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1.
Recently, the visible-light photoredox decarboxylative couplings of N-(acyloxy)phthalimides (NHPI esters) and its derivatives have become an efficient chemical transformation. Under visible light, the NHPI esters undergo a single-electron transfer (SET) process to afford the corresponding carbon or nitrogen radicals that participate in many chemical transformations. The photoredox decarboxylative couplings have been applied to achieve construction of an array of carbon–carbon and carbon–heteroatom bonds as well as the synthesis of carbocycles and heterocycles. This review categorises photocatalysts, discusses the application and catalysis mechanisms of NHPI esters, and details recent progress in this field.  相似文献   
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《Comptes Rendus Physique》2015,16(10):986-993
Deciphering the mechanisms at play in the formation and evolution of the large-scale structure of the universe is part of the scientific goals of many projects of observational cosmology. In particular, large-scale structure observations can be used to infer mode-coupling effects, whether they come from the physics of the early universe or from its late time evolution. Specificities of such couplings are presented, noting that in principle they can be directly detected through bispectra of the cosmic microwave background temperature anisotropies or density in the local universe. The existence of such couplings have however more far-reaching consequences for the growth of the structure. Those are sketched as well as their possible observational impacts.  相似文献   
4.
We study a family of directed random graphs whose arcs are sampled independently of each other, and are present in the graph with a probability that depends on the attributes of the vertices involved. In particular, this family of models includes as special cases the directed versions of the Erd?s‐Rényi model, graphs with given expected degrees, the generalized random graph, and the Poissonian random graph. We establish a phase transition for the existence of a giant strongly connected component and provide some other basic properties, including the limiting joint distribution of the degrees and the mean number of arcs. In particular, we show that by choosing the joint distribution of the vertex attributes according to a multivariate regularly varying distribution, one can obtain scale‐free graphs with arbitrary in‐degree/out‐degree dependence.  相似文献   
5.
In this review, methods to obtain the orientational order of topologically variant molecular mesogens using by one- and two-dimensional (2D) solid-state 13C nuclear magnetic resonance (NMR) spectroscopy are described. Besides 13C chemical shifts, the 13C─1H dipolar couplings measured from 2D-separated local field (SLF) technique are used for computing the order parameters of a variety of mesogens. The investigated molecules are composed of a variable number of rings in the core, that is, core ranging from simply one ring to five rings. Among the mesogens investigated, a special focus has been placed on mesogens with thiophene rings, which are gaining popularity as liquid crystalline organic semiconductors. The replacement of a phenyl ring by thiophene in the core has a dramatic influence on molecular topology, as observed from the measured order parameters. The review highlights the advantages of the 2D SLF method for understanding the local dynamics and for mapping the topology of mesogens through the measured order parameters. SLF NMR studies of as many as 24 molecular mesogens that vary in terms of the molecular structure as well as topology are covered in the review. Order parameters of the rings have been estimated from the 13C─1H dipolar couplings in the nematic, smectic A, smectic C, and tilted hexatic phases as well as in B1 and B2 mesophases of various mesogens. It is anticipated that, in the years to come, the 2D SLF method would provide advanced molecular information on structurally complex mesogens that are emerging in liquid crystal science through the incessant efforts of synthetic chemists. The mini review covers the orientational order of topologically variant molecular mesogens determined by 1D and 2D solid-state 13C NMR spectroscopy. Accordingly, rod-like, bent-core, and thiophene mesogens were subjected to 2D SLF measurements to get the order parameters from which the topology was established. The replacement of phenyl ring by thiophene and its influence on order parameters as well as on molecular topology is also discussed.  相似文献   
6.
