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1.
The increasing application of positron emission tomography (PET) in nuclear medicine has stimulated the extensive development of a multitude of novel and versatile techniques to introduce fluorine-18, especially for the radiolabelling of biologically or pharmacologically active molecules. Taking into consideration that the introduction of fluorine-18 (t1/2=109.8 min) mostly proceeds under harsh conditions, radiolabelling of such molecules represents a challenge and is of enormous interest. Ideally, it should proceed in a regioselective manner under mild physiological conditions, in an acceptable time span, with high yields and high specific activities. Special attention has been drawn to 2-fluoroethyl and 3-fluoropropyl groups, which are often the active sites of radiofluorinated compounds. Precursors containing an ammonium leaving group – such as a strained azetidinium or aziridinium moiety – can help to overcome these obstacles leading to a convenient and mild introduction of [18F]fluoride with high radiochemical yields.  相似文献   
2.
A detailed study of the geometry, aromatic character, electronic and magnetic properties for a series of positively charged N-doped polycyclic aromatic hydrocarbons (PAHs) was performed. Magnetic properties of the examined molecules were analyzed by means of the magnetically induced current density calculated using the diamagnetic-zero version of the continuous transformation of origin of current density (CTOCD-DZ) method. The comparative study of the local aromaticity of the studied molecules was performed using several different indices: energy effect (ef), harmonic oscillator model of aromaticity (HOMA) index, six centre delocalization index (SCI) and nucleus independent chemical shifts (NICS). The presence of N-atoms in the inner rings was found to cause a planarity distortion in the studied N-doped systems. The geometric changes and charged nature of the studied N-doped systems do not significantly influence the current density and the local aromaticity distribution in comparison with the corresponding parent benzenoid hydrocarbons. The present study demonstrates how quantum chemical calculations can be used for rational design of novel PAHs and for fine tuning of their properties.  相似文献   
3.
Let G be a finite group, H be a proper subgroup of G, and S be a unitary subring of C. The kernel of the restriction map S[Irr(G)] → S[Irr(H)] as a ring homomorphism is studied. As a corollary, the main result in [Isaacs, I. M. and Navarro, G., Injective restriction of characters, Arch. Math., 108, 2017, 437–439] is reproved.  相似文献   
4.
Let R be an associative unital ring and not necessarily commutative.We analyze conditions under which every n × n matrix A over R is expressible as a sum A =E1 +…+ Es + N of (commuting) idempotent matrices Ei and a nilpotent matrix N.  相似文献   
5.
Application of rotary tillage has been increased due to less tillage passes required, reduced draft, and greater efficiency through reduction in wheel slippage. Early failure of the bearing of tractor power take-off (PTO) shaft was observed in tractors of power range 30–35 horsepower during rotary tillage. An instrumentation setup involving an extended octagonal ring transducer (EORT) was developed and installed at the bottom of the bearing to measure the axial load and the vertical component of the radial load. The horizontal component of radial load was measured by strain gauges. Based on measured loads, the bearing life was assessed. Independent variables were: operating depth, number of blades, gear setting, engine speed, and tyre size. The average axial and radial loads varied from 786–3869 N, and 134–430 N, respectively. However, bearing experienced very high peak loads during each trial. The peak axial and radial loads was recorded between 1081–7534 N and 566–1794 N, respectively. The estimated bearing life based on peak loads was 171.98–28341.39 h. Based on the findings, it may be concluded that the average loads were not sufficient to cause quick failure of PTO bearing, rather sudden peak loads might be the root cause of early failure.  相似文献   
6.
介绍了一种使用钢环和碳纤维复合材料环共同预紧方式的两面顶超高压模具,该结构在全钢环两面顶模具的基础上,使用一层碳纤维复合材料环代替最外层钢环,得到了一种具有碳纤维复合材料环的超高压模具。这种设计避免了大直径钢环难以制造加工的问题,形成一种以钢环与复合材料环共同对压缸预紧的新型预紧方式。数值分析表明:该模具结构设计具有可行性,可以在一定程度上减小压缸的周向应力、最大剪切应力和等效应力。此外,对碳纤维复合材料环进行了失效判别。  相似文献   
7.
We quantify the nonclassicality of multimode bosonic field states by adopting an information-theoretic approach involving the Wigner-Yanase skew information. The fundamental properties of the quantifier such as convexity, superadditivity, monotonicity, and conservation relations are revealed. The quantifier is illustrated by a variety of typical examples, and applications to the quantification of nonclassical correlations are discussed. Various extensions are indicated.  相似文献   
8.
We consider the dynamics and formation of vortices from ring dark solitons in a two-dimensional Bose–Einstein condensate with the Rashba spin–orbit coupling based on the time-dependent coupled Gross–Pitaevskii equation. Compared with previous results, the system exhibits complex dynamical behaviors in the presence of the spin–orbit coupling. With the modulation of the spin–orbit coupling, not only the lifetime of ring dark solitons is greatly prolonged, but also their attenuation kinetics is significantly affected. For two shallow ring dark solitons with the equal strength of the spin–orbit coupling, the radius of ring dark solitons increases to a maximum value over time and then shrinks into a minimum value. Due to the effect of the snake instability, ring dark solitons split into a series of ring-like clusters of vortex pairs, which perform complex oscillations. This indicates that the system is strongly dependent on the presence of the spin–orbit coupling. Furthermore, the effect of different initial modulation depths on the dynamics of ring dark solitons is investigated.  相似文献   
9.
刘嘉成  吴超  夏功榆  郑骑林  朱志宏  徐平 《中国物理 B》2022,31(1):14201-014201
We designed a reconfigurable dual-interferometer coupled silicon nitride microring resonator.By tuning the integrated heater on interferometer's arms,the"critical coupling"bandwidth of resonant mode is continuously adjustable whose quality factor varies from 7.9×104 to 1.9×105 with the extinction ratio keeping higher than 25 dB.Also a variety of coupling spanning from"under-coupling"to"over-coupling"were achieved,showing the ability to tune the quality factor from 6.0×103 to 2.3×105.Our design can provide an adjustable filtering method on silicon nitride photonic chip and contribute to optimize the nonlinear process for quantum photonics and all-optical signal processing.  相似文献   
10.
An sp2-sp3 hybrid carbon allotrope named HSH-carbon is proposed by the first-principles calculations. The structure of HSH-carbon can be regarded as a template polymerization of [1.1.1]propellane molecules in a hexagonal lattice, as well as, an AA stacking of recently reported HSH-C10 consisting of carbon trigonal bipyramids. Based on calculations, the stability of this structure is demonstrated in terms of the cohesive energy, phonon dispersion, Born−Huang stability criteria, and ab initio molecular dynamics. HSH-carbon is predicted to be a semiconductor with an indirect energy gap of 3.56 eV at the PBE level or 4.80 eV at the HSE06 level. It is larger than the gap of Si and close to the gap of c-diamond, which indicates HSH-carbon is potentially an ultrawide bandgap semiconductor. The effective masses of carriers in the VB and CB edge are comparable with wide bandgap semiconductors such as GaN and ZnO. The elastic behavior of HSH-carbon such as bulk modulus, Young’s modulus and shear modulus is comparable with that of T-carbon and much smaller than that of c-diamond, which suggests that HSH-carbon would be much easier to be processed than c-diamond in practice.  相似文献   
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