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以天然长叶薄荷酮[R-( )-Pulegone]为起始原料,经过一系列立体选择性化学反应步骤,成功地建立了3个手性中心,从而完成了具有抗艾滋病活性Didemnaketals类似物的关键中间体3,7-二甲基-5,6-二羟基-辛-7-烯醛中间体的合成,发现PCC与三级氧醇8-9的非对映选择性反应,使得9被完全氧化,而8以93%的产率回收,其de值高达98%。 相似文献
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Tiffany Burch 《代数通讯》2013,41(8):3622-3625
A converse to Lie's theorem for Leibniz algebras is found and generalized. The result is used to find cases in which the generalized property, called triangulable, is 2-recognizable; that is, if all 2-generated subalgebras are triangulable, then the algebra is also. Triangulability joins solvability, supersolvability, strong solvability, and nilpotentcy as a 2-recognizable property for classes of Leibniz algebras. 相似文献
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Let G be a group and πe(G) the set of element orders of G.Let k∈πe(G) and m k be the number of elements of order k in G.Letτe(G)={mk|k∈πe(G)}.In this paper,we prove that L2(16) is recognizable byτe (L2(16)).In other words,we prove that if G is a group such that τe(G)=τe(L2(16))={1,255,272,544,1088,1920},then G is isomorphic to L2(16). 相似文献
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Let G be a group and πe(G) the set of element orders of G.Let k∈πe(G) and m k be the number of elements of order k in G.Letτe(G)={mk|k∈πe(G)}.In this paper,we prove that L2(16) is recognizable byτe (L2(16)).In other words,we prove that if G is a group such that τe(G)=τe(L2(16))={1,255,272,544,1088,1920},then G is isomorphic to L2(16). 相似文献
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