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汉防己甲素是防己科千金藤属植物粉防己中分离提取的双苄基异喹啉类生物碱,已作为临床药物用于抗风湿及阵痛、抗肺癌、抗矽肺。基于粉防己产量的限制及汉防己甲素的需求量增加,深入开展汉防己甲素的全合成研究势在必行。本文按照合成策略,对汉防己甲素的全合成方法进行了综述。   相似文献   
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The purpose of this investigation is to theoretically shed some light on the effect of the unsteady electroosmotic flow (EOF) of an incompressible fractional second-grade fluid with low-dense mixtures of two spherical nanoparticles, copper, and titanium. The flow of the hybrid nanofluid takes place through a vertical micro-channel. A fractional Cattaneo model with heat conduction is considered. For the DC-operated micropump, the Lorentz force is responsible for the pressure difference through the microchannel. The Debye-Hükel approximation is utilized to linearize the charge density. The semi-analytical solutions for the velocity and heat equations are obtained with the Laplace and finite Fourier sine transforms and their numerical inverses. In addition to the analytical procedures, a numerical algorithm based on the finite difference method is introduced for the given domain. A comparison between the two solutions is presented. The variations of the velocity heat transfer against the enhancements in the pertinent parameters are thoroughly investigated graphically. It is noticed that the fractional-order parameter provides a crucial memory effect on the fluid and temperature fields. The present work has theoretical implications for biofluid-based microfluidic transport systems.

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In this paper, we consider the existence and uniqueness of solutions to time-varying delays stochastic fractional differential equations (SFDEs) with non-Lipschitz coefficients. By using fractional calculus and stochastic analysis, we can obtain the existence result of solutions for stochastic fractional differential equations.  相似文献   
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There are marine cytotoxic bromotriterpenoids, named the thyrsiferol family that are structurally characterized by some tetrahydropyran (THP) and tetrahydrofuran (THF) rings. The thyrsiferol family belongs to natural products that are often difficult to determine their stereostructures even by the current, highly advanced spectroscopic methods, especially in acyclic systems including stereogenic tetrasubstituted carbon centers. In such cases, it is effective to predict and synthesize the possible stereostructures. Herein, to elucidate ambiguous stereostructures and unassigned absolute configurations of aplysiol B, laurenmariannol, and saiyacenol A, members of the thyrsiferol family, we carried out their asymmetric chemical syntheses featuring 6-exo and 5-exo oxacyclizations of epoxy alcohol precursors and 6-endo bromoetherification of a bishomoallylic alcohol. In this paper, we report total assignments of their stereostructures through their asymmetric chemical syntheses and also their preliminary cytotoxic activities against some tumor cells. These results could not have been achieved without depending on asymmetric total synthesis.  相似文献   
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The first total synthesis of resveratrone and iso-resveratrone based on an epoxide olefination approach is described. The pivotal reaction proceeds by insertion of the lithiated epoxide into a boronic ester and subsequent syn-elimination. Resveratrone has been described to have remarkable photophysical properties, including two-photon absorption. Therefore, an azide derivative has been prepared to allow for use as a biological label.  相似文献   
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The pivotal aim of the present work is to find the numerical solution for fractional Benney–Lin equation by using two efficient methods, called q ‐homotopy analysis transform method and fractional natural decomposition method. The considered equation exemplifies the long waves on the liquid films. Projected methods are distinct with solution procedure and they are modified with different transform algorithms. To illustrate the reliability and applicability of the considered solution procedures we consider eight special cases with different initial conditions. The fractional operator is considered in Caputo sense. The achieved results are drowned through two and three‐dimensional plots for different Brownian motions and classical order. The numerical simulations are presented to ensure the efficiency of considered techniques. The behavior of the obtained results for distinct fractional order is captured in the present framework. The outcomes of the present investigation show that, the considered schemes are efficient and powerful to solve nonlinear differential equations arise in science and technology.  相似文献   
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In this paper, we study the Holder regularity of weak solutions to the Dirichlet problem associated with the regional fractional Laplacian (-△)αΩ on a bounded open set Ω ■R(N ≥ 2) with C(1,1) boundary ■Ω. We prove that when f ∈ Lp(Ω), and g ∈ C(Ω), the following problem (-△)αΩu = f in Ω, u = g on ■Ω, admits a unique weak solution u ∈ W(α,2)(Ω) ∩ C(Ω),where p >N/2-2α and 1/2< α < 1. To solve this problem, we consider it into two special cases, i.e.,g ≡ 0 on ■Ω and f ≡ 0 in Ω. Finally, taking into account the preceding two cases, the general conclusion is drawn.  相似文献   
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