Phosphine‐Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds

The lability of B=B, B?P, and B–halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes undergo cleavage of all six of their central bonds in different ways, leading to products of B=B hydrogenation and dihalogenation as well as halide exchange.     

基于不确定理论的铁路货运需求预测

合理预测铁路货运需求是铁路管理部门建设、运营等决策基础。为应对铁路货运需求的复杂变化,基于Pearson相关性分析方法筛选出铁路货运需求的七个具有关键影响的因素,并结合不确定理论建立不确定多元线性回归模型,相应的铁路货运预测结果由传统单一值变成可能的需求区间范围,更加符合处于不确定环境下的铁路货运需求实际情况。选取国家统计局2004~2016年相关数据进实证研究,并与回归模型以及BP模型的预测结果对比分析,实验表明不确定多元线性回归的预测结果更加精确。     

基于广义WOWA算子的Pythagorean模糊决策方法

针对Pythagorean模糊信息的决策问题,构建广义Pythagorean模糊信息加权有序加权平均(PF-GWOWA)算子。首先,提出PF-GWOWA算子,并证明Pythagorean模糊广义加权平均(PF-GWA)算子、Pythagorean模糊加权有序加权平均(PF-WOWA)算子与Pythagorean模糊加权平均(PF-WA)算子均为PF-GWOWA算子的特例;其次,根据GWOWA算子属性综合权重计算模型,利用PF-GWOWA算子对信息进行集结;最后,通过算例分析和传统方法对比,说明本文提出方法的合理性与有效性。     

利用电磁法研究HMX与TATB混合钝感炸药的冲击起爆特性

为研究含有少量奥克托金(HMX)且以三氨基三硝基苯(TATB)为基的高能钝感炸药PBX-3的冲击起爆反应增长规律,采用火炮驱动蓝宝石飞片的方法和铝基组合式电磁粒子速度计技术进行了一维平面冲击实验。通过实验测量撞击表面及内部不同深度处的冲击波后粒子速度,得到PBX-3炸药的Hugoniot关系。根据冲击波示踪器所测数据绘制了炸药到爆轰的时间-距离(x-t)图,获得了反映炸药冲击起爆性能的Pop关系。将入射压力为12.964 GPa时达到爆轰的6条速度曲线修整成相同零点,通过读取6条曲线的分离点即反应区末端的C-J点,计算出化学反应区时间和宽度。     

由多平衡态快子系统所诱发的簇发振荡及机理

通过引入子电路模块, 并选取适当的参数及非线性电阻特性, 建立了多时间尺度下具有多平衡态的四维广义哈特利(Hartley) 电路模型. 基于快子系统的多平衡态及其稳定性, 给出了参数空间的分岔集, 得到了不同区域中的动力学特性及其相应的分岔模式和临界条件. 针对两种典型具有不同分岔特征的情形, 分别给出了多平衡态参与下的两种不同的周期簇发振荡行为, 结合快子系统的分岔分析, 揭示了沉寂态和激发态之间相互转化的产生机制, 指出多平衡态不仅会导致多种沉寂态和激发态同时参与同一周期簇发振荡, 也会导致簇发振荡模式的多样性.     

Multiple Scattering Between Adjacent Sound Sources in Head-Related Transfer Function Measurement System

To accelerate head-related transfer functions (HRTFs) measurement, two or more independent sound sources are usually employed in the measurement system. However, the multiple scattering between adjacent sound sources may influence the accuracy of measurement. On the other hand, the directivity of sound source could induce measurement error. Therefore, a model consisting of two spherical sound sources with approximate omni-directivity and a rigid-spherical head is proposed to evaluate the errors in HRTF measurement caused by multiple scattering between sources. An example of analysis using multipole re-expansion indicates that the error of ipsilateral HRTFs are within the bound of ± 1.0 dB below a frequency of 20 kHz, provided that the sound source radius does not exceed 0.025 m, the source distance relative to head center is not less than 0.5 m, and the angular interval between two adjacent sources is not less than 20 degrees. Similar conclusions under different conditions can also be analyzed and discussed by using this calculation method. Furthermore, the results are verified by measurements of HRTFs for a rigid sphere and a KEMAR artificial head.     

Photo-Controlled Macroscopic Self-Assembly Based on Photo-Switchable Hetero-Complementary Quadruple Hydrogen Bonds

A photo-switchable hetero-complementary quadruple H-bonding array, which consists of an azobenzene-derived ureidopyrimidinone (UPy) module ( Azo-UPy ) and a nonphotoactive diamidonaphthyridine (DAN) derivative ( Napy-1 ), is constructed based on a reversible photo-locking approach. Upon UV (390 nm)/Vis (460 nm) light irradiations, photo-switchable quadruple H-bonded dimerization between Azo-UPy and Napy-1 can be achieved with exhibiting 4.8×10⁴-fold differences in binding strength (ON/OFF ratios). Furthermore, smart polymeric gels with unique photo-controlled macroscopic self-assembly behavior can be fabricated by introducing such quadruple H-bonding array as photo-regulable noncovalent interfacial connections.     

A modified model for isothermal homogeneous and heterogeneous reactions in the boundary-layer flow of a nanofluid

The homogeneous and heterogeneous reactions in the boundary-layer of a flat surface are considered. The autocatalysts are assumed to be of regular sizes, while the solution is a dilute nanofluid. The heat release due to the chemical reactions is taken into account. The Buongiorno's model is used to describe the behaviors of this reaction system. This configuration makes the current model be different from all previous publications. Multiple solutions are given numerically to the rescaled nonlinear system, whose stability is verified. The results show that the strength coefficients of the homogeneous and heterogeneous reactions are key factors to cause the appearance of the multiple solutions in the distribution of the chemical reactions. Nanofluids enhance the diffusion of heat and help maintain the stability of chemical reactions.     

基于改进VIKOR方法的地震应急物资运输决策问题研究

地震灾害应急救援物资方案的合理选择对与减少人员伤亡,降低灾民的财产损失具有重要影响。本文针对属性权重未知情形下的地震应急物资运输方案决策问题,提出了一种Pythagorean模糊不确定语言与前景理论相结合的改进VIKOR决策方法,即PFUL-PT-VIKOR法。首先,采用Pythagorean模糊不确定语言用于描述和融合专家对地震应急物资运输方案在考虑多种属性影响下的感知信息;其次,利用主客观融合法对属性权重进行求解;然后,提出基于前景理论的改进VIKOR法并得出方案排序;最后,通过算例分析,对所提出方法的有效性和实践性给予验证。结果表明,PFUL-PT-VIKOR模型有助于增强决策专家对不确定突发情景信息感知的知识表示能力,解决属性赋权过于主观或过分依赖样本的困难,并突围了应急决策者隐性心理行为较难定量应用的思维定势,增强了模型的现实适用性,为地震应急物资是否合理运输提供决策支持。