随着特种超精密加工技术的发展,复杂流体被越来越多地用于超精密加工工艺中。超精密加工流场分析具有几何特征复杂、流体本构特性多样、流体边界为自有边界等特点,传统流体数值分析方法难以实现可靠分析。从流体的一般特性出发,将D. G. Christopherson提出的非负二阶偏微分系统的超松弛迭代方法用于超精密加工流场分析,建立了适应性与可靠性兼顾的流场分析方法。以磁流变抛光为例,开展了抛光区域压力场数值计算,结果表明所得压力分布形态正确,且分布从x轴正半轴延伸到负半轴,与郑立功等人的实验测定结果一致。另外,基于Kistler力传感器对磁流变抛光过程的法向压力在0.1~0.3 mm浸深段进行了在位测量,发现计算与实验结果偏差均小于20%。表明了该方法的有效性与准确性。 相似文献
Ti_3C_2 belongs to MXenes family,which is a new two-dimensional material and has been applied in many fields.With simple method of hydrothermal and high temperature calcination,nano structured Ni/Ti_3C_2T_x hybrid was synthesized.The stable layer structure of Ti_3C_2 MXene providing high surface area as well as excellent electronic conductivity are beneficial for deposition and decomposition of discharge product Li_2O_2.Furthermore,possessing special catalytic activity,Ni nanoparticles with size of about 20 nm could accelerate Li_2O_2 breaking down.Taking advantage of two kinds of materials,Ni/Ti_3C_2T_x hybrid as cathode of Li-O_2 battery can achieve a maximal specific capacity of 20,264 mAh/g in 100 mA/g and 10,699 mAh/g in 500 mA/g at the first cycle.This work confirms that the prepared Ni/Ti_3C_2T_x hybrid exhibiting better cycling stability points out a new guideline to improve the electrochemical performance of lithium-oxygen batteries. 相似文献
The recent development of selective oxidation of aromatic sulfides with molecular oxygen was highlighted. The sulfoxides and sulfones could be obtained by simply switching the reaction media, i.e., bis(2-butoxyethyl)ether (BBE) or poly(ethylene glycol)dimethyl ether (PEGDME). The application of the high-boiling-point polyether as an initiator and green media can eliminate the need of large quantities of additives and volatile solvents. This strategy represents an economic and eco-friendly method that could find potential applications. 相似文献
Carbon quantum dots (CQDs) co-doped with N, P and S derived from expired milk was prepared by a simple hydrothermal method. By dipping pure cotton face towel (PCFT) into CQDs ink, a flexible all-biomass CQDs/PCFT sensor was prepared for the first time. Due to the heteroatom doping, extremely small particle size of CQDs and excellent permeability of CQDs/PCFT film, the flexible CQDs/PCFT sensor showed the high sensitivity and bending stability. In the range of 0–60° bending states, the responses of CQDs/PCFT sensor to four target analytes changed by less 5.0%. After 3000 bending of 60°, the maximum change of the response to the target analytes was only 6.4%. Interestingly, due to the abundant functional groups and defects of CQDs, the flexible CQDs/PCFT sensor displayed sensing curves of different shapes for different target analytes. In this way, by establishing a database of sensing curves of target analytes, multiple analytes can be detected discriminatively by relying only on single sensor with the help of image recognition. This work provided a reference for the development of cotton fiber based all biomass flexible gas sensor.
We designed and synthesised a reactive mesogen (CRM) containing cinnamate moiety in the core and two acrylate groups at both ends. The structure was characterised by 1H NMR and FT-IR, and its liquid crystalline property was investigated by DSC and POM. The compound showed a nematic phase between 175.2 – 97.5 oC, followed by a smectic C phase between 97.5 and 57.9 oC during the cooling cycle. We proposed a fabrication method to achieve uniaxial homogeneous alignment of liquid crystals by irradiating the CRM-doped LC mixture in a sandwich cell of in-plane switching mode (CRM-IPS) with linearly polarised ultraviolet light. The results indicated that the CRM-IPS cell showed excellent initial dark state with a good alignment state, electro-optical performance and durability. This confirmed that the photo-induced alignment of LCs by CRM possesses outstanding alignment capability compared to the conventional rubbed polyimide alignment layer. We expect that this fabrication method is a promising candidate for cost-effective, green-manufacturing, and high-quality alignment method for the manufacturing of high-resolution liquid crystal displays (LCDs). 相似文献