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1.
Constructing molecular switches based on supramolecular assembly strategy is a research hotspot. In this work, we constructed an all visible-light-regulated supramolecular photo-switch based on pyridinium-modified diarylethene derivative (DTE-Me) and cucurbit[8]uril (CB[8]). CB[8] not only accelerated the photochromic process under 365 nm ultraviolet light but also shifted the absorption of open formed DTE-Me to the visible region, which led to efficient photocyclization under 450 nm visible light irradiation, while DTE-Me and DTE-Me/CB[7] remained unchanged under the same irradiating condition. Moreover, the complexation with CB[8] could induce the strong thermally activated delayed fluorescence (TADF) of guest molecular at 550 nm, which further shifted to 670 nm through two-step sequential energy transfer with sulforhodamine B (SRB) and Cy5. This energy transfer process could also be regulated with visible light, and the application for information encryption was also demonstrated. This assembly provides a convenient approach to construct all visible light-regulated TADF photo-switch. 相似文献
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Rui Feng Zi-Ying Li Zhao-Quan Yao Zi-Ang Guo Yi-Nan Zhang Hao-Xiang Sun Wei Li Xian-He Bu 《中国科学:化学(英文版)》2022,65(1):128-134
The rational designability and chemical tunability of metal-organic frameworks(MOFs)are enabling tributes to efficaciously enhance their room temperature phosphorescence(RTP)performance.A family of stable anionic MOFs,[Zn2(4,5-ImDC)2]M2(NKU-132,M=(CH3)2NH2or(CH2CH3)2NH2),featuring significant RTP have been synthesized.By rational cation selection and in-situ replacement from dimethylammonium to diethylammonium,the phosphorescence lifetime is increased from 30.88 to126.3 ms,along with less sensitivity to air.This work provides an anti-quenching and lifetime tuning example for RTP-MOFmaterials via facile host-guest chemistry. 相似文献
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Supercapacitors (SCs) with high energy density and power density are a research hotspot. Herein, we report a flexible porous carbon membrane supercapacitor prepared by electrospinning polyacrylonitrile (PAN) with γ-cyclodextrin-MOF (γ-CD-MOF) and then carbonizing at 900 °C. BET results showed that the supercapacitor retained the skeleton of γ-CD, γ-CD-MOF and the pores formed by the spun-fibers, which were 0.73, 1.09 and 23–186 nm, respectively, showing a high specific surface area of 134.7 m2/g. The hierarchically porous structures ensure rapid charge transfer and ion diffusion, resulting in the PAN/γ-CD-MOF carbon electrode with a high capacity of 283.3 F/g. Moreover, the supercapacitor had a high energy density up to 17.5 Wh/kg and power density up to 6 kW/kg. Significantly, it showed excellent cycle stability with a capacitance retention of 97.5% after 6000 cycles. This work provides a supramolecular strategy to construct a flexible porous carbon membrane, which has potential for supercapacitor applications. 相似文献
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Supramolecular optical chemosensors are useful tools in analytical chemistry for the visualization of molecular recognition information. One advantage is that they can be utilized for array systems to detect multiple analytes. However, chemosensor arrays have been evaluated mainly in the solution phase, which limits a wide range of practical applications. Thus, appropriate solid support materials such as polymer gels and papers are required to broaden the scope of the application of chemosensors as on-site analytical tools. In this review, we summarize the actual approaches for the fabrication of solid-state chemosensor arrays combined with powerful data processing techniques and portable digital recorders for real-world applications. 相似文献
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We study the pseudoholomorphic curves with brake symmetry in symplectization of a closed contact manifold. We introduce the pseudo-holomorphic curves with brake symmetry and the corresponding moduli space. Then we get the virtual dimension of the moduli space. 相似文献
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考虑由竞争合同制造商和原始设备生产商(OEM)组成的竞合供应链,竞争合同制造商在上游是OEM的合作者,在下游市场上是OEM的竞争者。当合同制造商因资金约束而不能进行生产运营时,一个通常做法是向银行贷款或者OEM融资;为了更好地探讨竞合供应链的融资决策,考虑了批发价格分别为外生变量和内生变量两种不同的情况下,以OEM为Stackelberg领导者的博弈,这与实际情况很接近。分析结果表明,当批发价格分别为外生变量时,合同制造商融资方式的选择主要受融资利率的影响;当批发价格为内生变量时,合同制造商融资方式的选择主要受自身自有资金量的影响。研究揭示了竞合供应链的融资决策过程,阐明了合同制造商的融资方式选择与自身的自有资金量和融资利率的关系。最后用数值算例对上述结论进行了验证说明。 相似文献
8.
Science China Mathematics - Latin hypercube designs (LHDs) are very popular in designing computer experiments. In addition, orthogonality is a desirable property for LHDs, as it allows the... 相似文献
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The biological activities of a series of 3,3-spirocyclic indole derivatives containing CF2, phosphine oxide,indole, and cyano functional groups were evaluated, and these derivatives were found to exhibit antiTMV, fungicidal, and insecticidal activities. 相似文献