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1.
《Arabian Journal of Chemistry》2022,15(8):103988
In this work, a green technique for preparing TbFeO3/CuO was reported by employing Crataegus and Lantana Camara leaves as fuel and alkalizing agents, respectively. The new sensor based on the perovskite-type nanocomposite was employed as a sensitive and selective platform to detect Pb(II), Zn(II) and Cd(II) simultaneously. TbFeO3/CuO/Carbon paste electrode (CPE) exhibited a large specific surface area and great electrical conductivity, which enhanced electron transport in the electrochemical process considerably. Moreover, square wave anodic stripping voltammetry (SWASV) was used for the investigation of some factors influencing the sensor sensitivity like pH, modifier concentration, as well as accumulation time and potential. Therefore, the low detection limit (LOD) and a wide linear range were obtained at optimum conditions. In this study, a linear range between 0.9 and 110 µg/L for three ions and LOD of 0.48, 0.29 and 0.12 for zinc, cadmium and lead were achieved, respectively. Moreover, TbFeO3/CuO/CPE was employed to detect zinc, cadmium and lead ions simultaneously in the real samples so that the results have shown consistency with a standard inductively coupled plasma (ICP). 相似文献
2.
Michnik Anna Kiełboń Agnieszka Duch Klaudia Sadowska-Krępa Ewa Pokora Ilona 《Journal of Thermal Analysis and Calorimetry》2022,147(12):6739-6743
Journal of Thermal Analysis and Calorimetry - The results of studies of physiological fluids by differential scanning calorimetry (DSC) for the purpose of diagnosis and monitoring of diseases are... 相似文献
3.
Automotive proton exchange membrane fuel cell stacks need to meet manufacturer specified rated beginning-of-life (BOL) performance before being assembled into vehicles and shipped off to customers. The process of “breaking-in” of a freshly assembled stack is often referred to as “conditioning.” It has become an intensely researched area especially in automotive companies, where imminent commercialization of fuel cell electric vehicles (FCEVs) demands a short, energy- and cost-efficient, and practical conditioning protocol. Significant advances in reducing the conditioning time from 1 to 2 days to as low as 4h or less, in some cases without the use of additional inert gases such as nitrogen, and with minimal use of hydrogen, and specialized test stations will be discussed. 相似文献
4.
A first-principles investigation of the origin of ferroelectricity in the Aurivillius compound Bi2VO5.5 is presented. Calculations with the density functional theory, in conjunction with the modern theory of polarization, allowed us to study the structural, electronic, and polar properties of two configurations built with oxygen vacancies, causing a charge imbalance and a subsequent displacement of the ions, generating two maximum polarizations, one of 14.75 μC/cm2 and one of 4.31 μC/cm2 along [011] direction. Electron localization function schemes were used to identify the asymmetry of charges in (001), (010) and (100) planes. The results obtained in this study establish that the origin of ferroelectricity is due to the displacement of the ions caused by oxygen vacancies and the asymmetric distribution of the isolated pair of Bi ions. On the other hand, the bandgap calculations and the results of Ps establish that Bi2VO5.5 is a candidate ferro-photovoltaic material. 相似文献
5.
6.
Effect of induced magnetic field is critical as a result of much controlled and focused on liquid flow is wanted in numerous modern and clinical procedures for example electromagnetic casting, drug delivery and cooling of nuclear reactors. Hence this investigation explains the behaviour of hybrid carbon nanotubes (CNTs) flow through slipped surface with induced magnetic field. Accumulation of SWCNTs (single wall) and MWCNTs (multi wall) nanomaterial with water base liquid is considered. Thermal performance is analyzed with regular heat source/sink effect. Chemical reaction and activation energy impacts are incorporated in mass equation. Solution of the similarity equations are obtained by adopting RKF45 method. Influence of flow variables are illustrated through graphs and computational values of drag force, Nusselt number and Sherwood number are presented in tables. It is noted that activation energy enhance the concentration field whereas opposite behaviour for reaction rate. Also induce magnetic field boosted with the larger values of magnetic Prandtl number. Furthermore it is observed that hybrid CNTs nanomaterial having higher rate of heating/cooling compare to singular CNTs nanomaterial. 相似文献
7.
