An adaptive smooth unsaturated bistable stochastic resonance system and its application in rolling bearing fault diagnosis

An adaptive smooth unsaturated bistable stochastic resonance (ASUBSR) system for bearing fault signal detection is established. Based on the problem of output saturation and poor low-frequency suppression performance of classical bistable stochastic resonance (CBSR) system, an SUBSR with unsaturated characteristics is proposed. An ASUBSR system is designed by extracting the envelope spectrum of the input signal and resampling it to satisfy the adiabatic approximation condition, combining high-pass filter to filter out low-frequency interference, and using genetic algorithm to select the optimal system parameters. Through simulations and experiments, we found that the system can effectively suppress the interference of low-frequency and high-frequency, indicates that the system performs like a band-pass filter, and the output signal-to-noise ratio is better than that of the CBSR system. The proposed ASUBSR system has great application in the field of fault detection of rolling bearings.     

Copper-catalyzed 1,4-protosilylation and 1,4-protoborylation of enynic orthoesters for synthesis of functionalized 2,3-allenoates

Herein, copper-catalyzed 1,4-protosilylation and 1,4-protoborylation of enynic orthoesters have been developed. The enynic orthoesters as precursors of unstable enynic esters were applied to produce the functionalized 2,3-allenoate products. Meanwhile, the asymmetric 1,4-protosilylation of enynic orthoesters with Ph Me2Si-Bpin was also studied. The chiral monopyridine imidazoline ligand was efficient to provide the asymmetric 1,4-protosilylation products with high enantioselectivity.     

Nanobody-based electrochemical immunoassay for Bacillus thuringiensis Cry1Ab toxin by detecting the enzymatic formation of polyaniline

We describe an electrochemical immunoassay for the Cry1Ab toxin that is produced by Bacillus thuringiensis. It is making use of a nanobody (a heavy-chain only antibody) that was selected from an immune phage displayed library. A biotinylated primary nanobody and a HRP-conjugated secondary nanobody were applied in a sandwich immunoassay where horseradish peroxidase (HRP) is used to produce polyaniline (PANI) from aniline. PANI can be easily detected by differential pulse voltammetry at a working voltage as low as 40 mV (vs. Ag/AgCl) which makes the assay fairly selective. This immunoassay for Cry1Ab has an analytical range from 0.1 to 1000 ng∙mL^-1 and a 0.07 ng∙mL^-1 lower limit of detection. The average recoveries of the toxin from spiked samples are in the range from 102 to 114 %, with a relative standard deviation of <7.5 %. The results demonstrated that the assay represented an attractive alternative to existing immunoassays in enabling affordable, sensitive, robust and specific determination of this toxin.

Nanobodies specific to Cry1Ab toxin were isolated from an immunized camel. A biotinylated primary nanobody and a HRP-conjugated secondary nanobody were applied in a sandwich immunoassay with horseradish peroxidase being used to produce polyaniline, which can be easily detected by differential pulse voltammetry.

     

Light-conversion phosphor nanoarchitectonics for improved light harvesting in sensitized solar cells

Photovoltaic technology provides a promising approach for solar energy conversion. One significant factor limiting the efficiency is the poor light harvesting of solar energy, which is related to the mismatch between the energy distribution of photons and the absorption of semiconductor materials or dye. Light-conversion phosphors have been explored as spectral converters to improve the light-harvesting ability in sensitized solar cells. Many progressive studies have been conducted to expand the family of light-conversion phosphors and exploit their application in sensitized solar cells, bringing emerging opportunities to develop commercial sensitized solar cells. In this review, we survey the development of light-conversion phosphors in sensitized solar cells. First, the application and conversion mechanism of light-conversion phosphors, including up-conversion phosphors, down-conversion phosphors, up/down conversion phosphors, and long-lasting phosphors, are summarized in detail. After that, the challenging problems and possible solutions of applying light-conversion phosphors to sensitized solar cells are discussed. The review also highlights some new ideas in the development of sensitized solar cells and the application of light-conversion phosphors in other solar technology.     

