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Peiyu Wang Qinglong Wang Guoheng Zhang Haiyan Jiao Xiaoyan Deng Liwei Liu 《Journal of Solid State Electrochemistry》2016,20(2):319-325
In this paper, cabbage leaves (CLs) were used to synthesize porous activated carbon by the carbonization and activation processes. The material for CLs were carbonized at 600 °C and activated at 800 °C with the KOH/C-600 mass ratio 4 (denoted as AC-800) show typical amorphous character and display porous structures with high specific surface areas 3102 m2/g via XRD and BET measurements. As the electro-active material, AC-800 electrode exhibit ideal capacitive behaviors in aqueous electrolytes and the maximal specific capacitance is as high as 336 F/g at the current density of 1 A/g. Furthermore, AC-800 electrode shows excellent electrochemical cycle stability with ~95 % initial capacitance being retained after 2000 cycles. The desirable capacitive performances enable the CLs to act as a new biomass source of carbonaceous materials for high-performance supercapacitors and low-cost electrical energy storage devices. 相似文献
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Application of chromatography technology in the separation of active alkaloids from Hypecoum leptocarpum and their inhibitory effect on fatty acid synthase 下载免费PDF全文
Qiulong Zhang Guangxiang Luan Tao Ma Na Hu Yourui Suo Xiaoyan Wang Xiaofeng Ma Chenxu Ding 《Journal of separation science》2015,38(23):4063-4070
A method that involved the combination of pH‐zone‐refining counter‐current chromatography and semipreparative reversed‐phase liquid chromatography has been established for the preparative separation of alkaloids from Hypecoum leptocarpum. From 1.2 g of crude sample, 31 mg N‐feruloyltyramine, 27 mg oxohydrastinine, 47 mg hydroprotopine, 25 mg leptopidine, and 18 mg hypecocarpine have been obtained. The structure of the new compound, hypecocarpine, is confirmed based on the analysis of spectroscopic data, including NMR, UV, and IR spectroscopy and positive electrospray ionization mass spectrometry. The known chemical structures were characterized on the basis of 1H and 13C NMR spectroscopy. The purities of the five alkaloids are all over 92.7% as determined by high‐performance liquid chromatography. The alkaloids’ cytotoxicity in breast cancer cells is assessed by using a Cell Counting Kit assay and their inhibitory effect on fatty acid synthase expression is assessed by a Western blot assay. These results suggest that leptopidine could suppress growth and induce cytotoxicity in breast cancer cells and that the cytotoxicity of leptopidine may be related to its inhibitory effect on fatty acid synthase expression. 相似文献
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Nonlinear Dynamics - A delay-induced predator–prey system with the effect of habitat complexity and Holling type functional response is proposed. The dynamical behaviors of the presented... 相似文献
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The interference of high-order harmonics generated by two successive gas jets within a single laser pulse is discussed by a modeling with the inclusion of macroscopic propagation of the fundamental and harmonic fields in an ionizing medium. Based on the interference, we show that one can extract the laser Rayleigh range from the interference of harmonics and the accuracy of retrieve is independent of carrier-envelope phase while dependent on the pulse duration. Moreover~ we demonstrate that it is possible to optimize the single or range of harmonics with a high ratio relative to the adjacent orders by changing the separation of two gas jets, which is unavailable by using a single gas jet and linear polarized laser pulse. 相似文献
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Han-Cheng Zhou Xiu-Lei Li Juan-Li Liu Cheng Peng Bin Zhang Jin Chen Qiong Su Lan Wu You-Zhu Yuan 《Chemical Papers》2015,69(10):1361-1366
Several Lewis acid ionic liquids (LAILs) with different acidic scales were synthesised and used as catalysts for the synthesis of benzofuranol by condensation of pyrocatechol and 3-chloro-2-methylpropene in one pot. The catalytic activity of these ionic liquids was correlated with their Lewis acidity. Low to moderate conversion with excellent selectivity to benzofuranol was obtained in the presence of the appropriate LAILs. Compared to the two-step synthetic method currently used in industry, a higher yield plateau (81.1%) of benzofuranol was achieved in the presence of [BMIm][AlCl4] IL as catalyst at 418 K after 4 h. Furthermore, the catalyst is readily separated from the resultant products via decantation and could be reused after treatment in vacuum. 相似文献