In this paper we investigated the stability of fractional order fuzzy cellular neural networks with leakage delay and time varying delays. Based on Lyapunov theory and applying bounded techniques of fractional calculation, sufficient criterion are established to guarantee the stability. Hybrid feedback control is applied to derive the proposed results. Finally, numerical examples with simulation results are given to illustrate the effectiveness of the proposed method. 相似文献
8.
Applied Mathematics and Mechanics - A consequence of nonlinearities is a multi-harmonic response via a mono-harmonic excitation. A similar phenomenon also exists in random vibration. The power... 相似文献
9.
This paper represents an ellipse-shaped patch with a ground slotted broadband patch antenna for microwave head imaging systems. The proposed antenna constructs with a simple ellipse shaped square patch and modified slotted plane. The proposed design is very simple to fabricate and is enclosed in a microwave imaging system. The slotted patch, and the partial ground plane improves the antenna's efficiency, operating frequency range, and gain. The size of the proposed antenna is 70 × 60 × 1.5 mm3 with the electrical dimension being 0.277λ × 0.238λ × 0.006λ at a lower frequency of 1.19 GHz and connected to a 50Ω microstrip feeding line. This antenna is printed onto a low-cost FR-4 substrate whose relative permittivity is 4.4, and whose thickness is 1.5 mm. CST and HFSS software have been used for simulation and thereafter successful completion of the measurements and the fabrication. The comprehensive simulation exhibits that this design provides a bandwidth of 2.37 GHz (1.19 – 3.56 GHz) and 100% of the fractional bandwidths (% BW) with the reflection coefficient of <-10 dB. This antenna on FR-4 can produce an average gain of around 3.63 dBi with 5.95 dBi peak gain at whole operation frequencies. The prototype has a peak radiation efficiency of approximately 97% across the active frequency spectrum with 93% of average. The antenna does have an improved fidelity-factor (> 90 %) with a shorter group-delay. Several design modifications have been performed to get perfect, effective, and suitable results for microwave imaging applications. A 3D-realist Hugo head model is fitted with a single antenna and a 9-antenna array component to verify the performance of both the single antenna, and the configured array antenna. The antenna penetrates the brain human tissues satisfactorily. Across the operational range, the specific absorption rate (SAR) attains a limit of <1 W/kg. The analysis of both numeric and experimental evidence clearly indicates that the suggested antenna is ideal for microwave head-imaging implementations. 相似文献
10.
作为重要的化石能源,褐煤资源潜力巨大、分布广泛但综合利用率低。研究褐煤的分子结构模型,有助于预测褐煤在热解、液化和气化过程中的化学反应机理及反应路径,进而提高褐煤的综合应用水平。以云南峨山褐煤为研究对象,利用傅里叶变换红外光谱、13C核磁共振波谱及X射线光电子能谱等分析测试方法,获取了峨山褐煤的含碳、含氧及含氮结构参数。在此基础上,借助Gaussian 09计算平台,采用量子化学建模的方法构建并优化了峨山褐煤的分子结构模型。研究结果表明:峨山褐煤的芳碳率为39.20%,芳香碳结构主要为苯和萘,且芳香桥头碳与周边碳的比值χb为0.07;脂碳率为49.51%,脂肪碳结构主要为亚甲基,季碳和氧接脂碳;氧原子主要存在于羟基、醚氧、羰基和羧基结构中;含氮结构则以吡啶为主。基于元素分析、13C 核磁共振波谱分析,又经过热重实验消除褐煤中残余水分的影响后,计算出峨山褐煤的分子式为C153H137O35N2。依据分子式及分析结果计算出峨山褐煤的结构单元含量并构建出其初始结构模型,采用半经验法PM 3基组及密度泛函理论M06-2X/3-21G基组对初始分子构型进行优化。优化后的分子模型具有明显的三维立体特征,芳香环之间较为分散且在空间中排列不规则,芳香簇主要通过亚甲基、醚氧基、羰基、酯基和脂肪环连接,含氧官能团主要分布在分子边缘,脂肪族侧链较多。对优化后的分子模型进行振动频率计算进而获得了分子模型的模拟红外光谱,其与实验红外谱图吻合度良好,证明了峨山褐煤分子结构模型的准确性、合理性。分子结构模型的构建有利于直观地了解峨山褐煤的分子结构特征,从而有助于从微观分子角度研究峨山褐煤的宏观性质。同时,峨山褐煤分子结构模型可为其在热解、液化和气化等领域研究中提供理论指导。 相似文献