首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5305篇
  免费   700篇
  国内免费   302篇
化学   1856篇
晶体学   26篇
力学   179篇
综合类   61篇
数学   2174篇
物理学   2011篇
  2023年   70篇
  2022年   104篇
  2021年   164篇
  2020年   156篇
  2019年   147篇
  2018年   129篇
  2017年   148篇
  2016年   160篇
  2015年   130篇
  2014年   278篇
  2013年   541篇
  2012年   345篇
  2011年   325篇
  2010年   355篇
  2009年   360篇
  2008年   384篇
  2007年   387篇
  2006年   286篇
  2005年   250篇
  2004年   211篇
  2003年   218篇
  2002年   128篇
  2001年   119篇
  2000年   99篇
  1999年   103篇
  1998年   86篇
  1997年   81篇
  1996年   78篇
  1995年   73篇
  1994年   52篇
  1993年   60篇
  1992年   45篇
  1991年   34篇
  1990年   28篇
  1989年   28篇
  1988年   21篇
  1987年   16篇
  1986年   15篇
  1985年   25篇
  1984年   14篇
  1983年   6篇
  1982年   6篇
  1981年   8篇
  1980年   8篇
  1979年   4篇
  1978年   6篇
  1977年   3篇
  1975年   4篇
  1974年   4篇
  1969年   1篇
排序方式: 共有6307条查询结果,搜索用时 15 毫秒
1.
设G=(V,E)是一个连通图.称一个边集合S■E是一个k限制边割,如果G-S的每个连通分支至少有k个顶点.称G的所有k限制边割中所含边数最少的边割的基数为G的k限制边连通度,记为λ_k(G).定义ξ_k(G)=min{[X,■]:|X|=k,G[X]连通,■=V(G)\X}.称图G是极大k限制边连通的,如果λ_k(G)=ξ_k(G).本文给出了围长为g>6的极大3限制边连通二部图的充分条件.  相似文献   
2.
Integrated information theory (IIT) provides a mathematical framework to characterize the cause-effect structure of a physical system and its amount of integrated information (Φ). An accompanying Python software package (“PyPhi”) was recently introduced to implement this framework for the causal analysis of discrete dynamical systems of binary elements. Here, we present an update to PyPhi that extends its applicability to systems constituted of discrete, but multi-valued elements. This allows us to analyze and compare general causal properties of random networks made up of binary, ternary, quaternary, and mixed nodes. Moreover, we apply the developed tools for causal analysis to a simple non-binary regulatory network model (p53-Mdm2) and discuss commonly used binarization methods in light of their capacity to preserve the causal structure of the original system with multi-valued elements.  相似文献   
3.
We provide an example of a strictly subcritical multiclass queueing network which is unstable under the least attained service (LAS) service protocol. It is a reentrant line with two servers and six customer classes. The customer interarrival times in our system are bounded below and have finite exponential moments, while the corresponding service times are deterministic. As a special case, we obtain a deterministic, strictly subcritical unstable LAS network.  相似文献   
4.
Hui Chen 《中国物理 B》2022,31(9):97405-097405
Recently, the discovery of vanadium-based kagome metal AV3Sb5 (A= K, Rb, Cs) has attracted great interest in the field of superconductivity due to the coexistence of superconductivity, non-trivial surface state and multiple density waves. In this topical review, we present recent works of superconductivity and unconventional density waves in vanadium-based kagome materials AV3Sb5. We start with the unconventional charge density waves, which are thought to correlate to the time-reversal symmetry-breaking orders and the unconventional anomalous Hall effects in AV3Sb5. Then we discuss the superconductivity and the topological band structure. Next, we review the competition between the superconductivity and charge density waves under different conditions of pressure, chemical doping, thickness, and strains. Finally, the experimental evidence of pseudogap pair density wave is discussed.  相似文献   
5.
The commonly used multi-center initiation methods always lead to the formation of quantities of homopolymer in the surface tailoring based on reverse atom transfer radical polymerization (ATRP) and reversible addition-fragmentation chain-transfer (RAFT) polymerization. In this study, a monocenter redox pair constructed of silica bearing tert-butyl hydroperoxide groups and ascorbic acid (SiO2-TBHP/AsAc) was applied to substitute the commonly used initiation method of R-supported RAFT grafting polymerization. All the propagating radicals were restricted on the surface of solid particles during the whole procedure theoretically, resulting in a higher grafting efficiency of 95.1% combined with the “controllable” feature at 10 h. This redox pair was also used to initiate the reverse ATRP in miniemulsion successfully with a grafting efficiency of 86.3% at 10 h. The grafting efficiency obtained under this monocenter initiation method was significantly higher than that of the frequently reported surface modification by reverse ATRP and RAFT polymerization. In addition, the high-efficient surface tailoring was traced and confirmed by nuclear magnetic resonance, Fourier transform infrared, X-ray photoelectron spectroscopy, thermogravimetric analysis, transmission electron microscopy, and other analysis tests. The advantage of this monocenter redox pair will open a new avenue for the potential “high-efficient” surface tailoring of various materials.  相似文献   
6.
