Momentum and heat transfer of a special case of the unsteady stagnation-point flow

This paper investigates the unsteady stagnation-point flow and heat transfer over a moving plate with mass transfer,which is also an exact solution to the unsteady Navier-Stokes(NS)equations.The boundary layer energy equation is solved with the closed form solutions for prescribed wall temperature and prescribed wall heat flux conditions.The wall temperature and heat flux have power dependence on both time and spatial distance.The solution domain,the velocity distribution,the flow field,and the temperature distribution in the fluids are studied for different controlling parameters.These parameters include the Prandtl number,the mass transfer parameter at the wall,the wall moving parameter,the time power index,and the spatial power index.It is found that two solution branches exist for certain combinations of the controlling parameters for the flow and heat transfer problems.The heat transfer solutions are given by the confluent hypergeometric function of the first kind,which can be simplified into the incomplete gamma functions for special conditions.The wall heat flux and temperature profiles show very complicated variation behaviors.The wall heat flux can have multiple poles under certain given controlling parameters,and the temperature can have significant oscillations with overshoot and negative values in the boundary layers.The relationship between the number of poles in the wall heat flux and the number of zero-crossing points is identified.The difference in the results of the prescribed wall temperature case and the prescribed wall heat flux case is analyzed.Results given in this paper provide a rare closed form analytical solution to the entire unsteady NS equations,which can be used as a benchmark problem for numerical code validation.     

Host–Guest Chemistry of a Bis‐Calix[4]pyrrole Derivative Containing a trans/cis‐Switchable Azobenzene Unit with Several Aliphatic Bis‐Carboxylates

The azobenzene unit used as a photochemically and thermally switchable linker in the assembly of a bis‐calix[4]pyrrole receptor provides a means to modulate the binding of bis‐carboxylates of significant biological importance in cancer research. Conversely, the complexation of different bis‐anionic guests has significant kinetic effects on both the photochemical and thermal trans/cis isomerization of the azobenzene unit.     

Real-time assessment of carbon nanotube alignment in a polymer matrix under an applied electric field via polarized Raman spectroscopy

A technique has been developed utilizing polarized Raman spectroscopy to measure alignment of carbon nanotubes in situ in a polymer matrix under an applied electric field. Previous studies of alignment have been restricted to optically transparent solvents or polymerized specimens that prevent accurate analyses of alignment dynamics in polymers. The effects of electric field strength on the degree of alignment and the time to achieve an aligned state are discussed. The use of in situ, real-time polarized Raman spectroscopy provides a non-invasive technique for assessing carbon nanotube alignment, which can assist in determining processing conditions to improve the mechanical and electrical properties of aligned nanocomposites.     

Backward heat equation with time dependent variable coefficient

Backward heat equation with time dependent variable coefficient is severely ill‐posed in the sense of Hadamard, so we need regularization. In this paper, we consider Backward heat equation with time dependent variable coefficient, and by small perturbing, we obtain an approximation problem. We show this approximation problem is well‐posed with small parameter. Also, we show this approximation system converges to the original problem when parameter goes to zero. Here, we use modified‐quasi boundary value method to regularize this problem. Copyright © 2016 John Wiley & Sons, Ltd.     

Fourier analysis of operations that preserve permutations

Fourier inversions of operations identify those with certain symmetries. A general method with invertible matrices over semirings sets up many different inversive schemes, such as disjunctive normal form, algebraic normal form and classical Fourier analysis. First, unary functions are inverted, and then, with tensor products, the same is done for operations of more than one argument. Classical Fourier analysis is applied to inverting operations on a set of k elements by replacing it by the set of \({k^{\rm th}}\) roots of unity. The Fourier transform of an operation preserving rotations of the roots has many coefficients that are zero, in fact, at most \({1/k}\) are non-zero. A related result holds for operations preserving reflections of the roots.