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1.
One of the most common problems in wounds is delayed healing and complications such as infection. Therefore, the need for novel materials accelerates the healing of wounds especially abdominal wounds after surgery besides high efficiency and safety is mandatory. The rate of wound healing, anti-inflammatory and biocompatibility of Zn-Al LDH (Zn-Al layer double hydroxide) alone and loaded with Curcumin (Zn-Al LDH/Curcumin) was screened via in-vivo assays through intramuscular implantation in rat abdominal wall with intact peritoneum cavity. The implanted drugs were formed through Curcumin loaded into LDH of Zn-Al with drug release of 56.78 ± 1.51% within 24 h. The synthesized nanocomposite was characterized by (TGA/DTA) thermal analysis, (XRD) X-ray diffraction, (FESEM) Field emission scanning electron microscopy, (HRTEM) high resolution transmission electron microscope, energy dispersive X-ray (EDX) and low-temperature N2 adsorption, pore volume and average pore size distribution. The integrity of blood circulation, inflammatory signs, wound healing rate, capacity of tissue integration, antigenicity and composite biocompatibility, auto fluorescence ability of collagen bundles and the tensile strength of the muscle were assessed histopathologically after 7 and 30 days’ post-implantation. Excellent wound healing ability was achieved with shortest length between the wound gap edges and higher tensile strength of the muscle. Besides emit florescence very well followed by good healing and tensile muscles strength in Curcumin while very low strength with scar formation in Zn-Al LDH/Curcumin in both acute and chronic wound. No signs of inflammation in Curcumin & Zn-Al LDH. No vessels obstruction or bleeding observed in both Zn-Al LDH and Curcumin more than Zn-Al LDH/Curcumin and control which examined through candling. Good healing & infiltrated immune cells in same groups through histopathological examination. This work supports the anti-inflammatory, wound healing and biocompatibility of both LDH and Curcumin with living matter, increasing their biomedical applications in this era with safety and increasing efficacy with prolonged drug release.  相似文献   
2.
The surface charge is a key concept in electrochemistry. Mathematically, the surface charge is obtained from a spatial integration of the volume charge along a particular direction. Ambiguities thus arise in choosing the starting and ending points of the integration. As for electrocatalytic interfaces, the presence of chemisorbates further complicates the situation. In this minireview, I adopt a definition of the surface charge within a continuum picture of the electric double layer. I will introduce surface charging behaviors of firstly ordinary electrochemical interfaces and then electrocatalytic interfaces featuring partially charged chemisorbates. Particularly, the origin of nonmonotonic surface charging behaviors of electrocatalytic interfaces is explained using a primitive model. Finally, a brief account of previous studies on the nonmonotonic surface charging behavior is presented, as a subline of the spectacular history of electric double layer.  相似文献   
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已有研究表明,在“日常生活世界”形成的群体身份认同能提升人们的主观幸福感。作为对当前社会快速变化的一种回应,背包旅行能提供展露自我的“自由空间”,建构独特的背包客身份认同。为探明背包客在“旅游世界”建构的身份认同是否显著提升其主观幸福感这一问题,基于社会认同理论和自我决定理论,将自尊作为中介变量,检验了背包客身份认同与主观幸福感之间的关系。通过问卷调查(n=400)收集数据,运用结构方程模型偏最小二乘法(PLS-SEM)进行统计分析。发现:(1)背包客身份认同的自我归类维度、群体自我价值维度对主观幸福感有显著正向影响;(2)群体自我评价维度、群体自我价值维度对自尊具有显著正向影响;(3)自尊对主观幸福感也有显著正向影响,且自尊在群体自我价值影响主观幸福感的过程中起部分中介作用。所得结果丰富了旅游者幸福感与背包客身份认同的理论研究。  相似文献   
5.
