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排序方式: 共有1533条查询结果,搜索用时 15 毫秒
1.
《Journal of Pure and Applied Algebra》2022,226(8):107024
We solve a combinatorial question concerning eigenvalues of the universal intertwining endomorphism of a subset representation. 相似文献
2.
Dr. Peter B. Karadakov Dr. Shohei Saito 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(24):9312-9314
The simple anti-aufbau DFT approach for estimating singlet excited state aromaticity suggested in a recent Communication published in this journal is shown to produce incorrect results because it targets a linear combination of the singlet and triplet configurations involving the HOMO and LUMO rather than the first singlet excited state. If the S1 state of a molecule is dominated by the HOMO→LUMO excitation, a comparably simple but theoretically consistent and qualitatively correct approximation to the S1 wavefunction can be achieved by performing a small “two electrons in two orbitals” CASSCF(2,2) calculation which can be followed by the evaluation of magnetic aromaticity criteria such as NICS. 相似文献
3.
量子疤痕是波函数在经典不稳定周期轨道周围反常凝聚的一种量子或波动现象.人们对疤痕态的量子化条件进行了大量研究,对深入理解半经典量子化起到了一定的促进作用.之前大部分研究工作主要集中在硬墙量子弹球上,即给定边界形状的无穷深量子势阱系统.本文研究具有光滑复杂势场的二维量子弹球系统,考察疤痕态的量子化条件及其重复出现的规律,得到了与硬墙弹球不一样的结果,对理解这类现象是一个有益的补充.这些结果将有助于理解具有无规长程杂质分布的二维电子系统的态密度谱和输运行为. 相似文献
4.
5.
Mourad Kainane Mezadek Mohamed Kainane Mezadek Michael Reissig 《Mathematical Methods in the Applied Sciences》2020,43(6):3117-3147
In this paper, we study the global (in time) existence of small data solutions to the Cauchy problem for the semilinear wave equation with friction, viscoelastic damping, and a power nonlinearity. We are interested in the connection between regularity assumptions for the data and the admissible range of exponents p in the power nonlinearity. 相似文献
6.
Accuracy arguments are the en vogue route in epistemic justifications of probabilism and further norms governing rational belief. These arguments often depend on the fact that the employed inaccuracy measure is strictly proper. I argue controversially that it is ill-advised to assume that the employed inaccuracy measures are strictly proper and that strictly proper statistical scoring rules are a more natural class of measures of inaccuracy. Building on work in belief elicitation I show how strictly proper statistical scoring rules can be used to give an epistemic justification of probabilism.An agent's evidence does not play any role in these justifications of probabilism. Principles demanding the maximisation of a generalised entropy depend on the agent's evidence. In the second part of the paper I show how to simultaneously justify probabilism and such a principle. I also investigate scoring rules which have traditionally been linked with entropies. 相似文献
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8.
This paper presents a framework for incorporating arbitrary implicit multistep schemes into the lattice Boltzmann method. While the temporal discretization of the lattice Boltzmann equation is usually derived using a second-order trapezoidal rule, it appears natural to augment the time discretization by using multistep methods. The effect of incorporating multistep methods into the lattice Boltzmann method is studied in terms of accuracy and stability. Numerical tests for the third-order accurate Adams-Moulton method and the second-order backward differentiation formula show that the temporal order of the method can be increased when the stability properties of multistep methods are considered in accordance with the second Dahlquist barrier. 相似文献
9.
Wei Qin Rishabh Jain Francisco C. Robles Hernández Prof. Dr. Jeffrey D. Rimer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(23):5893-5898
Zeolite crystals can be used as seeds or aluminosilicate sources in syntheses to control polymorphs and/or reduce the quantity of organics used as structure-directing agents. A frequently invoked hypothesis for interzeolite transformations is that zeolites share some underlying similarity in structure, most notably in cases pertaining to organic-free syntheses. Herein, we show for the first time that ZSM-5 (MFI) can be directly obtained from USY (FAU) through an interzeolite transformation between parent–daughter structures lacking common building units in the absence of a structure-directing agent and seeds. We show that interzeolite transformation leads to a crystalline product with fewer defects. Our findings also reveal that ZSM-5 is a metastable intermediate that undergoes further transformation to mordenite (MOR) and quartz. The MFI-to-MOR transition is counter to reported trends for which transformations lead to structures with reduced molar volume. Herein, we propose mechanistic arguments that suggest the driving force for interzeolite transformation is more complex than guidelines posited in the literature. 相似文献
10.
《Physics letters. A》2020,384(28):126725
Everettian Quantum Mechanics, or the Many Worlds Interpretation, lacks an explanation for quantum probabilities. We show that the values given by the Born rule equal projection factors, describing the contraction of Lebesgue measures in orthogonal projections from the complex line of a quantum state to eigenspaces of an observable. Unit total probability corresponds to a complex Pythagorean theorem: the measure of a subset of the complex line is the sum of the measures of its projections on all eigenspaces.Postulating the existence of a continuum infinity of identical quantum universes, all with the same quasi-classical worlds, we show that projection factors give relative amounts of worlds. These appear as relative frequencies of results in quantum experiments, and play the role of probabilities in decisions and inference. This solves the probability problem of Everett's theory, allowing its preferred basis problem to be solved as well, and may help settle questions about the nature of probability. 相似文献