全文获取类型
收费全文 | 567篇 |
免费 | 34篇 |
国内免费 | 229篇 |
专业分类
化学 | 105篇 |
晶体学 | 1篇 |
力学 | 11篇 |
综合类 | 7篇 |
数学 | 630篇 |
物理学 | 76篇 |
出版年
2023年 | 10篇 |
2022年 | 5篇 |
2021年 | 8篇 |
2020年 | 20篇 |
2019年 | 13篇 |
2018年 | 15篇 |
2017年 | 11篇 |
2016年 | 31篇 |
2015年 | 18篇 |
2014年 | 13篇 |
2013年 | 73篇 |
2012年 | 14篇 |
2011年 | 19篇 |
2010年 | 22篇 |
2009年 | 31篇 |
2008年 | 49篇 |
2007年 | 38篇 |
2006年 | 52篇 |
2005年 | 48篇 |
2004年 | 46篇 |
2003年 | 39篇 |
2002年 | 38篇 |
2001年 | 44篇 |
2000年 | 32篇 |
1999年 | 28篇 |
1998年 | 30篇 |
1997年 | 20篇 |
1996年 | 27篇 |
1995年 | 6篇 |
1994年 | 2篇 |
1993年 | 5篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1987年 | 1篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1978年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有830条查询结果,搜索用时 15 毫秒
1.
A *-ring R is called a nil *-clean ring if every element of R is a sum of a projection and a nilpotent.Nil *-clean rings are the *-version of nil-clean rings introduced by Diesl.This paper is about the nil *-clean property of rings with emphasis on matrix rings.We show that a *-ring R is nil *-clean if and only if J(R) is nil and R/J(R) is nil*-clean.For a 2-primal *-ring R,with the induced involution given by (aij)* =(a*ij)T,the nil *-clean property of Mn(R) is completely reduced to that of Mn(Z2).Consequently,Mn(R) is not a nil *-clean ring for n =3,4,and M2(R) is a nil *-clean ring if and only if J(R) is nil,R/J(R) is a Boolean ring and a*-a ∈ J(R) for all a ∈ R. 相似文献
2.
Yuji Naruse Atsushi Takamori Itsuki Nagasawa 《Phosphorus, sulfur, and silicon and the related elements》2020,195(7):523-525
AbstractWe previously designed and prepared the first molecules to exhibit observable CD spectra by n-σ* excitation, 2,6-dithiaspiro[3.3]heptane 2,6-dioxide. Spiro[3.3]heptane frameworks possess axial asymmetry due to puckering of 2 four-membered rings; the ring bonds are rich in p-character due to acute bond angles, which lowers the σ* energy levels. In contrast, the lone pairs are rich in s-character, which results in a good donor with conformational fixation. We expected that, instead of lone pairs as donating orbitals, the use of σ-electron-donating Si-Si bonds should result in UV absorption in the observable range (>180?nm), so that the Cotton effect could appear, at least partially, in that range. We designed 2,6-disilyl-2,6-disilaspiro[3.3]heptanes as models, and performed theoretical calculations to confirm our idea. 相似文献
3.
Synthesis,spatial structure and spectral properties of pyrylo‐4 (thio) squaraines variously substituted in cyclobutene moiety 下载免费PDF全文
Vladimir V. Kurdyukov Aleksei I. Tolmachev Marina L. Dekhtyar Yurii G. Vlasenko Aleksandr N. Chernega 《Journal of Physical Organic Chemistry》2015,28(7):452-459
Synthetic routes have been developed to a number of (thio) squaraine dyes containing the residues of CH‐acids at the central cyclobutene ring. The electronic and spatial structure as well as the chemical conversions and optical behaviour of the compounds obtained have been studied both theoretically and by X‐ray diffraction analysis, 1H NMR and electronic spectroscopy. As shown, the electronic nature and sterical characteristics of the central ring substituents give rise to some general conformational features and crystal packing regularities and also govern the spectral position of the first π–π* absorption band. The structure–property relationships established in the study provide guidance for the purposeful design of deeply coloured (thio) squaraines. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
4.
The effect of Fe on the phase and magnetocaloric property of LaFe11.6*xSi1.4B0.1 alloys with x = 1.0–1.4 have been studied. The results show that the excess of Fe will make the α-Fe phases increase, but the easy corrosion LaFeSi phase reduces in LaFe11.6*xSi1.4B0.1 alloys. All LaFe11.6*xSi1.4B0.1 alloys keep the first-order magnetic phase transition. The saturation magnetizations of LaFe11.6*xSi1.4B0.1 alloys with x > 1 are much higher than LaFe11.6Si1.4B0.1 alloy under 2T magnetic field. This results in the maximum isothermal magnetic entropy changes, and the relative cooling power of LaFe11.6*xSi1.4B0.1 alloys is bigger than for LaFe11.6Si1.4B0.1 alloys. 相似文献
5.
