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S. A. Koldobskiy O. Adriani G. A. Bazilevskaya G. C. Barbarino R. Bellotti E. A. Bogomolov M. Boezio V. Bonvicini M. Bongi S. Bottai A. Bruno A. Vacchi E. Vannuccini G. I. Vasilyev S. A. Voronov A. M. Galper C. De Santis V. Di Felice G. Zampa N. Zampa M. Casolino D. Campana A. V. Karelin P. Carlson G. Castellini F. Cafagna A. A. Kvashnin A. N. Kvashnin S. V. Koldashov S. Y. Krutkov A. A. Leonov A. G. Mayorov V. V. Malakhov M. Martucci L. Marcelli W. Menn M. Merge V. V. Mikhailov E. Mocchiutti A. Monaco N. Mori R. Munini G. Osteria B. Panico P. Papini P. Picozza M. Pearce M. Ricci S. B. Ricciarini M. F. Runtso M. Simon R. Sparvoli P. Spillantini Y. I. Stozhkov Y. T. Yurkin 《Bulletin of the Russian Academy of Sciences: Physics》2017,81(2):151-153
The preliminary results from measurements of deuteron fluxes in galactic cosmic rays (GCR) in the vicinity of the Earth in 2006–2009 are presented. The results are obtained by analyzing data from the PAMELA experiment aboard the Resurs DK-1 satellite. High-precision detection instruments provided an opportunity to identify GCR deuterons and measure their spectrum in the energy interval of 90–650MeV/nucleon. Spectra averaged over six-month intervals from the summer of 2006 to the summer of 2009 (the solar activity minimum) are presented. The influence of solar modulation on the observed spectrum is clearly seen in the results. 相似文献
4.
Jie Guo Seng Ghee Tan Mansoor Bin Abdul Jalil Dax Enshan KohGuchang Han Hao Meng 《Journal of magnetism and magnetic materials》2011,323(1):83-87
The effect of itinerant spin moment (m) dynamic in spin transfer switching has been ignored in most previous theoretical studies of the magnetization (M) dynamics. Thus in this paper, we proposed a more refined micromagnetic model of spin transfer switching that takes into account in a self-consistent manner of the coupled m and M dynamics. The numerical results obtained from this model further shed insight on the switching profiles of m and M, both of which show particular sensitivity to parameters such as the anisotropy field, the spin torque field, and the initial deviation between m and M. 相似文献
5.
Cleaning the surfaces of the as-deposited Ge2Sb2Te5 was studied by X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and X-ray diffraction (XRD). The mixed native oxides on the as-deposited Ge2Sb2Te5 surface can be easily removed by dipping Ge2Sb2Te5 in de-ionized water for 1 min, while the surface morphology remains unchanged after cleaning. Native oxides only re-grow after exposure to air for more than 4 min. Although dipping in water leads to a surface layer deficient in Ge and Sb, the surface composition of Ge2Sb2Te5 can recover to its stoichiometric value after annealing at 200 °C in vacuum. The phase remains amorphous at room temperature after dipping in water, and changes to fcc and hcp after annealing at 100 and 220 °C, respectively. 相似文献
6.
B. Aslibeiki H. Salamati T. Tahmasebi 《Journal of magnetism and magnetic materials》2010,322(19):2929-9985
Nanosized MnFe2O4 ferrites were synthesized by a simple method, which is based on the solid state ball-milling and calcinations of nitrate precursors and citric acid. The samples were characterized by using different methods. The results indicate that the products mainly consist of MnFe2O4 nanoparticles. The effect of different annealing temperatures on particle sizes and crystallinity of the samples was also studied. By increasing the particle size, the coercivity and magnetization of the samples increase. The increase of magnetization by increasing the crystallite size could be attributed to the lower surface spin canting and surface spin disorder of the larger magnetic nanoparticles. Our analysis of ac susceptibility measurements shows that the interparticle magnetic interaction leads to the superspin glass-like behavior in these nanoparticle samples. 相似文献
7.
Mehdi Janbazi Yavar T. Azar Farhood Ziaie Khashayar Ghandi Chérif F. Matta Muhammad Shadman Lakmehsari 《International journal of quantum chemistry》2020,120(12):e26211
Alanine is used as a transfer standard dosimeter for gamma ray and electron beam calibration. An important factor affecting its dosimetric response is humidity which can lead to errors in absorbed dose calculations. Ab initio molecular dynamics calculations were performed to determine the environmental effects on the electron paramagnetic resonance (EPR) parameters of L-α-alanine radicals in acidic and alkaline solutions. A new result, not dissimilar to the closed-shell amino acid molecule alanine, is that the non-zwitterionic form of the alanine radical is the stable form in the gas phase while the zwitterionic neutral alanine radical is not a stable structure in the gas phase. Geometric and EPR parameters of radicals in both gas and solution phases are found to be dependent on hydrogen bonding of water molecules with the polar groups and on dynamic solvation. Calculations on the optimized free radicals in the gas phase revealed that for the neutral radical, hydrogen bonding to water molecules drives a decrease in the magnitudes of g-tensor components g xx and g yy without affecting neither g zz component nor the hyperfine coupling constants (HFCCs). The transfer from the gas to solution phase of the alanine radical anion is accompanied with an increase in the spin density on the carboxylic group's oxygen atoms. However, for the neutral radical, this transfer from gas to solution phase is accompanied with the decrease in the spin density on oxygen atoms. Calculated isotropic HFCCs and g-tensor of all radicals are in good agreement with experiment in both acidic and alkaline solutions. 相似文献
8.
