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**排序方式：**共有10000条查询结果，搜索用时 15 毫秒

1.

Polyoxometalate‐Mediated One‐Pot Synthesis of Pd Nanocrystals with Controlled Morphologies for Efficient Chemical and Electrochemical Catalysis

*下载免费PDF全文* Dr. Dongheun Kim Ji Hyun Seog Minjune Kim MinHo Yang Eleanor Gillette Prof. Dr. Sang Bok Lee Prof. Dr. Sang Woo Han 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(14):5387-5394

Polyoxometalates (POMs), as inorganic ligands, can endow metal nanocrystals (NCs) with unique reactivities on account of their characteristic redox properties. In the present work, we present a facile POM‐mediated one‐pot aqueous synthesis method for the production of single‐crystalline Pd NCs with controlled shapes and sizes. The POMs could function as both reducing and stabilizing agents in the formation of NCs, and thus gave a fine control over the nucleation and growth kinetics of NCs. The prepared POM‐stabilized Pd NCs exhibited excellent catalytic activity and stability for electrocatalytic (formic acid oxidation) and catalytic (Suzuki coupling) reactions compared to Pd NCs prepared without the POMs. This shows that the POMs play a pivotal role in determining the catalytic performance, as well as the growth, of NCs. We envision that the present approach can offer a convenient way to develop efficient NC‐based catalyst systems. 相似文献

2.

An infrared based positioning and tracking (IPT) system was introduced and its accuracy and efficiency for patient setup and monitoring were tested for daily radiotherapy treatment. The IPT system consists of a pair of floor mounted infrared stereoscopic cameras, passive infrared markers and tools used for acquiring localization information as well as a custom controlled software which can perform the positioning and tracking functions. The evaluation of IPT system characteristics was conducted based on the AAPM 147 task report. Experiments on spatial drift and reproducibility as well as static and dynamic localization accuracy were carried out to test the efficiency of the IPT system. Measurements of known translational (up to 55.0 mm) set-up errors in three dimensions have been performed on a calibration phantom. The accuracy of positioning was evaluated on an anthropomorphic phantom with five markers attached to the surface; the precision of the tracking ability was investigated through a sinusoidal motion platform. For the monitoring of the respiration, three volunteers contributed to the breathing testing in real time. The spatial drift of the IPT system was 0.65 mm within 60 min to be stable. The reproducibility of position variations were between 0.01 and 0.04 mm. The standard deviation of static marker localization was 0.26 mm. The repositioning accuracy was 0.19 mm, 0.29 mm, and 0.53 mm in the left/right (L/R), superior/inferior (S/I) and anterior/posterior (A/P) directions, respectively. The measured dynamic accuracy was 0.57 mm and discrepancies measured for the respiratory motion tracking was better than 1 mm. The overall positioning accuracy of the IPT system was within 2 mm. In conclusion, the IPT system is an accurate and effective tool for assisting patient positioning in the treatment room. The characteristics of the IPT system can successfully meet the needs for real time external marker tracking and patient positioning as well as respiration monitoring during image guided radiotherapy treatments. 相似文献

3.

Conny Unger Olga Kofanova Kate Sokolowska Daniel Lehmann Fay Betsou 《Electrophoresis》2015,36(17):2072-2081

The analytical and clinical validity of analyses of RNA samples destined for clinical diagnosis and therapeutic management is directly impacted by RNA quality. RNA is affected by heat, enzymatic degradation, and Ultraviolet (UV) light. RNA from three eukaryotic cell lines was degraded by heat, RNase, or UV light. RNA integrity values obtained with the benchmark Agilent Bioanalyzer 2100 system were compared with those from the more recent QIAxcel Advanced system. The application of this novel method has allowed us to unravel differences between RNA biophysical and biochemical degradation modes. Agilent RNA integrity number (RIN) and QIAxcel RIS were comparable in heat‐degraded and RNase III‐degraded RNA. Agilent RIN and QIAxcel RIS were comparable at a RIN decision level of 7 in UV‐degraded RNA but not overall. The QIAxcel RIS method was more precise than Agilent RIN for RIN<8, while the inverse was true for RIN≥8. Greater degradation of mRNA and rRNA in UV‐damaged samples hampered the Agilent RIN calculation algorithm. Overall, RIS was more robust than RIN for assessing RNA integrity. The ΔΔCt‐values for heat‐ and UV‐degraded RNA samples showed slightly higher correlation with RIS than with RIN. RNA integrity can be used to categorize RNA samples for suitability for downstream gene expression analyses, independently of the RNA degradation mechanism. The new method QIAxcel is more robust and therefore allows more accurate categorization of compromised RNA samples. 相似文献

4.

The aggregate claim amount in a particular time period is a quantity of fundamental importance for proper management of an insurance company and also for pricing of insurance coverages. In this paper, we show that the proportional hazard rates (PHR) model, which includes some well-known distributions such as exponential, Weibull and Pareto distributions, can be used as the aggregate claim amount distribution. We also present some conditions for the use of exponentiated Weibull distribution as the claim amount distribution. The results established here complete and extend the well-known result of Khaledi and Ahmadi (2008). 相似文献

5.