Characterizations of ( m,n )-Jordan Derivations and ( m,n )-Jordan Derivable Mappings on Some Algebras 下载免费PDF全文
Let R be a ring, M be a R-bimodule and m, n be two fixed nonnegative integers with m + n = 0. An additive mapping δ from R into M is called an(m, n)-Jordan derivation if(m +n)δ(A~2) = 2 mAδ(A) + 2nδ(A)A for every A in R. In this paper, we prove that every(m, n)-Jordan derivation with m = n from a C*-algebra into its Banach bimodule is zero. An additive mappingδ from R into M is called a(m, n)-Jordan derivable mapping at W in R if(m + n)δ(AB + BA) =2mδ(A)B + 2 mδ(B)A + 2 nAδ(B) + 2 nBδ(A) for each A and B in R with AB = BA = W. We prove that if M is a unital A-bimodule with a left(right) separating set generated algebraically by all idempotents in A, then every(m, n)-Jordan derivable mapping at zero from A into M is identical with zero. We also show that if A and B are two unital algebras, M is a faithful unital(A, B)-bimodule and U = [A M N B] is a generalized matrix algebra, then every(m, n)-Jordan derivable mapping at zero from U into itself is equal to zero. 相似文献
6.
Jordan operator algebras are norm‐closed spaces of operators on a Hilbert space with for all . In two recent papers by the authors and Neal, a theory for these spaces was developed. It was shown there that much of the theory of associative operator algebras, in particular, surprisingly much of the associative theory from several recent papers of the first author and coauthors, generalizes to Jordan operator algebras. In the present paper we complete this task, giving several results which generalize the associative case in these papers, relating to unitizations, real positivity, hereditary subalgebras, and a couple of other topics. We also solve one of the three open problems stated at the end of our earlier joint paper on Jordan operator algebras. 相似文献
7.
本文研究了具有卷积的中心自反环的性质,定义并引入了中心-自反环,显然,中心-自反环是自反环、中心自反环和-自反环的推广.给出了这类环的一些特征,研究了相关的环扩张,包括平凡扩张,Dorroh扩张和多项式扩张. 相似文献
8.
Nadica Mihajlović 《代数通讯》2020,48(4):1803-1818
AbstractIn this paper, we have focused our study on the acute perturbation of the group inverse for the elements of Banach algebra with respect to the spectral radius. We also give perturbation analysis for the core inverse in C*- algebra. The perturbation bounds for the core inverse under some conditions are presented. Additionally, this paper extends the results obtained in [11, 14]. 相似文献
9.
Julia Post Vanessa Kogel Anja Schaffrath Philipp Lohmann N. Jon Shah Karl-Josef Langen Dieter Willbold Antje Willuweit Janine Kutzsche 《Molecules (Basel, Switzerland)》2021,26(6)
Amyotrophic lateral sclerosis (ALS) is a progressive neurodegenerative disease characterised by selective neuronal death in the brain stem and spinal cord. The cause is unknown, but an increasing amount of evidence has firmly certified that neuroinflammation plays a key role in ALS pathogenesis. Neuroinflammation is a pathological hallmark of several neurodegenerative disorders and has been implicated as driver of disease progression. Here, we describe a treatment study demonstrating the therapeutic potential of a tandem version of the well-known all-d-peptide RD2 (RD2RD2) in a transgenic mouse model of ALS (SOD1*G93A). Mice were treated intraperitoneally for four weeks with RD2RD2 vs. placebo. SOD1*G93A mice were tested longitudinally during treatment in various behavioural and motor coordination tests. Brain and spinal cord samples were investigated immunohistochemically for gliosis and neurodegeneration. RD2RD2 treatment in SOD1*G93A mice resulted not only in a reduction of activated astrocytes and microglia in both the brain stem and lumbar spinal cord, but also in a rescue of neurons in the motor cortex. RD2RD2 treatment was able to slow progression of the disease phenotype, especially the motor deficits, to an extent that during the four weeks treatment duration, no significant progression was observed in any of the motor experiments. Based on the presented results, we conclude that RD2RD2 is a potential therapeutic candidate against ALS. 相似文献
10.
Let A and B be two factor von Neumann algebras. For A, B ∈ A, define by [A, B]_*= AB-BA~*the skew Lie product of A and B. In this article, it is proved that a bijective map Φ : A → B satisfies Φ([[A, B]_*, C]_*) = [[Φ(A), Φ(B)]_*, Φ(C)]_*for all A, B, C ∈ A if and only if Φ is a linear *-isomorphism, or a conjugate linear *-isomorphism, or the negative of a linear *-isomorphism, or the negative of a conjugate linear *-isomorphism. 相似文献