In this paper, novel multi-layer networks with superior couplings are proposed firstly which are established on a non-strongly connected digraph. Within the multi-layer networks, a nonlinear coupling based on white noises is introduced, which is the feature of superior couplings. We adopt aperiodically adaptive intermittent pinning control to stabilize the multi-layer networks. An concrete analysis framework about selecting the target vertex of the control is revealed. Aperiodically adaptive intermittent control is employed on the vertex systems of the first layer networks, to achieve the stabilization of the first layer networks, where the couplings of drift terms are treated as negative effects on stabilization. With the help of noise stabilization, the stabilization of the other layers networks is realized based on the stability of the first layer networks and the characteristics of the superior coupling that is based on white noises. By employing graph theory and the Lyapunov method, an almost sure exponential stabilization criterion of the multi-layer networks is acquired. As a subsequent result, the proposed theory is applied to a class of stochastic coupled oscillators with sufficient conditions being given to ensure their stability. Finally, a numerical example is provided to illustrate the feasibility of the stated theoretical results.  相似文献   
7.
This review demonstrates the multiple roles of surfactants in aqueous micellar catalysis. It covers the design and recent applications of proline-based amphiphile PS-750-M, including completely organic solvent-free amide couplings, C–H fluorination of arenes and heteroarenes achieved via radical pathway facilitated by the shielding effect of micelles. In addition, it critically sheds light on selective hydrogenolysis and cross-couplings of water-sensitive acid chlorides in water, catalyzed by phosphine ligand-free Pd (0) nanoparticles. The metal-micelle interaction responsible for catalytic activities as probed by various spectroscopic techniques is also discussed.  相似文献   
8.
We observed that the planar aligned nematic liquid crystal (5CB) doped with a volume fraction of 1% of FeTPPCl [5,10,15,20-tetraphenylporphyriniron(III)chloride] or MnTPPCl [5,10,15,20-tetraphenylporphyrinmanganese(III)chloride] dramatically decreased the critical magnetic field for the magnetic field induced Freedericksz transition, while 5CB doped with ZnTPP [5,10,15,20-tetraphenylporphyrinzinc(II)] revealed no such effect, when compared with pure 5CB. In the guest-host (5CB) system, FeTPPCl and MnTPPCl as guests are both strong paramagnetic materials with an interaction through coordination of the -CN group in 5CB onto the metal ion of the porphyrin. As a result, the 5CB molecules are dragged to reorientate under a static magnetic field, while ZnTPP is a diamagnetic material without such a property. This phenomenon concerning magneto-optical components could be useful in liquid crystal displays.  相似文献   
9.
We provide criteria for the strong ergodicity of regime-switching diffusion processes. Our conditions are imposed on the coefficients of the processes. Particularly, we show that for regime-switching diffusions on the half line, if the corresponding diffusion on each fixed environment is strongly ergodic, then the regime-switching diffusion is strongly ergodic as well, which does not depend on the changing rate of the environment. Moreover, the converse is not always true, which is shown by an example. For transience, recurrence and positive recurrence, there is no such good consistency [R. Pinsky and M. Scheutzow, Some remarks and examples concerning the transience and recurrence of random diffusions, Ann. Inst. Henri. Poincaré 28 (1992) 519–536].  相似文献   
10.
密度矩阵重正化群的异构并行优化   总被引:1,自引:0,他引:1       下载免费PDF全文
魏含玉  夏铁成 《物理学报》2013,62(12):120202-120202
密度矩阵重正化群方法(DMRG)在求解一维强关联格点模型的基态时可以获得较高的精度,在应用于二维或准二维问题时,要达到类似的精度通常需要较大的计算量与存储空间.本文提出一种新的DMRG异构并行策略,可以同时发挥计算机中央处理器(CPU)和图形处理器(GPU)的计算性能.针对最耗时的哈密顿量对角化部分,实现了数据的分布式存储,并且给出了CPU和GPU之间的负载平衡策略.以费米Hubbard模型为例,测试了异构并行程序在不同DMRG保留状态数下的运行表现,并给出了相应的性能基准.应用于4腿梯子时,观测到了高温超导中常见的电荷密度条纹,此时保留状态数达到104,使用的GPU显存小于12 GB.  相似文献   
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