在准化学模型框架下, 假设有序原子对同时具有可区分与不可区分的双重属性, 首先构造了双重短程有序准化学模型, 然后讨论了该模型所能满足的各类理论极限. 经总结提炼, 提出了有序原子对的对立统一理论. 基于该理论, 进一步将双重短程有序准化学模型做了一般化推广, 开发了多重短程有序准化学模型. 该模型能够有效描述二元熔体中存在多重短程有序构型时的热力学行为. 选取了至少存在两重短程有序构型的Bi-K熔体来检验模型的合理性和可靠性. 结果表明, 除配位数外, 只需4个模型参数就能合理再现该二元熔体所有的热化学数据.  相似文献   
7.
采用聚醚改性三硅氧烷表面活性剂、 丙烯酸酯改性硅油和水3种组分制备了稳定的油包水(W/O)乳液, 经酸碱催化水解、 紫外引发聚合和干燥除水过程得到了双网络多孔有机硅弹性体. 扫描电子显微镜(SEM)分析结果表明, 所制备的有机硅弹性体具有丰富的孔径结构分布. 压缩强度测试结果表明, 弹性体具备良好的耐压缩性能, 45%压缩应变下循环50次, 仍具备良好的回弹性能. 有机硅弹性体具有优异的耐高温性能, 分解温度为370 ℃, 高于绝大多数多孔有机硅弹性体材料的分解温度. 丙烯酸酯改性硅油的制备工艺成熟、 廉价易得, 显著降低了多孔有机硅弹性体的生产成本, 为规模性开发有机硅材料提供了新的思路和应用前景.  相似文献   
8.
Heteroaryl boronic acids and esters are extremely important and valuable intermediates because of their wide application in the synthesis of marketed drugs and bioactive compounds. Over the last couple of decades, the construction of highly important heteroaryl carbon-boron bonds has created huge attention. The transition-metal-free protocols are more green, less sensitive to air and moisture, and also economically advantageous over the transition-metal-based protocols. The transition-metal-free C−H borylation of heteroarenes and C−X (X=halogen) borylation of heteroaryl halides represents an excellent approach for their synthesis. Also, various cyclization and alkyne activation protocols have been recently established for their synthesis. The goal of this review article is to summarize the existing literature and the current state of the art for transition-metal-free synthesis of heteroaryl boronic acid and esters.  相似文献   
9.
Hai-Zhu Pan 《中国物理 B》2022,31(12):120701-120701
Benefiting from the development of hyperspectral imaging technology, hyperspectral image (HSI) classification has become a valuable direction in remote sensing image processing. Recently, researchers have found a connection between convolutional neural networks (CNNs) and Gabor filters. Therefore, some Gabor-based CNN methods have been proposed for HSI classification. However, most Gabor-based CNN methods still manually generate Gabor filters whose parameters are empirically set and remain unchanged during the CNN learning process. Moreover, these methods require patch cubes as network inputs. Such patch cubes may contain interference pixels, which will negatively affect the classification results. To address these problems, in this paper, we propose a learnable three-dimensional (3D) Gabor convolutional network with global affinity attention for HSI classification. More precisely, the learnable 3D Gabor convolution kernel is constructed by the 3D Gabor filter, which can be learned and updated during the training process. Furthermore, spatial and spectral global affinity attention modules are introduced to capture more discriminative features between spatial locations and spectral bands in the patch cube, thus alleviating the interfering pixels problem. Experimental results on three well-known HSI datasets (including two natural crop scenarios and one urban scenario) have demonstrated that the proposed network can achieve powerful classification performance and outperforms widely used machine-learning-based and deep-learning-based methods.  相似文献   
10.
Vehicular communication networks are emerging as a promising technology to provide high-quality internet service such as entertainment for road users via infrastructure-to-vehicle (I2V) communication, and to guarantee road users’ safety via vehicle-to-vehicle (V2V) communication. Some technical issues that impact the performance of these networks are the lack of or poor communication paths between vehicles, and the limitation of radio resources. Unmanned aerial vehicles (UAVs) as promising solutions for supporting vehicular networks could provide communication coverage in hazardous environments and areas with no capacities for installation or maintenance of ground base stations (BSs). Also, non-orthogonal multiple access (NOMA) methods can improve spectral and energy efficiency and thereby allow more users to be connected to the desired network. In this paper, exploring the NOMA, we develop a scheme for optimum resource allocation in presence of a UAV that supports vehicular communications. Resource allocation for this scenario is formulated as a mixed-integer non-linear programming (MINLP) problem. Due to the high complexity of such problems, we propose two low-complexity near-optimal methods. First, we apply difference-of-concave-functions (DC) approximations to solve the problem in an iterative process. Next, we use Stackelberg game-based method for efficient solving, and then, closed-form expressions of optimal power allocations using KKT-conditions are derived. Simulations illustrate the effectiveness of the proposed scheme along with the Stackelberg game-based method.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号