托卡马克中局域磁扰动引起的高能量离子损失研究

基于单粒子导心运动代码ORBIT，采用测试粒子模拟方法，研究了托卡马克等离子体内部不同径向位置处局域磁场扰动对高能量离子的损失的影响。研究表明，在局域磁扰动主要分布在某磁面附近、其环向具有类似纹波场形式下，可造成一些靠近等离子体中心区域的高能量离子损失，但对靠近等离子边界的离子损失影响相对不大。这些损失的高能量离子均为捕获离子，离子的投掷角越大就越容易损失。此外，造成高能量离子最大损失率的局域场径向位置与这些损失离子的初始径向位置通常存在一定的偏移，而且这个偏移与这些离子的能量密切相关。当局域场出现在某些位置时，能量较低的离子会有一定的损失，能量较高的离子反而不会损失。     

Decision and approximation complexity for identifying codes and locating-dominating sets in restricted graph classes

An identifying code is a subset of vertices of a graph with the property that each vertex is uniquely determined (identified) by its nonempty neighbourhood within the identifying code. When only vertices out of the code are asked to be identified, we get the related concept of a locating-dominating set. These notions are closely related to a number of similar and well-studied concepts such as the one of a test cover. In this paper, we study the decision problems Identifying Code and Locating-Dominating Set (which consist in deciding whether a given graph admits an identifying code or a locating-dominating set, respectively, with a given size) and their minimization variants Minimum Identifying Code and Minimum Locating-Dominating Set. These problems are known to be NP-hard, even when the input graph belongs to a number of specific graph classes such as planar bipartite graphs. Moreover, it is known that they are approximable within a logarithmic factor, but hard to approximate within any sub-logarithmic factor. We extend the latter result to the case where the input graph is bipartite, split or co-bipartite: both problems remain hard in these cases. Among other results, we also show that for bipartite graphs of bounded maximum degree (at least 3), the two problems are hard to approximate within some constant factor, a question which was open. We summarize all known results in the area, and we compare them to the ones for the related problem Dominating Set. In particular, our work exhibits important graph classes for which Dominating Set is efficiently solvable, but Identifying Code and Locating-Dominating Set are hard (whereas in all previous works, their complexity was the same). We also introduce graph classes for which the converse holds, and for which the complexities of Identifying Code and Locating-Dominating Set differ.     

Versatile ligands for high-performance liquid chromatography: An overview of ionic liquid-functionalized stationary phases

Ionic liquids (ILs), a class of unique substances composed purely by cation and anions, are renowned for their fascinating physical and chemical properties, such as negligible volatility, high dissolution power, high thermal stability, tunable structure and miscibility. They are enjoying ever-growing applications in a great diversity of disciplines.     

Coating properties of a novel water stationary phase in capillary supercritical fluid chromatography

The coating properties of a novel water stationary phase used in capillary supercritical fluid chromatography were investigated. The findings confirm that increasing the length or internal diameter of the type 316 stainless‐steel column used provides a linear increase in the volume of stationary phase present. Under normal operating conditions, results indicate that about 4.9 ± 0.5 μL/m of water phase is deposited uniformly inside of a typical 250 μm internal diameter 316 stainless‐steel column, which translates to an area coverage of about 6.3 ± 0.5 nL/mm² regardless of dimension. Efforts to increase the stationary phase volume present showed that etching the stainless‐steel capillary wall using hydrofluoric acid was very effective for this. For instance, after five etching cycles, this volume doubled inside of both the type 304 and the type 316 stainless‐steel columns examined. This in turn doubled analyte retention, while maintaining good peak shape and column efficiency. Overall, 316 stainless‐steel columns were more resistant to etching than 304 stainless‐steel columns. Results indicate that this approach could be useful to employ as a means of controlling the volume of water stationary phase that can be established inside of the stainless‐steel columns used with this supercritical fluid chromatography technique.     

新解色谱现象

在客观分析色谱现象的基础上对色谱分离机理的传统解释提出了质疑和否定,并对色谱分离机理作出了新的解释。通过对色谱现象的研究和分析,不仅确定了一条流体运动的基本规律,还对固定相赋予了新的内涵,提出了能量场固定相的设想。由于对色谱分离原理进行了新的解释,因此对色谱现象提出了一个新的定义。