Zhengran Wang 《中国物理 B》2022,31(4):48202-048202
Excited-state double proton transfer (ESDPT) in the 1-[(2-hydroxy-3-methoxy-benzylidene)-hydrazonomethyl]-naphthalen-2-ol (HYDRAVH2) ligand was studied by the density functional theory and time-dependent density functional theory method. The analysis of frontier molecular orbitals, infrared spectra, and non-covalent interactions have cross-validated that the asymmetric structure has an influence on the proton transfer, which makes the proton transfer ability of the two hydrogen protons different. The potential energy surfaces in both S0 and S1 states were scanned with varying O-H bond lengths. The results of potential energy surface analysis adequately proved that the HYDRAVH2 can undergo the ESDPT process in the S1 state and the double proton transfer process is a stepwise proton transfer mechanism. Our work can pave the way towards the design and synthesis of new molecules.  相似文献   
6.
为解决单一的小波神经网络预测精度不高的问题,提出一种新的基于小波去噪和WNN-ARIMA组合模型,应用小波阈值去噪法对小波神经网络的输入值进行预处理,同时对模型残差值进行ARIMA模型修正.利用该组合模型对洮河流域下巴沟站年径流量进行预测,预测趋势和预测值与原始实测数据吻合度高,表明此组合模型可靠性强,可以有效预测年径流量,以期为洮河流域和其他流域的年径流量预测提供新方法,为水利工程建设和水资源优化配置提供依据.  相似文献   
7.
Ion-selective water treatment is needed to address emerging problems in an energy- and cost-efficient manner. Capacitive deionization (CDI) is a membraneless water treatment technology, which relies on storing ions in charged electric double layers (EDLs) of micropores. CDI has shown remarkable selectivity, with local density approximations (LDAs) showing some success in guiding selective separations. However, many underlying processes are represented by lumped fitting parameters in LDA models, hindering further progress. Atomistic models help unravel selectivity mechanisms, but are difficult to integrate with cell-level CDI theory. Here, we review and extend LDA models for CDI, highlight a knowledge gap in connecting between LDA and atomistic models for CDI, and emphasize and build upon analogies between micropore EDLs and nanofiltration membranes.  相似文献   
8.
相比传统的弹簧法等方法,基于球松弛算法的动网格松弛法在复杂边界大变形条件下可以得到质量更高的边界网格以及更大的极限变形量,但该方法在时间效率上还有提升的空间。引入二重网格,采用动网格松弛法进行稀疏网格的网格变形,将边界位移传递到整个网格计算域;再利用二重网格映射,将稀疏网格位移映射到原有计算网格的节点上。算例表明,改进后的动网格松弛法在极限变形量和变形后网格质量基本保持不变的情况下,能够有效地提高网格变形的计算效率。此外还研究了二重网格的粗细网格节点数之比(粗网格为稀疏网格,细网格为原计算网格)对网格变形的影响,算例表明最佳计算效率出现在粗细网格节点数之比为0.5左右时。  相似文献   
9.
Herein, we report a facile method for synthesizing MoCo-layered double hydroxide (LDH) nanosheets employing Prussian blue analog (PBA) as the precursor. The introduction of Mo in Co-LDH modulates the electronic structure, increases the number of active sites and electrochemical surface area to improve the hydrogen evolution, oxygen evolution, and overall water splitting activity. As a result, PBA-derived Mo0.25Co0.75-LDH nanosheets demonstrated 10 mA cm?2 current density at only 220 mV and 115 mV overpotentials for OER and HER, respectively. The overall water splitting was attained at 1.52 V cell voltage for 10 mA cm?2 current density.  相似文献   
10.
In this study, the Pauli blocking potential between two colliding nuclei in the density overlapping region is applied to describe the heavy nuclei fusion process. Inspired by the Pauli blocking effect in the \begin{document}$ \alpha $\end{document}-decay of heavy nuclei, the Pauli blocking potential of single nucleon from the surrounding matter is obtained. In fusion reactions with strong density overlap, the Pauli blocking potential between the projectile and target can be constructed using a single folding model. By considering this potential, the double folding model with a new parameter set is employed to analyze the fusion processes of 95 systems. A wider Coulomb barrier and shallower potential pocket are formed in the inner part of the potential between the two colliding nuclei, compared to that calculated using the Akyüz-Winther potential. The fusion hindrance phenomena at deep sub-barrier energies are described well for fusion systems \begin{document}$ ^{16} $\end{document}O + \begin{document}$ ^{208} $\end{document}Pb and \begin{document}$ ^{58} $\end{document}Ni + \begin{document}$ ^{58} $\end{document}Ni.  相似文献   
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