In this research, the main emphasis has been focused on the preparation of a novel Fe3O4-supported propane-1-sulfonic acid-grafted graphene oxide quantum dots (Fe3O4@GOQD-O-(propane-1-sulfonic acid)) that it was readily synthesized via a five-step procedure as a hitherto unreported magnetic nanocatalyst. This newly prepared Fe3O4@GOQD-O-(propane-1-sulfonic acid) nanocomposite was structurally well-established by different analytical techniques including Fourier transform infrared (FT-IR), X-ray diffraction (XRD), energy-dispersive X-ray (EDX), thermal gravimetric analysis (TGA), field emission gun-scanning electron microscope (FESEM), high-resolution transmission electron microscopy (HRTEM) and vibrating sample magnetometer (VSM) analyses. The high catalytic performance of this nanocomposite was exhibited in one-pot synthesis of dihydropyrano[2,3-c]pyrazole and 4H-chromene derivatives under mild conditions. Low reaction times, excellent yields of the products, benignity of the catalyst, easy reaction work-up and magnetic recyclability of the catalyst are the main advantages of the present protocol. Also, our research indicated that the Fe3O4@GOQD-O-(propane-1-sulfonic acid) could be reused up to five times without considerable loss of catalytic activity. 相似文献
9.
Dr. Yanbo Mei Prof. Dr. Xiaodan Chen Dr. Rui Wei Dr. Xiao-Yong Chang Prof. Dr. Lizhi Tao Prof. Dr. Liu Leo Liu 《Angewandte Chemie (International ed. in English)》2023,62(52):e202315555
Featuring an extra electron in the π* antibonding orbital, species with a 2-center-3-electron (2c3e) π bond without an underlying σ bond are scarcely known. Herein, we report the synthesis, isolation and characterization of a radical anion salt [K(18-C-6)]+{[(HCNDipp)2Si]2P2}⋅− (i.e. [K(18-C-6)]+ 3 ⋅−) (18-C-6=18-crown-6, Dipp=2,6-diisopropylphenyl), in which 3 ⋅− features a perfectly planar Si2P2 four-membered ring. This species represents the first example of a Si- and P-containing analog of a bicyclo[1.1.0]butane radical anion. The unusual bonding motif of 3 ⋅− was thoroughly investigated via X-ray diffraction crystallography, electron paramagnetic resonance spectroscopy (EPR), and calculations by density functional theory (DFT), which collectively unveiled the existence of a 2c3e π bond between the bridgehead P atoms and no clearly defined supporting P−P σ bond. 相似文献
10.
Minkyu Kim Moon Jong Han Hansol Lee Paraskevi Flouda Daria Bukharina Kellina J. Pierce Katarina M. Adstedt Madeline L. Buxton Young Hee Yoon William T. Heller Srikanth Singamaneni Vladimir V. Tsukruk 《Angewandte Chemie (International ed. in English)》2023,62(30):e202305646
Chiral metal–organic frameworks (MOFs) have gained rising attention as ordered nanoporous materials for enantiomer separations, chiral catalysis, and sensing. Among those, chiral MOFs are generally obtained through complex synthetic routes by using a limited choice of reactive chiral organic precursors as the primary linkers or auxiliary ligands. Here, we report a template-controlled synthesis of chiral MOFs from achiral precursors grown on chiral nematic cellulose-derived nanostructured bio-templates. We demonstrate that chiral MOFs, specifically, zeolitic imidazolate framework (ZIF), unc -[Zn(2-MeIm)2, 2-MeIm=2-methylimidazole], can be grown from regular precursors within nanoporous organized chiral nematic nanocelluloses via directed assembly on twisted bundles of cellulose nanocrystals. The template-grown chiral ZIF possesses tetragonal crystal structure with chiral space group of P41, which is different from traditional cubic crystal structure of I-43 m for freely grown conventional ZIF-8. The uniaxially compressed dimensions of the unit cell of templated ZIF and crystalline dimensions are signatures of this structure. We observe that the templated chiral ZIF can facilitate the enantiotropic sensing. It shows enantioselective recognition and chiral sensing abilities with a low limit of detection of 39 μM and the corresponding limit of chiral detection of 300 μM for representative chiral amino acid, D- and L- alanine. 相似文献