(VI) bis(imido) complexes [Mo(NtBu)2(LR)2] (R=H 1 a ; R=CF3 1 b ) combined with B(C6F5)3 ( 1 a /B(C6F5)3, 1 b /B(C6F5)3) exhibit a frustrated Lewis pair (FLP) character that can heterolytically split H−H, Si−H and O−H bonds. Cleavage of H2 and Et3SiH affords ion pairs [Mo(NtBu)(NHtBu)(LR)2][HB(C6F5)3] (R=H 2 a ; R=CF3 2 b ) composed of a Mo(VI) amido imido cation and a hydridoborate anion, while reaction with H2O leads to [Mo(NtBu)(NHtBu)(LR)2][(HO)B(C6F5)3] (R=H 3 a ; R=CF3 3 b ). Ion pairs 2 a and 2 b are catalysts for the hydrosilylation of aldehydes with triethylsilane, with 2 b being more active than 2 a . Mechanistic elucidation revealed insertion of the aldehyde into the B−H bond of [HB(C6F5)3]−. We were able to isolate and fully characterize, including by single-crystal X-ray diffraction analysis, the inserted products Mo(NtBu)(NHtBu)(LR)2][{PhCH2O}B(C6F5)3] (R=H 4 a ; R=CF3 4 b ). Catalysis occurs at [HB(C6F5)3]− while [Mo(NtBu)(NHtBu)(LR)2]+ (R=H or CF3) act as the cationic counterions. However, the striking difference in reactivity gives ample evidence that molybdenum cations behave as weakly coordinating cations (WCC). 相似文献
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《Discrete Mathematics》2022,345(4):112767
Let R be a finite commutative chain ring, be the dihedral group of size 2n and be the dihedral group ring. In this paper, we completely characterize left ideals of (called left -codes) when . In this way, we explore the structure of some skew-cyclic codes of length 2 over R and also over , where S is an isomorphic copy of R. As a particular result, we give the structure of cyclic codes of length 2 over R. In the case where is a Galois field, we give a classification for left -codes over , for any positive integer N. In both cases we determine dual codes and identify self-dual ones. 相似文献
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The collision frequencies of electron-neutral-particle in weakly ionized complex plasmas with the non-Maxwellian velocity distributions are studied. The average collision frequencies of electron-neutral-particle in plasmas are accurately derived. We find that these collision frequencies are significantly dependent on the power-law spectral indices of non-Maxwellian distribution functions and so they are generally different from the collision frequencies in plasmas with a Maxwellian velocity distribution, which will affect the transport properties of the charged particles in plasmas. Numerically analyses are made to show the roles of the spectral indices in the average collision frequencies respectively. 相似文献
10.
Peng Sun Zihan Xia Zhongfang Li Ziwei Fan Fengqi He Qiang Liu Xiaoyan Yin 《Materials Today Chemistry》2022
A high-temperature proton exchange membrane with high proton conductivity over a wide humidity range still remains a challenge. PBI dendrimer containing triazine rings (TPBI) was synthesized to approach this aim considering its high content of hygroscopic terminal groups and of larger free volume. A novel proton conductor previously synthesized (zirconium 3-sulfopropyl phosphonate, ZrSP) was doped due to its good proton conductivity over a wide humidity range. TPBI was post-crosslinked with a tetrafunctional epoxy resin (N,N,N′,N′-tetraglycidyl-4,4′-diaminodiphenylmethane, TGDDM) to enhance the mechanical stability at low cross-linking degrees, which allowed high doping levels of ZrSP, and thus, high conductivity. The prepared membranes (TPBI-TGDDM/ZrSP) showed good thermal stability, high proton conductivity over wide humidity range, and good dimensional stability. At suitable degrees of branching, TPBI-TGDDM/ZrSP exhibited superior mechanical property, oxidative stability, methanol barrier property, and membrane selectivity than its linear analog (mPBI-TGDDM/ZrSP). As ZrSP instead of PA was applied as the proton conductor, TPBI-TGDDM/ZrSP showed good durability of proton conductivity, especially in comparison with TPBI-TGDDM/PA, which highly retarded decline in conductivity caused by PA leaking. The proton conductivity at 180 °C of TPBI(20)-TGDDM(10)/ZrSP(50) achieved 142, 84.2 and 23.6 mS cm?1 at 100%, 50%, and 0 RH, respectively. 相似文献