A characterization of generalized derivations of JSL algebras

Let AlgL be a J-subspace lattice algebra on a Banach space X and M be an operator in AlgL. We prove that if δ : AlgL → B(X) is a linear mapping satisfying δ(AB) = δ(A)B + Aδ(B)for all A, B ∈ AlgL with AMB = 0, then δ is a generalized derivation. This result can be applied to atomic Boolean subspace lattice algebras and pentagon subspace lattice algebras.     

SPME-GC-MS分析瀑布毛峰茶叶的赋香成分

采用顶空-固相微萃取法(SPME)从瀑布毛峰茶叶中提取挥发性成分,用气相色谱-质谱法(GC-MS)分析其组成。从一级和特级茶叶中分别鉴定了相对含量大于0.50%的化合物48个和41个,其中共同组分27个。一级瀑布毛峰茶叶的主要挥发性成分有壬醛(9.22%),芳樟醇(4.75%),牛儿醇(4.07%),(Z)-3-己烯-1-醇(3.53%),十一醛(3.16%),邻苯二甲酸二异丁酯(2.94%),十六烷(2.35%),己醛(2.00%),1-辛醇(1.97%),6-甲基-5-庚烯-2-酮(1.86%)。特级瀑布毛峰茶叶的主要挥发性成分有:壬醛(8.85%),1-辛烯-3-醇(6.37%),十一醛(4.81%),2,5,5-三甲基-1-己烯(2.84%),辛醛(2.73%),1-辛醇(2.63%),6-甲基-5-庚烯-2-酮(2.60%),芳樟醇(2.20%),1-戊醇(2.20%),己醛(2.16%)。两个等级的瀑布毛峰茶的主要挥发性成分大致相同,但各成分的含量存在一定差异。     

Analysis of transient response of saturated porous elastic soil under cyclic loading using element-free Galerkin method

A two-dimensional numerical procedure is presented to analyse the transient response of saturated porous elastic soil layer under cyclic loading. The procedure is based on the element-free Galerkin method and incorporated into the periodic conditions (temporal and spatial periodicity). Its shape function is constructed by moving least-square approximants, essential boundary conditions are implemented through Lagrange multipliers and the periodic conditions are implemented through a revised variational formulation. Time domain is discretized through the Crank–Nicolson scheme. Analytical solutions are developed to assess the effectiveness and accuracy of the current procedure in one and two dimensions. For only temporal periodic problems, a one-dimensional transient problem of finite thickness soil layer is analysed for sinusoidal surface loading. For both temporal and spatial periodic problems, a typical two-dimensional wave-induced transient problem with the seabed of finite thickness is analysed. Finally, a moving boundary problem is analysed. It is found that the current procedure is simple, efficient and accurate in predicting the response of soil layer under cyclic loading.     

Synthesis,Crystal Structures and Properties of Two Novel Co（Ⅱ） and Cd（Ⅱ） Complexes of N-AcetyI-L-glutamic Acid and Imidazole Ligands

Two novel complexes {[Co（A-glu）（Im）2]·0.5H2O}n （1） and [Cd（A-glu）（Im）3]n （2） （H2A-glu=N-acetyl-L-glutamic acid, Im=imidazole） have been synthesized from the reaction of H2A-glu with Co（CH3COO）2·4H2O or Cd（CH3COO）2·2H2O in the presence of Im. Both of the complexes display different coordination environment and similar one-dimensional chain structure. The magnetic susceptibility measurements for 1 show a weak antiferromagnetic interaction between two cobalt（Ⅱ） ions bridged by A-glu ligand. The complex 2 exhibits an intense fluorescent emission in solid state at room temperature.     

稀土（Ce,Gd）掺杂CdS的第一性原理研究

采用第一性原理赝势平面波法中的LDA+U的方法对稀土(Ce,Gd)掺杂CdS的光电性质进行了计算与分析. 结果表明: Ce, Gd掺杂后, CdS的晶格常数增大, 费米面附近的能带明显增多、变密, 禁带宽度有所增大. Ce和Gd的f态的强局域性使体系产生磁有序性. 稀土掺杂后CdS的静态介电常数增大而反射率明显降低. 以上结果表明稀土元素的掺入能有效调制CdS的光电性质.     

A comment on “Ab initio study: the potential energy curves and ro-vibrational spectrum of low-lying excited states of HCl+ cation”

Since the ²Π state in HCl⁺ is an inverted doublet, the energy of the ²Π_1/2 state is higher than the ²Π_3/2. Therefore, the larger value of intensity correspond to the transition of ²Π_3/2. We calculated the Einstein A coefficients and radiation lifetimes for the A²Σ⁺-X²Π transition. Our results are in good agreement with the experimental data and theoretical values. Then the ro-vibrational line intensities of the 1-0 band were calculated for the ²Π_3/2 and ²Π_1/2 states of HCl⁺. Employing the RKR potential, the predicted band origins for Δν=1-0 are 2569.3 and 2568.55 cm-1 for ²Π_3/2 and ²Π_1/2, respectively.     

Synthesis of a new Hg(II) coordination polymer: Ultrasonic-assisted synthesis and mechanical preparation of nanostructure

A new mercury(II) coordination polymer, [Hg(4-bpmo)I₂]_n (1), (4-bpmo = N,N′-bis(pyridin-4-ylmethyl)oxalamide), was synthesized, by branched tube method, and structurally characterized by single-crystal X-ray diffraction. Compound 1 is a polymer with a distorted tetrahedral HgN₂I₂ coordination environment. The thermal stability of 1 was studied by thermal gravimetric (TG) and differential thermal (DTA) analyses. Also 1 was prepared by a sonochemical process at ambient temperature. Reaction time and concentration of initial reagents effects on the size and morphology were studied. Nanoparticles of 1, was synthesized easily by a mechanical method (neat grinding). The resulting structures were characterized by scanning electron microscopy (SEM), IR spectroscopy and X-ray powder diffraction (XRD).     

AgBr/CeO2复合物的制备及其光催化降解甲基橙的研究

以十六烷基三甲基溴化铵为模板,采用共沉淀法合成了AgBr/CeO2复合物,用TEM、XRD和XPS等对产物进行了表征。研究了AgBr/CeO2复合物对甲基橙的光催化效果,探讨了该复合物的催化持久性,以及反应时间、pH、H2O2用量等对光催化降解效果的影响。     

Melting kinetics of bulk SiC using molecular dynamics simulation

The melting kinetics of bulk SiC is studied by using classical molecular dynamics simulation.The mean square displacement,diffusion coefficient,Lindemann index and non-Gaussian parameter are used to analyze the melt nucleation and macrokinetics in the melting process.Melting occurs when the superheated crystal spontaneously generates many Lindemann particles in which they coalesce together to form melt nucleation inside the crystal.The melting process is similar to the solidification process,but also experiences three processes such as nucleation,growth and relaxation.The melting process can be divided into premelting,accelerated melting and relaxation stages.Using the sectional method can properly reflect the kinetic characteristics of the melting process.