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基于半刚性的配体3'',5''-di (1H-1,2,4-triazol-1-yl)-(1,1''-biphenyl)-3,5-dicarboxylic acid (H2DTBDA)和硝酸钴制备了一个柔性超微孔的金属有机骨架{[Co (DTBDA)]·4H2O}n(FJI-H35),并对该材料的结构进行了系统的表征。FJI-H35活化以后可以发生自适应的结构转变,使得孔径从0.43 nm收缩到0.37 nm。气体吸附测试表明FJI-H35可以从氮气和甲烷中选择性捕获二氧化碳,具有很高的吸附选择性和相对低的吸附焓。突破实验进一步证实FJI-H35可以从二氧化碳/氮气(15∶85,V/V)和二氧化碳/甲烷(50∶50,V/V)混合气中高效选择性捕获二氧化碳。 相似文献
3.
分析了初中化学微粒观的教学内容和“原子的结构”的相关教学设计,针对学生“微粒观”建构存在的难题,提出利用反馈机制,采用“寓教于乐”的游戏化教学设计,并进行实践效果访谈。不仅完成了本课时的教学目标,也让学生对化学的兴趣更加浓厚。 相似文献
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本文设计了一种梯形的周期极化掺镁铌酸锂(PPMgLN)波导,并通过在传播方向上引入温度梯度来拓宽其倍频(SHG)过程的泵浦光源可接收带宽。通过有限差分的光束传输法,计算波导的有效折射率,并进行波导尺寸的设计。结果表明,通过改变梯形波导不同位置的温度,使其形成一个温度梯度,可拓宽泵浦光源的波长可接收带宽。本文所设计的PPMgLN波导最大泵浦光源可接收带宽为C波段,即1 530~1 565 nm,该波导可倍频C波段,得到输出波段带宽为765~782.5 nm,温度调谐范围为30~150 ℃。 相似文献
5.
Joshi Rachna 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2022,76(2):1-8
The European Physical Journal D - We investigate the two-color two-photon K-shell ionization of neutral atoms based on the relativistic second-order perturbation theory and independent particle... 相似文献
6.
Phoresis, a classic example of particle transport driven by thermodynamic gradients, is enjoying a resurgent research interest motivated both by technological developments and by its relevance to the motility of chemically active particles. Here we succinctly review, using the case of chemophoresis (also called diffusiophoresis), the general framework of phoresis and self-phoresis formulated as a Stokes-flow problem for a liquid solution (solvent and solute) maintained out of thermodynamic equilibrium by solute gradients. Within the constraints of local equilibrium, we discuss the simplest extension of the theory in order to account for correlations in the fluid. We show that this leads to a shift from the paradigm based on the ideal case, in that self-phoresis can no longer be represented as phoresis in a self-generated composition gradient. Our review concludes with a concise overview of a few directions which we think hold the potential to reveal a rich behavior in future investigations. 相似文献
7.
Lu Chen 《Frontiers of Physics》2021,16(5):52500
Rayleigh–Taylor (RT) instability widely exists in nature and engineering fields. How to better understand the physical mechanism of RT instability is of great theoretical significance and practical value. At present, abundant results of RT instability have been obtained by traditional macroscopic methods. However, research on the thermodynamic non-equilibrium (TNE) effects in the process of system evolution is relatively scarce. In this paper, the discrete Boltzmann method based on non-equilibrium statistical physics is utilized to study the effects of the specific heat ratio on compressible RT instability. The evolution process of the compressible RT system with different specific heat ratios can be analyzed by the temperature gradient and the proportion of the non-equilibrium region. Firstly, as a result of the competition between the macroscopic magnitude gradient and the non-equilibrium region, the average TNE intensity first increases and then reduces, and it increases with the specific heat ratio decreasing; the specific heat ratio has the same effect on the global strength of the viscous stress tensor. Secondly, the moment when the total temperature gradient in y direction deviates from the fixed value can be regarded as a physical criterion for judging the formation of the vortex structure. Thirdly, under the competition between the temperature gradients and the contact area of the two fluids, the average intensity of the non-equilibrium quantity related to the heat flux shows diversity, and the influence of the specific heat ratio is also quite remarkable. 相似文献
8.
Ding Qingran Zhang Xingyu Lin Zheshuai Xiong Zheyao Wang Yusong Long Xifa Zhao Sangen Hong Maochun Luo Junhua 《中国科学:化学(英文版)》2022,65(9):1710-1714
Science China Chemistry - As structural variants of famous hexagonal tungsten bronzes, hexagonal tungsten oxides (HTO) represent an important family with fascinating functional properties, such as... 相似文献
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10.
Zhuomin Chi Yuzhen Gao Lei Yang Chunlin Zhou Meng Zhang Peiming Cheng Gang Li 《中国化学快报》2022,33(1):225-228
A visible-light-induced spirocyclizative hydroarylation via reductive dearomatization of a series of non activated arenes including 2-phenyl indoles and naphthalene derivatives under mild conditions is de scribed. An intriguing chemoselective dearomative hydroarylation of 2-phenyl indoles is presented. Th dearomative hydroarylation protocol rapidly delivers valuable spirocycles with carbon-carbon doub bonds from readily accessible aromatic precursors in a single step. 相似文献