Influence of capillary pressure on the evaporation of thin liquid films

A model is presented that considers the influence of capillary pressure on the evaporation of a liquid film on a vertical that plate. The governing equations are derived and numerically integrated with a step-variable Runge-Kutta method. The numerical results are compared with the analytical solution from Nusselt's film condensation theory. The deviation from the Nusselt film theory become very prominent when the liquid film becomes thin enough. This can be attributed to the fact that the Nusselt film theory does not consider the influence of capillary pressure on the shape of the liquid film.Es wird ein Modell vorgestellt, das den Einfluß des Kapillardrucks auf die Verdampfung eines dünnen Flüssigkeitsfilms berücksichtigt, der entlang einer senkrechten Platte herabrieselt. Die maßgebenden Gleichungen werden abgeleitet und numerisch mit einem Runge-Kutta-Verfahren veränderlicher Schrittweite integriert. Die numerischen Ergebnisse werden mit denen der Nusseltschen Filmtheorie verglichen. Dabei ergeben sich beträchtliche Abweichungen von dieser in den Bereichen, in denen der Flüssigkeitsfilm sehr dünn wird. Dies ist darauf zurückzuführen, daß die Nusseltsche Filmtheorie den Einfluß des Kapillardrucks auf die Filmkontur nicht berücksichtigt.     

Structure and magnetostriction of RFex (1.6 ? x ? 2.0) and R(Fe1−yTiy)1.8 (y ? 0.2) alloys (RDy0.65Tb0.25Pr0.1)

Structure, Curie temperature and magnetostriction of RFe_x (1.6 ? x ? 2.0) and R(Fe_1−yTi_y)_1.8 (y ? 0.2) alloys (RDy_0.65Tb_0.25Pr_0.1) have been investigated using optical microscopy, X-ray diffraction, AC initial susceptibility and standard strain gauge techniques. The homogenized RFe_x alloys are found to be essentially single phase in the range of 1.8 ? x ? 1.85. The second phase is a rare-earth-rich phase when x ? 1.8, and (Dy, Tb, Pr)Fe₃ phase when x ? 1.85. X-ray diffraction indicates that the R(Fe_1−yTi_y)_1.8 alloys contain a small amount of Fe₂Ti phase when y ? 0.05, which increases with the increment of Ti content. The Curie temperature of R(Fe₁−_yTi_y)_1.8 alloys slightly enhances with increasing Ti concentration when y ? 0.05, then remains almost unchanged in the range of 0.05 ? y ? 0.20. The magnetostriction of RFe_x alloys is improved when x ? 1.80 and reduced by increasing Fe content when x ? 1.85. The magnetostriction of R(Fe_1−yTi_y)_1.8 alloys is lowered by increasing Ti content.     

A note on interval-polynomial stability

In this note, a theorem of Kharitonov and a theorem of XieNare combined to obtain an approach which simplifies dealingwith the problems of interval–polynomial stability. ^*On leave with Sibley School of Mechanical & Aerospace Engineering,Cornell Univ., Ithaca, NY 14853, USA.     

基于小波变换的数字胸片自适应增强

利用图像自适应增强原理, 推导出小波域中的等价表示. 根据视觉生理心理学原理, 具体的增益系数由图像的背景灰度确定. 同时考虑到胸片中重要的细节信息位于中间频率的特性, 增益系数需要进行调整. 实验结果表明, 调整增益后的小波自适应增强方法能有效的增强数字胸片中的细节信息.     

大气中SO2顺序注射光度测定方法的初步研究

基于SO2在微碱性条件下使孔雀绿褪色的反应原理, 结合顺序注射进样技术建立了光度分析测定大气中SO2的方法. 对试剂加入顺序、各种试剂的浓度、注入体积、反应系统流速等实验参数进行了优化. 采用顺序注射进样, 极大地节省了试剂和试样的用量, 显著地提高了分析速度, 可达到60样·h-1. 方法的线性响应范围0.25～4.0 μg·mL-1, 检出限为0.15 μg·mL-1, 11次重复测定的相对标准偏差为1.5%. 对实际样品的回收率为94%～108%.     

Enzymatic Determination of Glucose by Optical-Fiber Sensor Sequential Injection Renewable Surface Spectrophotometry

Introduction Determinationofglucoseisrequiredinmedicine industry,foodindustry,clinicaldiagnosisaswellas variousresearchfields.Therefore,intensiveefforts havebeendirectedtothedevelopmentofanalytical methodsfordeterminationofglucose,suchasthose basedonbiose…     

杜芬方程的1/3纯亚谐解及过渡过程的分形特征研究

通过谐波平衡法和数值积分法研究了杜芬方程的1／3纯亚谐解．提出假设解，找出了亚谐频域，并对参数变化的过渡过程的敏感性和初始值扰动的过渡过程进行了研究．考察了亚谐响应幅值系数对阻尼的敏感性及亚谐振动谐波成分的渐近稳态性．此外，运用广义分形理论对杜芬方程纯亚谐解过渡过程进行了分析．分析表明，广义维数的敏感维数能清楚地描述杜芬方程纯亚谐解过渡过程特征；并对改变初始扰动、阻尼系数、激励幅值情况下，其两个不同频域的杜芬方程纯亚谐解过渡过程的不同分形特性显现出敏感性．     

On-line sample-pre-treatment schemes for trace-level determinations of metals by coupling flow injection or sequential injection with ICP-MS

Within the last decade, the first generation of flow injection (FI) has been supplemented by sequential injection (SI), also termed the second generation, and, recently, by the third generation, i.e., SI-Lab-on-Valve (SI-LOV). As apparent from the literature, FI and/or SI have become dominant as substitutes for labor-intensive, manual, sample-pre-treatment and/or solution-handling procedures prior to analyte detection by inductively coupled plasma mass spectrometry (ICP-MS). The present review presents and discusses the progress of the state of the art in implementing miniaturized FI/SI systems for on-line matrix separation and pre-concentration of trace levels of metals with detection by ICP-MS. It highlights some of the frequently applied on-line, sample-pre-treatment schemes, including solid phase extraction (SPE), on-wall molecular sorption and precipitate/(co)-precipitate retention using a polytetrafluoroethylene (PTFE) knotted reactor (KR), solvent extraction-back extraction and hydride/vapor generation. It also addresses a novel, robust approach, whereby the protocol of SI-LOV-bead injection (BI) on-line separation and pre-concentration of ultra-trace levels of metals by a renewable microcolumn is interfaced to ICP-MS, as conducted in the present authors' group. It discusses the future outlook in this field.     

流动注射蒸气发生原子吸收光谱测定痕量铜

建立了流动注射蒸气发生原子吸收光谱测定铜的新方法。使含有微量邻菲咯啉的样品溶液与硼氢化钠溶液汇合并反应生成蒸气态物质。在Ar载气下随反应液进入气液分离器分离 ,并进入石英管原子化器在 1 0 0 0℃下检测。在 5 0 0 μL进样体积下 ,铜的检出限为 1 8μg·L- 1 ,相对标准偏差为 2 6%(n =1 1 ,c=1 0 0 μg·L- 1 )。采样频率为 1 4 4样·h- 1 。分析标准参考物质大米粉和头发样品中的铜 ,结果与标准值一致