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Biomimetic superhydrophobic UHMWPE/nanosilica films with different sticky behavior on several metals 下载免费PDF全文
Hongling Wang Yunxia Wang Chufeng Sun Yanbin Wang Qiong Su Jianzhang Wang Fengyuan Yan 《Surface and interface analysis : SIA》2017,49(9):850-857
A kind of organic–inorganic composite film with biomimetic superhydrophobic performance was prepared on several metals including steel, aluminum, and copper. The organic matrix was ultrahigh‐molecular‐weight polyethylene (UHMWPE), and the inorganic filler was nanosilica. Scanning electron microscope observation indicated addition of nanosilica greatly changed the topography of the UHMWPE film. Special convexities were formed on the surfaces of the composite films, which made the composite films rougher than that of pure UHMWPE film. The nanosilica randomly scattered on the surface of the convexities and formed hierarchical structure similar to that of some plant leaves with superhydrophobic characteristics. Interestingly, it was found that there were remarkable differences between the sliding angles (SA) of water droplet on the composite films on different metals although the contact angles (CA) of water droplet on these films were quite close. The CA on the composite films on steel was about 157°, and the SA was larger than 90°, which demonstrated obvious superhydrophobic and sticky characteristic. But to the films on aluminum and copper, the CAs on them were larger than 160° and the SAs were between 3° and 4°, which meant excellent superhydrophobic and roll‐off performance. Scanning electron microscope observation indicated that there were some micro‐orifices in the film on steel and these micro‐orifices were connected to some extent. It was believed that these micro‐orifices provided capillary force and restrained sliding of water droplet. A sticky model based on capillary mechanism was proposed. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
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Dr. Hong Wang Jia Jia Prof. Pengfei Song Dr. Qiang Wang Dr. Debao Li Prof. Shixiong Min Dr. Chenxi Qian Dr. Lu Wang Young Feng Li Chun Ma Prof. Tom Wu Prof. Jiayin Yuan Prof. Markus Antonietti Prof. Geoffrey A. Ozin 《Angewandte Chemie (International ed. in English)》2017,56(27):7847-7852
Herein we introduce a straightforward, low cost, scalable, and technologically relevant method to manufacture an all-carbon, electroactive, nitrogen-doped nanoporous-carbon/carbon-nanotube composite membrane, dubbed “HNCM/CNT”. The membrane is demonstrated to function as a binder-free, high-performance gas diffusion electrode for the electrocatalytic reduction of CO2 to formate. The Faradaic efficiency (FE) for the production of formate is 81 %. Furthermore, the robust structural and electrochemical properties of the membrane endow it with excellent long-term stability. 相似文献
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A novel red-emitting phosphor CaSrAl2SiO7:Eu3+ was firstly synthesized through the high temperature solid state reaction at 1300 °C. The structure, diffuse reflection spectra, photoluminescence spectra, color-coordinate parameters and quantum efficiencies (QE) of phosphors were investigated. The obtained CaSrAl2SiO7:Eu3+ phosphors have the same structure with that of the Ca2Al2SiO7 and Sr2Al2SiO7 phosphor, which have the melilite structure. Optical properties were studied as a function of Eu3+ concentration x, when x>0.14, the intensity of absorption of the f–f transitions of Eu3+ at 393 nm is stronger than that of the broad charge transfer transition band (CTB) around 254 nm, and which matches well with the output lights of NUV–LEDs, whereas, the concentration of Eu3+x≤0.14, the absorption of 393 nm is weaker than that of CTB. The underlying reason of Eu3+ concentration on their luminescent properties was investigated and discussed in detail. As a result, comparing with the commercial red phosphor Y2O2S:Eu3+, the CaSrAl2SiO7:xEu3+ (x>0.14) phosphor exhibited excellent color purity and much higher brightness and could be considered as promising red phosphors for NUV–LEDs. 相似文献