拟似然非线性模型的某些渐近推断:几何方法

Abstract. A modified Bates and Watts geometric framework is proposed for quasi-likelihoodnonlinear models in Euclidean inner product space. Based on the modified geometric framework,some asymptotic inference in terms of curvatures for quasi-likelihood nonlinear models is stud-ied. Several previous results for nonlinear regression models and exponential family nonlinearmodels etc. are extended to quasi-likelihood nonlinear models.     

Prototype of immunochromatographic assay strips using colloidal CdTe nanocrystals as biological luminescent label

Colloidal semiconductor nanocrystals have attracted considerable attention as a novel biological luminescent label. The bioinorganic conjugates of luminescent CdTe nanocrystals and protein, including CdTe/BSA (bovine serum albumin) and CdTe/MAB (mouse monoclonal antibody against hepatities B surface antigen), were formed via electrostatic/coordination self-assembly. Pure CdTe nanocrystals, CdTe/BSA and CdTe/MAB were used in the immunochromatographic assay experiments, respectively. And the results indicated that CdTe nanocrystals could be used and developed as a novel label with good stability, high sensitivity and facile determination of several analytes in immunochromatographic assay strips.     

Synthesis,Structure and Magnetic Properties of dimeric Nickel(II) Benzoate with Pyridyl‐substituted Nitronyl Nitroxides

The novel heterospin complex [Ni₂(PhCOO)₄(NITpPy)₂]·2CH₃CN ( 1 ) was synthesized by the reaction of nickel benzoate and 2‐(4‐pyridyl)‐4,4,5,5‐tetramethylimidazoline‐1‐oxyl‐3‐oxide (NITpPy) in acetonitrile and dichloromethane solutions. The X‐ray structure determination shows that complex 1 consists of a symmetrical dimeric Ni^II benzoate paddle‐wheel core and pyridyl nitrogen atoms of radical ligands at the apical position, in addition, the temperature (2–300K) dependent magnetic susceptibility measurements indicate that 1 has antiferromagnetic behavior.     

三阶Levi-Civita张量在量子力学中的应用

利用Levi-Civita张量及其基本性质,讨论了量子力学中坐标、动量及角动量的对易关系,给出了相关习题的一般解法.该解法可帮助学生克服在量子力学学习中解此类习题的困难.     

Cubic equation-of-state correlation of the solubility of some anti-inflammatory drugs in supercritical carbon dioxide

The accurate experimental determination of solid drug solubility in supercritical fluids (SCFs) and its correlation are crucially important to the development of supercritical technologies for the pharmaceutical industry. In this work, the solubilities of flurbiprofen, ketoprofen, naproxen and ibuprofen in supercritical carbon dioxide (scCO₂) were correlated using the Peng–Robinson (PR), Soave–Redlich–Kwong (SRK) and Patel–Teja–Valderrama (PTV) equations-of-state with van der Waals (vdW), Panagiotopoulos–Reid (mrPR) and Mukhopadhyay–Rao (MR) mixing rules. Several modeling and correlation computational programs were developed in Mathematica^®, a powerful symbolic computational language. Correlations were compared and discussed on the basis of the employed equation-of-state and mixing/combining rules. The importance of the estimation methods used for the determination of critical and other drug physical properties (namely drug's sublimation pressure) was also underlined in the discussion of the correlation results quality. A potential helpful procedure (based on simultaneous correlation of one of the critical or physicochemical properties) is suggested, in order to satisfactorily choose property estimation methods to use.     

迷迭香单体的抗氧化活性

采用柱层析方法对迷迭香抗氧化剂(Rao)进行分离,分离出8个含量较高的单体.用光度法、ESR法、滴定法测定了迷迭香的8个单体、单体组合及Rao的抗氧化活性,并分析了抗氧化活性与其结构的关系.结果表明,在单体中,对超氧阴离子自由基及羟基自由基清除率最高的是槲皮素,分别为82.6%和87.1%.对香烟烟气自由基平均清除率最高的是迷迭香二酚,清除率为48.17%.单体活性最强的槲皮素和迷迭香二酚组合后,其抗氧化活性高于单体.活性强的抗氧化剂对油脂过氧化的抑制效果好,但作用时间较短.     

中立型时滞模型的周期正解

本文通过使用某些新技巧，研究了中立型时滞模型Ｎ＇（ｔ）＝Ｎ（ｔ）［ａ（ｔ）－－β（ｔ）－ｂ（ｔ）Ｎ（ｔ－Ｔ（ｔ））－Ｃ（ｔ）Ｎ＇（ｔ－Ｔ（ｔ））］周期正解的存在性，解决了文［１］中的一个公开问题，并改正了文［２］中的错误。     

一类适用于非凸函数的非单调共轭梯度法

This paper discusses the global convergence of a class of nonmonotone conjugate gradient methods (NM methods) for nonconvex object functions. This class of methods includes the nonmonotone counterpart of modified Polak-Ribiere method and modified Hestenes-Stiefel method as special cases.     

Synthesis and Mesophase Behavior of Phenylthiophene Based Amphiphilic Molecules

Novel amphiphilic molecules consisting of a rigid 2‐phenylthiophene core, with a polar flexible tri(oxylethylene) moiety attached to the phenyl ring and one or two alkyl chains attached to the thiophene ring at the other side have been synthesized by using Ni(II) and Pd(0) catalyzed coupling reaction as key steps. The tri(oxylethylene) moieties were terminated with hydroxyl group, sodium carboxylate group and lithium carboxylate group respectively. The thermotropic and solvent induced liquid crystalline behavior of these substances was investigated by polarized optical microscopy, differential scanning calorimetry and X‐ray diffraction. Thereby the influence of the terminal groups attached to the tri(oxylethylene) moities as well as the influence of the length and the number of the alkyl chains on the mesophase behavior were investigated. The single alkyl chain Na‐carboxylate termianted derivatives show smectic A phases, double alkyl chain Na‐carboxylate terminated derivatives show a thermo tropic hexagonal columnar mesophase, while columnar mesophases are found in both single and double alkyl chain Li‐carbonate terminated derivatives. The model for molecular organization in the hexagonal columnar mesophase is established.     

新的植物毒素蒜头果蛋白的荧光光谱研究

蒜头果蛋白(Malanin)是从我国稀有植物蒜头果中分离纯化出的一种具有高细胞毒性的蛋白质。用荧光光谱法研究在温度、酸度、有机溶剂、表面活性剂、变性剂及荧光猝灭剂等不同条件对蒜头果蛋白溶液构象的变化。实验表明,Malanin在天然状态下荧光发射峰位于340 nm处,色氨酸(Trp)残基较大程度位于Malanin分子的疏水区。十二烷基硫酸钠、异硫氰酸胍、丙烯酰胺和碘化钾的加入均可使Malanin的分子构象发生变化,导致分子内Trp残基的荧光猝灭。异硫氰酸胍的加入使Trp残基的荧光发射峰位明显红移,表明位于Malanin分子较疏水环境内的Trp残基相对外露。