A hybrid feedback control strategy for autonomous waypoint transitioning and loitering of unmanned aerial vehicles

We consider the problem of autonomously controlling a fixed-wing aerial vehicle to visit a neighborhood of a pre-defined waypoint, and when nearby it, loiter around it. To solve this problem, we propose a hybrid feedback control strategy that unites two state-feedback controllers: a transit controller capable of steering or transitioning the vehicle to nearby the waypoint and a loiter controller capable of steering the vehicle about a loitering radius. The aerial vehicle is modeled on a level flight plane with system performance characterized in terms of the aerodynamic, propulsion, and mass properties. Thrust and bank angle are the control inputs. Asymptotic stability properties of the individual control algorithms, which are designed using backstepping, as well as of the closed-loop system, which includes a hybrid algorithm uniting the two controllers, are established. In particular, for this application of hybrid feedback control, Lyapunov functions and hybrid systems theory are employed to establish stability properties of the set of points defining loitering. The analytical results are confirmed numerically by simulations.     

Copper-based oxygen carriers supported with alumina/lime for the chemical looping conversion of gaseous fuels

Copper(Ⅱ) oxide in varying ratios was combined with either an alumina-based cement(Al300), or CaO derived from limestone as support material in a mechanical pelletiser. This production method was used to investigate its influence on possible mechanical and chemical improvements for oxygen carriers in chemical looping processes. These materials were tested in a lab-scale fluidised bed with CO or CH_4 as a reducing gas at 950 °C. As expected, the oxygen carriers containing a greater ratio of support material exhibited an enhanced crushing strength. Oxygen carriers comprised of a 1:3 ratio of support material to active CuO exhibited increased crushing strength by a minimum of 280% compared to pure CuO pellets.All oxygen carriers exhibited a high CO conversion yield and were fully reducible from CuO to Cu. For the initial redox cycle, Al300-supported oxygen carriers showed the highest fuel and oxygen carrier conversion. The general trend observed was a decline in conversion with an increasing number of redox cycles.In the case of CaO-supported oxygen carriers, all but one of the oxygen carriers suffered agglomeration.The agglomeration was more severe in carriers with higher ratios of CuO. Oxygen carrier Cu25Al75(75 wt% aluminate cement and 25 wt% CuO), which did not suffer from agglomeration, showed the highest attrition with a loss of approximately 8% of its initial mass over 25 redox cycles. The reducibility of the oxygen carriers was limited with CH_4 in comparison to CO. CH_4 conversion were 15%-25% and 50% for Cu25Ca75(25 wt% CuO and 75 wt% CaO) and Cu25Al75, respectively. Cu25Ca75 demonstrated improved conversion, whereas Cu25Al75 exhibited a trending decrease in conversion with increasing redox cycles.     

子立方无爪图的单射边色数至多为6

设$G$是一个图. 图$G$的一个单射边染色是指图$G$的一个边染色, 使得距离为$2$的两条边或者在同一个三角形中的两条边染不同的颜色. 图$G$的单射边色数是指图$G$的任意单射边染色所需要的最少颜色数. 关于单射边色数有一个猜想: 任意一个子立方图的单射边色数都不超过$6$. 在本文中, 我们证明了这个猜想对子立方无爪图是成立的, 并且给出图例说明上界$6$是紧的. 同时, 我们的证明隐含了求解这类图不超过$6$种颜色的单射边染色方案的一个线性时间算法.     

Lattice Boltzmann simulation on thermal performance of composite phase change material based on Voronoi models

Phase change materials(PCMs) are important for sustaining energy development. For the thermal performance enhancement, the composite PCM with metal foam reconstructed by the Voronoi method is investigated in this work. The lattice Boltzmann method(LBM) is used to analyze the melting process on a pore scale. The melting interface evolution and temperature contour of the composite PCM are explored and compared with those of pure PCM. Moreover, structure parameters including the pore density, porosity and irregularity are investigated comprehensively, indicating that the additive of metal foam strengthens the melting performance of PCM obviously. Compared with pure PCM, the composite PCM has quick rates of the melting front evolution and heat transfer. The heat conduction plays a great role in the whole melting process since the convection is weakened for the composite PCM. To improve the melting efficiency, a larger pore density and smaller irregularity are recommended in general. More significantly, a suitable porosity is determined based on the requirement for the balance between the melting rate and heat storage capacity in practical engineering.