材料表征方法理论与实践课程的改革与建设*

通过与超星专业慕课制作团队合作搭建网络教学平台,将线上慕课教学与线下实验教学相结合,对材料表征方法理论与实践课程进行了全方位的改革。与传统实验教学相比,改革后的课程不仅能够激发学生的学习兴趣,实现时间空间的相对自由,还可以完善考核机制,提升教学质量,从而为高校化学研究生实验课程的改革提供一定的借鉴意义。     

Additive Hermitian idempotent preservers between operator algebras

Let L be an additive map between (real or complex) matrix algebras sending $n\times n$ Hermitian idempotent matrices to $m\times m$ Hermitian idempotent matrices. We show that there are nonnegative integers $p,q$ with $n(p+q)=r\le m$ and an $m\times m$ unitary matrix U such that$L(A)=U[(I_p?A)\oplus (I_q?A^t)\oplus 0_{m?r}]U^{?},\text{for any}n\times n\text{Hermitian}A\text{with rational trace}.$ We also extend this result to the (complex) von Neumann algebra setting, and provide a supplement to the Dye-Bunce-Wright Theorem asserting that every additive map of Hermitian idempotents extends to a Jordan ?-homomorphism.     

Some extensions of the operator entropy type inequalities

In this paper, we define the generalised relative operator entropy and investigate some of its properties such as subadditivity and homogeneity. As application of our result, we obtain the information inequality. In continuation, we establish some reverses of the operator entropy inequalities under certain conditions by using the Mond–Pe?ari? method.     

Equivalences among Z2s-linear Hadamard codes

The ${\mathbb{Z}}_{2^s}$-additive codes are subgroups of ${\mathbb{Z}}_{2^s}^n$, and can be seen as a generalization of linear codes over ${\mathbb{Z}}_2$ and ${\mathbb{Z}}_4$. A ${\mathbb{Z}}_{2^s}$-linear Hadamard code is a binary Hadamard code which is the Gray map image of a ${\mathbb{Z}}_{2^s}$-additive code. A partial classification of these codes by using the dimension of the kernel is known. In this paper, we establish that some ${\mathbb{Z}}_{2^s}$-linear Hadamard codes of length $2^t$ are equivalent, once $t$ is fixed. This allows us to improve the known upper bounds for the number of such nonequivalent codes. Moreover, up to $t=11$, this new upper bound coincides with a known lower bound (based on the rank and dimension of the kernel). Finally, when we focus on $s\in \{2,3\}$, the full classification of the ${\mathbb{Z}}_{2^s}$-linear Hadamard codes of length $2^t$ is established by giving the exact number of such codes.     

A novel chaotic image encryption scheme using DNA sequence operations

In this paper, we propose a novel image encryption scheme based on DNA (Deoxyribonucleic acid) sequence operations and chaotic system. Firstly, we perform bitwise exclusive OR operation on the pixels of the plain image using the pseudorandom sequences produced by the spatiotemporal chaos system, i.e., CML (coupled map lattice). Secondly, a DNA matrix is obtained by encoding the confused image using a kind of DNA encoding rule. Then we generate the new initial conditions of the CML according to this DNA matrix and the previous initial conditions, which can make the encryption result closely depend on every pixel of the plain image. Thirdly, the rows and columns of the DNA matrix are permuted. Then, the permuted DNA matrix is confused once again. At last, after decoding the confused DNA matrix using a kind of DNA decoding rule, we obtain the ciphered image. Experimental results and theoretical analysis show that the scheme is able to resist various attacks, so it has extraordinarily high security.     

Incompressible fluid flow simulations with flow rate as the sole information at synthetic inflow and outflow boundaries

In numerically simulating heat and mass transport processes in an unconfined domain involving synthetic open (inflow and/or outflow) boundaries, how to properly specify flow conditions at these boundaries can become a challenging issue. In this work, within the context of a pressure‐based finite volume method under an unstructured grid, a solution procedure without the need for explicit specification of flow profiles at any of these boundaries when simulating incompressible fluid flow is proposed and numerically examined. Within this methodology, the flow at any open boundary is not necessarily assumed to be unidirectional or fully developed; indeed, the sole information required is the mass flow rate crossing the boundary. As a result, one can select the specific region of interest to perform simulations, rather than having to artificially increase the flow domain so as to invoke fully developed flow at all open boundaries. This not only greatly reduces computational costs (both in terms of memory requirements and simulation run‐time) but provides the means to engage with flow problems, which otherwise cannot be solved with currently available methods for handling the flow conditions at open boundaries. The proposed methodology is demonstrated by simulating laminar flow of an incompressible fluid in a two‐dimensional planar channel with a 90° T‐branch, a known inflow rate, and flow splits for the two outflow channels. The results obtained by placing the entrance and the two exits at different locations show that the flow behavior predicted is completely unaffected by using a highly truncated domain. Copyright © 2015 John Wiley & Sons, Ltd.     

OCS分子在128 nm附近的光解动力学研究：S(3PJ=2,1,0)、S(1D2)以及S(1S0)产物通道

本文利用时间切片离子成像技术对OCS分子进行了真空紫外波段的光解动力学研究. 在四个光解光波长(从129.32到126.08 nm)下测量了硫原子解离产物S(³P_J=2,1,0)、S(¹D₂)、S(¹S₀)的速度影像，并从中清晰地发现了四个主要的解离产物通道：S(³P_J=2,1,0)+CO(X¹Σ⁺)，S(³P_J=2,1,0)+CO(A³π)，S(¹D₂)+CO(X¹Σ⁺)和S(¹S₀)+CO(X¹Σ⁺). 在实验影像中，产物CO分子的部分振动态结构能够得到分辨. 实验还获取解离产物总平动能谱，产物分支比和角分布. 对实验结果进行分析显示除绝热解离通道S(³P_J=2,1,0)+CO(A³π)之外，在其他三个产物通道中非绝热效应都起到非常重要的作用.