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Kento Nishikibe Keisuke Nishikawa Momochika Kumagai Matsumi Doe Yoshiki Morimoto 《化学:亚洲杂志》2022,17(1):e202101137
There are marine cytotoxic bromotriterpenoids, named the thyrsiferol family that are structurally characterized by some tetrahydropyran (THP) and tetrahydrofuran (THF) rings. The thyrsiferol family belongs to natural products that are often difficult to determine their stereostructures even by the current, highly advanced spectroscopic methods, especially in acyclic systems including stereogenic tetrasubstituted carbon centers. In such cases, it is effective to predict and synthesize the possible stereostructures. Herein, to elucidate ambiguous stereostructures and unassigned absolute configurations of aplysiol B, laurenmariannol, and saiyacenol A, members of the thyrsiferol family, we carried out their asymmetric chemical syntheses featuring 6-exo and 5-exo oxacyclizations of epoxy alcohol precursors and 6-endo bromoetherification of a bishomoallylic alcohol. In this paper, we report total assignments of their stereostructures through their asymmetric chemical syntheses and also their preliminary cytotoxic activities against some tumor cells. These results could not have been achieved without depending on asymmetric total synthesis. 相似文献
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Konstantinos Tsouvalas 《代数通讯》2018,46(8):3397-3412
We define Euler characteristics on classes of residually finite and virtually torsion free groups and we show that they satisfy certain formulas in the case of amalgamated free products and HNN extensions over finite subgroups. These formulas are obtained from a general result which applies to the rank gradient and the first L2?Betti number of a finitely generated group. 相似文献
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Dong Zhang 《Discrete Mathematics》2018,341(1):25-32
In this paper, we reveal the connection between the independent number of a graph and the topological multiplicity of the maximal eigenvalue of the corresponding graph 1-Laplacian. The pseudo independent number of a graph is introduced, which provides a better lower estimate of the topological multiplicity of the maximum eigenvalue. The technique of our proof is based on the localization property of the eigenvector for graph 1-Laplacian, the Krasnoselski genus, and its relation to the topological join. 相似文献