This paper deals with the optimal reinsurance problem if both insurer and reinsurer are facing risk and uncertainty, though the classical uncertainty free case is also included. The insurer and reinsurer degrees of uncertainty do not have to be identical. The decision variable is not the retained (or ceded) risk, but its sensitivity with respect to the total claims. Thus, if one imposes strictly positive lower bounds for this variable, the reinsurer moral hazard is totally eliminated.Three main contributions seem to be reached. Firstly, necessary and sufficient optimality conditions are given in a very general setting. Secondly, the optimal contract is often a bang–bang solution,

*i.e.*, the sensitivity between the retained risk and the total claims saturates the imposed constraints. Thirdly, the optimal reinsurance problem is equivalent to other linear programming problem, despite the fact that risk, uncertainty, and many premium principles are not linear. This may be important because linear problems may be easily solved in practice, since there are very efficient algorithms. 相似文献6.

Tall structures, such as towers and bridges, can oscillate at excessive magnitudes when subjected to wind and earthquake loads. Liquid sloshing absorbers can be used to suppress these excessive oscillations by tuning the frequency of the sloshing to the critical frequency of the structure. Sloshing absorbers are simple structures consisting of a partially full container of liquid with a free surface. Tuning ensures that significant amounts of harmful energy can be extracted from the structure to the sloshing liquid. However, there needs to be a rapid means of dissipating this energy to avoid its returning back to the structure (then back to the liquid periodically).A hen׳s egg seems to have evolved to efficiently dissipate energy to protect its embryo using sloshing of its liquid content. Hence, the potential to implement the egg׳s unique properties as a sloshing absorber for structural control, is the main focus of this study. Numerical simulations, using Smoothed Particle Hydrodynamics (SPH), and experimental comparisons are presented in this paper. One objective is to demonstrate the ability of SPH to simulate complex free surface behaviour in three dimensions. Such a tool is then useful to identify different dissipation modes. Effects of fill volume and viscosity on the rate of dissipation, are also investigated. 相似文献

7.

We numerically study convection–diffusion equations arising in financial modeling. We focus on the convection-dominated cases, in which the diffusion coefficients are relatively small. Both finite-difference and Monte-Carlo methods which are widely used in the problems of this kind might be inefficient due to severe restrictions on the meshsize and the number of realizations needed to achieve high resolution.We propose an alternative approach based on particle methods which have extremely low numerical diffusion and thus do not have the aforementioned restrictions. Our approach is based on the operator splitting: The hyperbolic steps are made using the method of characteristics, while the parabolic steps are performed using either a special discretization of the integral representation of the solution (which leads to a deterministic particle method) or a stochastic random walk approach.We apply the designed particle methods to a variety of test problems and the numerical results indicate high accuracy, efficiency and robustness of both the deterministic and stochastic methods. In addition, our numerical experiments clearly demonstrate that the deterministic particle method outperforms its stochastic counterpart. 相似文献

8.

In active sound control, noise shielding of a target region is achieved via additional sources (called controls) situated at the perimeter of the region. The sources protect the target region by adjusting the acoustic field near the boundary of the region. In the present paper a numerical model of active sound control based on surface potentials in 3D bounded composite regions is numerically studied. In the composite region setup, it is required that the regions be shielded from noise while allowing admissible sound that is generated in the shielded regions to be preserved. The admissible sound is usually required to propagate freely inside the protected regions or in a (selective) predetermined pattern. The adjusting approach used here does not require any knowledge of the sound sources or the properties of the propagation medium in order to obtain the controls. Moreover, the approach differs sharply from some other approaches where the detailed knowledge of the sound sources and the propagation medium is required. For the first time, numerical test cases involving both free communication and predetermined communication pattern between the regions in three dimensions are considered. In all test cases, these regions are effectively shielded from the noise while any present admissible sound is preserved. In addition, selective propagation of the admissible sound between the regions is enforced. The effect of the number of controls on their operation is also studied. Whether admissible sound is present or not, the level of noise cancellation decreases linearly as fewer controls are used. In addition to the increase in size of the interference zone, the controls become individually distinguishable. 相似文献

9.

This paper investigates the investment and reinsurance problem in the presence of stochastic volatility for an ambiguity-averse insurer (AAI) with a general concave utility function. The AAI concerns about model uncertainty and seeks for an optimal robust decision. We consider a Brownian motion with drift for the surplus of the AAI who invests in a risky asset following a multiscale stochastic volatility (SV) model. We formulate the robust optimal investment and reinsurance problem for a general class of utility functions under a general SV model. Applying perturbation techniques to the Hamilton–Jacobi–Bellman–Isaacs (HJBI) equation associated with our problem, we derive an investment–reinsurance strategy that well approximates the optimal strategy of the robust optimization problem under a multiscale SV model. We also provide a practical strategy that requires no tracking of volatility factors. Numerical study is conducted to demonstrate the practical use of theoretical results and to draw economic interpretations from the robust decision rules. 相似文献

10.

In this paper, a general Kolmogorov type predator–prey model is considered. Together with a constant-yield predator harvesting, the state dependent feedback control strategies which take into account the impulsive harvesting on predators as well as the impulsive stocking on the prey are incorporated in the process of population interactions. We firstly study the existence of an order-1 homoclinic cycle for the system. It is shown that an order-1 positive periodic solution bifurcates from the order-1 homoclinic cycle through a homoclinic bifurcation as the impulsive predator harvesting rate crosses some critical value. The uniqueness and stability of the order-1 positive periodic solution are derived by applying the geometry theory of differential equations and the method of successor function. Finally, some numerical examples are provided to illustrate the main results. These results indicate that careful management of resources and harvesting policies is required in the applied conservation and renewable resource contexts. 相似文献