新型手性硫醚-亚磷酰胺配体的设计与应用

根据模块组合法原理,设计并合成了一种具有亚磷酰胺结构的硫醚配体,该配体具有原料便宜易得、合成步骤简单、易于修饰和结构稳定等特点。以配体/钯络合物催化的丙二酸二甲酯与1,3-二苯基烯丙基醋酸酯的烯丙基化反应作为模板反应,探究了溶剂、碱对其立体控制的影响。随后探究了中心手性与轴手性的匹配/错配现象以及硫醚片段的空间位阻、电性对反应立体控制的作用。在最佳条件下,产物的对映选择性能够达到-76% ee。     

硫酸肼比浊法测定微量硒

依据硒(Ⅳ)在以甘油为稳定剂,盐酸为反应介质的条件下,被过量硫酸肼还原,使体系形成稳定悬浊液的原理,建立了比浊法测定硒的方法。探讨了盐酸用量、甘油用量、反应温度和反应时间以及硫酸肼用量等5个关键因素的影响,确定了最佳测定条件。实验结果表明:大量的共存物质不干扰测定。在选定的实验条件下,线性方程为:ΔA750nm=12.725ρ+0.0076,在2.0×10-4~3.2×10-2mg·m L-1范围内线性关系良好,相关系数(R2)=0.9911,方法的检出限为1.2×10-4mg·m L-1。方法用于测定强化营养盐中总硒,回收率在97.0~103.5%之间,RSD为1.8%。     

以PBL法进行药学实验基本技能教学的探索与实践*

根据西部少数民族地区院校的客观条件和教学特点,提出用以问题为导向的教学法(PBL)进行药学基本技能实验教学。实践证明,实验组(PBL法)的实践基本技能操作水平和发现、分析并解决问题的能力均显著高于对照组(传统教学法)。该法对提高西部少数民族地区药学本科生的创新能力具有较大意义,对其他地区药学本科生创新能力的培养也有一定的借鉴作用。     

停车收费与拥挤道路收费综合决策研究

停车换乘收费与拥挤道路收费是改善城市交通的有效手段.考虑乘坐公交车,全程自驾车及停车换乘这三种出行方式,给出了停车换乘收费与拥挤道路收费的双层规划模型,证明了模型的一阶条件与出行者的方式选择及路径选择条件等价,并给出了算法.算例分析表明,实行停车收费及拥挤道路收费后,能有效改善道路的拥挤状况,为交通管理部门决策提供了理论依据.     

基于2-丙基-4,5-咪唑二甲酸的锰(Ⅱ)和铜(Ⅰ)配合物的合成、晶体结构及性质研究(英文)

采用水热法合成了2个化合物{[Cu2(Hpimdc)(4,4′-bpy)]·H2O}n(1)和[Mn3(pimdc)2·6H2O]n(2)(H3pimdc=2-丙基-4,5-咪唑二甲酸,4,4′-bpy=4,4′-联吡啶),并对2个化合物进行了红外、元素分析、晶体结构和热稳定性分析。晶体结构分析发现化合物1之中的H3pimdc和4,4′-bpy交替与铜(Ⅰ)配位形成一维链线性铜(Ⅰ)配合物。沿a轴和(100)面去观察,2个一维链分子通过游离水连接而形成1个"U"型拓扑结构。而化合物2通过2-丙基-4,5-咪唑二甲酸链与锰(Ⅱ)连接为三维的网状结构。沿b轴方向,三维结构中存在交替的左/右手螺旋状二维结构。     

Topology identification and adaptive synchronization of uncertain complex networks with adaptive double scaling functions

This paper discusses topology identification and adaptive synchronization of uncertain complex networks with adaptive the scaling functions. In comparison with those of the existing scaling function synchronization, the scaling function can be identified by adaptive laws in this paper. Moreover, the uncertain network topological structure are identified simultaneously in the process of synchronization. Illustrative examples are presented to demonstrate the application of the theoretical results.     

黑洞阴影在SSD中的位置和形状

假设旋转的黑洞在标准吸积盘内,在吸积盘的内边界等于最后稳定轨道的情况下,画出黑洞阴影在吸积盘的图像.通过定性和定量分析黑洞的形状和位置,发现对于相同质量的黑洞,黑洞阴影的大小及形状与黑洞的自旋参量有关.旋转黑洞阴影的形状和位置与它的旋转轴是不对称的,通过研究旋转轴与黑洞阴影的位置关系来确定黑洞的质量中心的位置及黑洞的旋转参量.     

Zinc Recovery from Wulagen Sulfide Flotation Plant Tail by Applying Ether Amine Organic Collectors

Separating oxidized zinc minerals from flotation tailings is always a challenge. In this study, a flotation tailing from Wulagen zinc mine in China (Zn grade < 1%) was processed using froth flotation with combinations of amines (OPA 10, OPA 1214, OPA 13, DDA) and Na₂S to study the effects of these amines on the zinc recovery as well as their interactions with other reagents, aiming to screen out a proper reagent scheme to improve zinc separation from extremely low-grade zinc flotation tailings. The results show that different amines led to different flotation performance, and the collectors were ranked as OPA 1214, OPA 13, OPA 10 and DDA in a decreasing order based on flotation collectivity and selectivity. An increase in the concentration of each collector increased the zinc recovery but reduced the concentrate zinc grade. Interactions were also observed between different amines and Na₂S and Na₂SiO₃, and OPA 1214 outdid the others in saving the usage of both the Na₂S and Na₂SiO₃. The measured adsorption of collector onto smithsonite was found to correlate well with flotation test results. It was concluded that hydrocarbon chains can be held accountable for the difference in the flotation performance with different amines. The longer the hydrocarbon chain, the stronger the hydrophobic association ability of amine, which is conducive to the selective amine adsorption onto sulfurized smithsonite particles and hence the smithsonite flotation.     

Some new insights into the Liu system

The present work is devoted to giving new insights into the Liu chaotic system. The local dynamical entities, such as the number of equilibria, the stability of hyperbolic equilibria, and the stability of the nonhyperbolic equilibrium obtained by using the center manifold theorem, the pitchfork bifurcation, the degenerate pitchfork bifurcation, and Hopf bifurcations, are all analyzed when the parameters are varied in the space of parameters. All the closed orbits of the system are also proven rigorously to be nonplanar but only to be curves in space. Moreover, the existence of singularly degenerate heteroclinic cycles for a suitable choice of the parameters is investigated.     

Effects of radial velocity on line profiles and images from the standard thin disk

This paper has derived the general formulae of observed line profiles based on the effects of radial velocity on the standard thin disk fluid around a rotating black hole. Through the ray-tracing method the line profiles of different parameters have been calculated. Comparison of the line profiles with and without a radial velocity shows that the effects of radial velocity on line profiles cannot be neglected in most cases. In both cases the accretive disk imaging shape remains unchanged.